Thesis for the Degree of Doctor of Philosophy - DTU Orbit

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Raisbeck GM and Yiou F. 1999. 129I in the oceans: origins and applications. Sci. Tot. Environ. 237, 31-41. Reifenhäuser C & Heumann KG. 1990. Development of a definitive method for iodine speciation in aquatic systems. Fresenius J. Anal. Chem., 336: 559-563. Robens E and Aumann DC. 1988. Iodine-129 in the environment of a nuclear fuel reprocessing plant: I. 127 I and 127 I contents of soils, food crops and animal products. J. Environ. Radioact. 7, 159–175. Schall C& Heumann KG. 1993. GC determination of volatile organoiodine and organobromine compounds in Artic seawater and air samples. Fresenius J Anal Chem. 346 : 717-722. Schlegel ML, Reiller P, Mercier – Bion F, Barre N, Moulin V. 2006. Molecular environment of iodine in naturally iodinated humic substances: Insight from X-ray absorption spectroscopy. Geochimica et Cosmochimica Acta 70, 5536-5551. Schmidtz K, Aumann DC. 1995. A study on the association of two iodine isotopes, of natural iodine-127 and of the fission product iodine-129, with soil components using a sequential extraction procedure. J. Radioanal. Nucl. Chem. 198 (1), 229–236. Schulze DG, Bertsch PM. 1995. Synchrotron X-ray techniques in soil, plant, and environmental research Advances in Agronomy, vol. 55, Elsevier. pp.1–66. Schwehr KA. 2003. 129I and 127I in the environment. Ph.D. Dissertation, Department of Oceanography, Texas A&M Universtity, College Station, TX, 2003. Schwehr KA, Santschi PH, Elmore D. 2005. 129I/127I in dissolved organic iodine: A novel tool for tracing terrestrial organic matter in the estuarine surface waters of Galveston Bay, Texas.Limnol. Oceanogr. 3, 326-337. Seki R, Kimura E, Takahashi T, Ikeda N. 1990. Distribution and behavior of long-lived radioiodine in soil. J. Radioanal. Nucl. Chem. 138, 17–31. Shah M, Wuilloud RG, Kannamkumarath SS and Carusow JA. 2005. Iodine speciation studies in commercially available seaweed by coupling different chromatographic techniques with UV and ICP-MS detection. J . A n a l . A t . S p e c t r o m. , 2 0 , 176–182. Sheppard IM and Thibault D.1992.Chemical behavior of iodine in organic and minerals soils. Applied Geochemistry. 7, 265-272. Shimamoto YS, Takahashi Y. 2008. Superiority of K-edge XANES over LIII-edge XANES in the speciation of iodine in natural soils. Anal. Sci. 24, 405–409. 60
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Chemical Speciation Analysis and En
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Thesis for the Degree of Doctor of
Page 5 and 6:
Abstract This thesis deals with che
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environment since they reflect the
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organiske jodformer. Adsorption af
Page 11 and 12: None of this would have been possib
Page 13 and 14: Abbreviations and acronyms b+ - pos
Page 15 and 16: 3.1 Analytical Development………
Page 17 and 18: Table 1 Some properties of iodine P
Page 19 and 20: In soils/sediments iodine occurs as
Page 21 and 22: Table 2 Nuclear properties of iodin
Page 23 and 24: Liquid scintillation counting (LSC)
Page 25 and 26: The bioavailability of radioactive
Page 27 and 28: data (Englund et al., 2010; Hou et
Page 29 and 30: 2. Analytical procedures used in th
Page 31 and 32: 2.3 Quantification of total iodine
Page 33 and 34: Fig. 5 Quantification of total iodi
Page 35 and 36: iodate were measured by counting 12
Page 37 and 38: Fig. 6 Sequential extraction proced
Page 39 and 40: a Fig. 8 Calibration curve for (a)
Page 41 and 42: experiment was subjected to combust
Page 43 and 44: Table 7 Adsorption of iodine specie
Page 45 and 46: numbers 11-14), which is about the
Page 47 and 48: marine environment from nuclear fue
Page 49 and 50: 127 I - (ppb) 127 IO3 - (ppb) a b 1
Page 51 and 52: Although the oxygen concentration d
Page 53 and 54: 129 I TBq 2,00E+00 1,80E+00 1,60E+0
Page 55 and 56: • Adsorption of iodine species on
Page 57 and 58: Reference Aldahan A, Kekli A, Possn
Page 59 and 60: Fuge R& Johnson C. 1986. The geoche
Page 61: Lo´pez-Gutie´rrez JM, Garcı ´a-
Page 65 and 66: http://www.irsn.fr/EN/news/Document
Page 67 and 68: Review Analytica Chimica Acta 632 (
Page 69 and 70: Table 1 Nuclear properties and prod
Page 71 and 72: Fig. 2. Liquid discharges of 129 I
Page 73 and 74: Fig. 5. Schematic diagram and pictu
Page 75 and 76: 129 I in iodide and iodate is then
Page 77 and 78: Fig. 8. Diagram of air sampler for
Page 79 and 80: Fig. 10. Iodine L3-edge (a) and K-e
Page 81 and 82: analysis of 129 I in water sample a
Page 83 and 84: Yi P, Aldahan A, Hansen V, Possnert
Page 85 and 86: FIGURE 1. Sampling sites (the red s
Page 87 and 88: FIGURE 3. Horizontal distribution o
Page 89 and 90: FIGURE 5. Time series data of 129 I
Page 91 and 92: Environmental Science & Technology
Page 93 and 94: prepared using KI and KIO3. No diff
Page 95 and 96: of their contribution to the Baltic
Page 97 and 98: Fig. S-1 Sampling sites (the red so
Page 99 and 100: Fig. S-3 Vertical distribution of I
Page 101 and 102: Fig. S-5 Marine discharges function
Page 103 and 104: Fig.S-7 Relationship between I-129
Page 105 and 106: Table S-1 Results of I-129 and I-12
Page 107 and 108: S17
Page 109 and 110: Paper III Hansen,V., Yi, P., Hou, X
Page 111 and 112: conversion process between iodide a
Page 113 and 114:
Table 1 Analytical results of 129 I
Page 115 and 116:
August April I-129 iodide ( 10 8 at
Page 117 and 118:
References Aldahan A, Kekli A, Poss
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Partition of iodine ( 129 I and 127
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Norway (Table 1). CTD-casts with ox
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5. Discussion 5.1. Separation of hu
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In the present study 40e60% of 129
Page 127 and 128:
Hutta, M., Gora, R., 2003. Novel st
Page 129 and 130:
Analysis of 129 I and 127 I in arch
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et al., 2002). Due to the fact that
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espectively. The iodine was leached
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salinities in the same area. Apart
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North Sea. 129 I/ 127 I ratios in w
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Table 2 Analytical results of 129-I
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129 I/ 127 I 1,40E-07 1,20E-07 1,00
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References Aldahan A, Englund E, Po
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O’Dowd, C.; Jimenez, J. L.; Bahre
Page 147 and 148:
Iodine ( 129 I and 127 I) speciatio
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water in winter by molecular oxygen
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0.2 M KNO3. The effluent and the wa
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maximum values is at 0.03-0.06×10
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into the English Channel from the L
Page 157 and 158:
References Aldahan A, Kekli A, Poss
Page 160 and 161:
Risø-PhD-81(EN)
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Thesis for the Degree of Doctor of Philosophy - DTU Orbit

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