Geological Survey of Denmark and Greenland Bulletin 26 ... - Geus
Geological Survey of Denmark and Greenland Bulletin 26 ... - Geus
Geological Survey of Denmark and Greenland Bulletin 26 ... - Geus
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New evidence for possible generation <strong>of</strong> oil<br />
<strong>of</strong>f south-western Greenl<strong>and</strong><br />
Troels Laier <strong>and</strong> Hans Peter Nyt<strong>of</strong>t<br />
In 2011, traces <strong>of</strong> bitumen in the 1160 Ma old Ilímaussaq intrusion<br />
in South Greenl<strong>and</strong> have been examined in order to<br />
determine their origin. The investigation was prompted by<br />
the recent interest in hydrocarbon exploration <strong>of</strong>f western<br />
Greenl<strong>and</strong>, an interest expressed in the form <strong>of</strong> four new licences<br />
in the region (Christiansen 2011). The hydrocarbon<br />
potential in the region was realised after reinterpretation <strong>of</strong><br />
seismic pr<strong>of</strong>iles across the Labrador Sea, <strong>and</strong> this indicates<br />
the presence <strong>of</strong> a sedimentary basin <strong>of</strong>f south-western Greenl<strong>and</strong><br />
(Fig. 1; Chalmers & Pulvertaft 2001). However, the<br />
main problem in petroleum exploration <strong>of</strong>f south-western<br />
Greenl<strong>and</strong> is that no prolific marine source rocks have been<br />
demonstrated (Christiansen 2011). Therefore, any trace <strong>of</strong><br />
hydrocarbons, however small that may help demonstrate the<br />
occurrence <strong>of</strong> source rocks in the region, deserves careful examination.<br />
Recently, bitumen biomarkers have been used to question<br />
the presumed abiogenic origin <strong>of</strong> hydrocarbons in crystalline<br />
rocks <strong>of</strong> the Ilímaussaq intrusion (Laier & Nyt<strong>of</strong>t 2012). In<br />
this paper, we focus on the origin <strong>of</strong> the bitumen <strong>and</strong> compare<br />
it with previous finds in central West Greenl<strong>and</strong>. The<br />
presence <strong>of</strong> hydrocarbons in the Ilímaussaq intrusion has<br />
been known since 1970 (Petersilie & Sørensen 1970) but<br />
unlike the discovery <strong>of</strong> oil seeps in the Nuussuaq region in<br />
central West Greenl<strong>and</strong> twenty years later, which had a positive<br />
impact on petroleum exploration (Christiansen 2011),<br />
the hydrocarbons in the Ilímaussaq intrusion were largely<br />
ignored in the context <strong>of</strong> <strong>of</strong>fshore exploration. The reason<br />
for this is tw<strong>of</strong>old: (1) hydrocarbons in the Ilímaussaq intrusion<br />
are much more difficult to recognise than on Nuussuaq,<br />
<strong>and</strong> (2) analytical results are confusing with respect<br />
to the origin <strong>of</strong> the hydrocarbons. Discrete millimetre-size<br />
hydrocarbon accumulations have only been observed twice,<br />
<strong>and</strong> samples <strong>of</strong> this material were unfortunately not available<br />
for analysis in the present investigation. The material,<br />
which is a waxy paraffinic hydrocarbon <strong>of</strong> C 28<br />
H 56<br />
, was located<br />
in vugs <strong>of</strong> pegmatite veins <strong>and</strong> labelled as an evenkitelike<br />
mineral by Konnerup-Madsen et al. (1979). Otherwise<br />
hydrocarbons in the Ilímaussaq intrusion only exist in fluid<br />
inclusions, mainly as C 1<br />
–C 5,<br />
<strong>and</strong> as dispersed bitumen invisible<br />
to the naked eye. The stable carbon isotopic ratio <strong>of</strong> methane<br />
(δ 13 C = –7‰) released from the inclusions by crushing<br />
(Petersilie & Sørensen 1970) differed from that <strong>of</strong> associated<br />
methane in most oil <strong>and</strong> gas reservoirs, which has δ 13 C values<br />
<strong>of</strong> –30 to –50‰. The ratio was closer to the isotopic ratio<br />
<strong>of</strong> primodial carbon <strong>of</strong> the Earth’s mantle, which has δ 13 C<br />
values around –5‰. The paraffinic hydrocarbons <strong>of</strong> ‘evenkite’<br />
on the other h<strong>and</strong> had a δ 13 C value <strong>of</strong> –29‰, which<br />
is within the expected range for hydrocarbons generated by<br />
thermal maturation <strong>of</strong> organic matter (Konnerup-Madsen et<br />
al. 1988).<br />
66°N<br />
Greenl<strong>and</strong><br />
60°N<br />
Nuussuaq<br />
Marraat<br />
100 km<br />
Ilímaussaq<br />
intrusion<br />
48°W<br />
66°N<br />
Fig. 1. Map <strong>of</strong> south-western Greenl<strong>and</strong> showing the distribution <strong>of</strong> Mesozoic/Cenozoic<br />
rift basins <strong>of</strong>fshore (green). Modified from Chalmers &<br />
Pulvertaft (2001). Oil seeps occur on Nuussuaq.<br />
© 2012 GEUS. <strong>Geological</strong> <strong>Survey</strong> <strong>of</strong> <strong>Denmark</strong> <strong>and</strong> Greenl<strong>and</strong> <strong>Bulletin</strong> <strong>26</strong>, 65–68. Open access: www.geus.dk/publications/bull<br />
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