Modern Polymer Spect..

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Contributors M. Del Zoppo Dipartimento di Chimica Industriale Politecnico di Milaiio Piazza L. Da Vinci 32 20133 Milano Italy A. E. Do?;rey The Procter and Gamble Company Miami Valley Laboratories P.O. Box 398707 Cincinnati, OH 45239-8707 USA Y. Furukawa Department of Chemistry School of Science and Engineering Waseda University Shinjuku-ku 169 Tokyo Japan U. Hoffmann Bruins Instruments D 82178 Puchheim Germany S. Krimm Biophysics Research Division and Department of Physics University of Michigan Ann Arbor, MI 48109 USA Ch. Kulinna Bayer AG D 40789, Monheim Germany C. Marcott The Procter and Gamble Company Miami Valley Laboratories P.O. Box 398707 Cincinnati, OH 45239-8707 USA I. Noda The Procter and Gamble Company Miami Valley Laboratories P.O. Box 398707 Cincinnati? OH 45239-8707 USA S. Okretic Fachhochschule Niederrhein Fachbereich 04 D 7805 Krefeld Germany S. Shilov Institute of Macromolecular Compounds 199004 St. Petersburg Russia H. W. Siesler Department of Physical Chemistry University of Essen D 45 1 17 Esseii Gerinaii y
xiv Coiitribirtovs M. Tasumi Department of Chemistry Faculty of Science Saitama University Urawa Saitama 338 Japan I. Zebger Department of Physical Chemistry University of Essen D 451 17 Essen Germany G. Zerbi Dipartiniento di Chiinica Iiidustriale Politecnico di Milano Piazza L. Da Vinci 32 20133 Milano Italy
Page 2 and 3: Modern Polymer Spectroscopy Edited
Page 4 and 5: Modern Polymer Spectroscopy Edited
Page 6 and 7: Preface For unfortunate reasons the
Page 8 and 9: However, theory and calculations yi
Page 10 and 11: Contents 1 Two-Dimensional Infrared
Page 12 and 13: Con ten t~ xi Index 5.2 Force Field
Page 16 and 17: 1 Two-Dimensional Infrared (2D IR)
Page 18 and 19: 1.2 Brick~qrorrnrl 3 . Figure 1-3.
Page 20 and 21: 1.0 , Figure 1-6. The in-phtrse and
Page 22 and 23: 1.2 Bcrckgroinizd 7 where AA (i~) i
Page 24 and 25: 1.2 Background 9 1.2.5 Two-Dimensio
Page 26 and 27: 1.3 Bnsic Properties of 20 IR Corre
Page 28 and 29: 2D IR spectrometer coupled with a d
Page 30 and 31: 1.5 Applirtrtions 15 Unlike a dispe
Page 32 and 33: \ '\ Melliyleiie 1'7- -3000 Posiliv
Page 34 and 35: 11 Amorphous Crystalline ,...." I F
Page 36 and 37: 1.5 Applications 21 / I 1430 Figure
Page 38 and 39: 1.5 Appliccitioiis 23 Methylene Fig
Page 40 and 41: 1.5 Ajqdicrrtions 25 3024 Figure 1-
Page 42 and 43: 1.5 Applicutions 27 Furthermore. th
Page 44 and 45: 1.7 Coizclirsions 29 derived in a s
Page 46 and 47: 1.9 References 31 [9] Colthup, N. B
Page 48 and 49: 2 Segmental Mobility of Liquid Crys
Page 50 and 51: SRMPLE/DETECTOR e3 ‘retardation
Page 52 and 53: 2.4 Srvuc me-Dependenr Alignment 37
Page 54 and 55: 2.5 Electric Field-Innductid Orirnt
Page 56 and 57: 2.5 Electric Field-nclticetl Orient
Page 58 and 59: a -@ COWER SRHPLE ._ 2.5 Elec tric
Page 60 and 61: 2.5 Electric Field-Itzduced Orienta
Page 62 and 63: 2.5 Electric Field-IwrElrced Orient
Page 64 and 65:
2.5 Electric Field-Im/irced Orientu
Page 66 and 67:
2.5 Electric Field-Induced Orientli
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2.5 Electric Field-Induced Orientat
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2.5 Electric Field-Induced Orienfat
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2.5 Elrc tric Field-Iiidircwl Orim
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2500 2008 I s00 WRVtNdMRtR CM-I Fig
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-3.6 Aligmient OJ' Side- Clinin Liy
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~ polyester 2.6 Alignnient qf Side-
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I." 0.9 0.8 Figure 2-34. FTlR 0.7 p
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induced alignment of the investigat
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2.7 Orientation oj Liquid Ci:i,stal
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2.7 Orieritation of Liquid Ciysttrl
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0 8 18 16 1 a W u z a m a 0 Ln m Q
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2.7 Orientation oj Liquid Crystals
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2.7 Orientation of Liquid Crjvtals
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2.7 Orientatioiz of Liquid Crystals
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2.8 Conclusions 81 strain. As A0 is
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3. I0 Refcreiice.r 83 [I 71 Hoffina
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2.10 References 85 [92] Wiesner, U.
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t Order/Disorder in Chain Molecules
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onds which hold atoms together thro
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3.2 The Dyriamical Case qf Simll ar
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3.2 The Dyrinniical Case of Sinnll
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3.4 S11or.f- and Loizg-Rcrizye Vibr
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3.4 Slzort- and Loiig-Range Vibrati
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eyularity), e.g., 2. During the pol
Page 116 and 117:
3.5 Towards Lnrger Molecules: From
Page 118 and 119:
3.5 TOIIYW~ Laiyer Molertiles: Fvoi
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3.5 Towmu" Larger Molecules: F~om O
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1700 - CIO --- ca c 22 _- c 12 l l
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3.6 From Dynamics to Vibrational Sp
Page 126 and 127:
3.6 Froin Dynaiiiics to T’ihratio
Page 128 and 129:
3.7 The Case of Isotactic Polypropy
Page 130 and 131:
3.7 The Cuse of Isotactic Polypvop.
Page 132 and 133:
3.8 Density of Vibrational States a
Page 134 and 135:
3.8 Dtvz.sit,v of L’ihrntioizal S
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3.8 Driisity of Vibratioiid StLitrs
Page 138 and 139:
3 9 Mouiiiq ToIvmds Rerrlitv: From
Page 140 and 141:
3.9 Moving Towards Reality: From Or
Page 142 and 143:
3.9 Moving Towards Reality: Froin O
Page 144 and 145:
3.10 Wlmt Do We Learn from Cnlcailc
Page 146 and 147:
+ 3.11 A Very Siriiple Ccrse: Latti
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3 I1 A Yey) Siiiiple Case: LLittice
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3.11 A Vq> Siiiiplc Crrw: Luttice D
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Figure 3-22. Sample eigenvectors in
Page 154 and 155:
3.12 CIS-trans Opening @the Double
Page 156 and 157:
3.13 Defect Modes cis Structtrr.al
Page 158 and 159:
3.13 Defect Mo&s cis Structurcil Pr
Page 160 and 161:
0 3.14 Case Studies N 0 d - Y N o m
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3.14 Case Studies 147 OC 60 58 57.
Page 164 and 165:
3.14 Case Studies 149 GI A V E N U
Page 166 and 167:
3.14 Case Studies 15 1 correspond t
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3.14 Case Studies 153 (I10 + 200) +
Page 170 and 171:
3.14 Case Studies 155 1500 1480 146
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3.14 Case Studies 157 the molecular
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17E (ir 1, R): (iii) z = 4, t = 1,
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3.16 Stnictural Znlioi~zogeneity an
Page 178 and 179:
3.1 7 Fermi Resonancrs 163 stants.
Page 180 and 181:
3.1 7 Femi Resorinnces 165 2 L 1 29
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lowing. The CHl-bending mode 6 [cer
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3.17 Ferini Re.sonrriire.s 169 a Fi
Page 186 and 187:
3. I7 Fernii Resoiiances 17 1 terin
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3.18 Band Broadening and Confonnati
Page 190 and 191:
3.18 Bmd Brourleiziriy md Cmforrnat
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3.18 Band Bvoaderiing arid Conjonna
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3.18 Band Broadening and Confornmti
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3.19 A Worked E.utinple 181 pre-mel
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3.19 A Wovh-ecl E.uanzple 183
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3.19 A Worked Example 185 19 5°C 2
Page 202 and 203:
3.19 A Workrd Example 187 Figure 3-
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3.19 A Worked E.rcnniplr 189 LAM I
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3.19 A Worked E.xuniple 191 Figure
Page 208 and 209:
3.19 A Worked E.vnn~yle 193 Figure
Page 210 and 211:
3.19 A Worked E.vnrqde 195 009.1 00
Page 212 and 213:
3.19 A Worked Example 197 existence
Page 214 and 215:
3.1 9 A Worked Example 199 The soli
Page 216 and 217:
3.20 References 201 very important,
Page 218 and 219:
3.20 References 203 [41] M. Gussoni
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3.20 Refeeveiicrs 205 [I 171 P. Jon
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4 Vibrational Spectroscopy of Intac
Page 224 and 225:
4.3 Georrietvy oj Intuct Po1vniev.r
Page 226 and 227:
1'45 4.4 Geometric Chunges I?zditce
Page 228 and 229:
4.4 Geometric Chmges Iiid~lrcecl bj
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4 5 Mer1iodolog.v of Raiii~11 Studi
Page 232 and 233:
4.7 Poly(p-pheiq.lene) 217 with an
Page 234 and 235:
4.7 Pol)~(p-pheiz~~lene) 219 ENERGY
Page 236 and 237:
is worthwhile pointing out that the
Page 238 and 239:
~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ 801 Table 4-3
Page 240 and 241:
4.7 Poly(y-phenylene) 225 Figure 4-
Page 242 and 243:
Table 4-4. Observed Raman frequenci
Page 244 and 245:
4.8 Other Polwieys 229 Table 4-5. T
Page 246 and 247:
under various models. According to
Page 248 and 249:
4. I0 Mechnriism oj Charge. Transpo
Page 250 and 251:
4.12 Reftrences 235 [ 131 Kuzmany,
Page 252 and 253:
4.12 References 237 [98j Matsunuma,
Page 254 and 255:
5 Vibrational Spectroscopy of Polyp
Page 256 and 257:
5.2 FOYCC Fields 241 such calculati
Page 258 and 259:
5.2 Force Fields 243 accounts for o
Page 260 and 261:
5.2 Force Fields 245 centers of the
Page 262 and 263:
5.2 Force Fields 247 ture with conf
Page 264 and 265:
5.3 Amide Modes 249 to the nh initi
Page 266 and 267:
5.3 Ainide Modes 251 Table 5-1. Ami
Page 268 and 269:
Table 5-2. Some amide modes of four
Page 270 and 271:
5.3 Amidc Modes 255 Figure 5-1. Opt
Page 272 and 273:
5.4 Polypeptides 257 nonhydrogen-bo
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5.4 Polvpeptida 259 Figure 5-2. Ant
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I 5.4 Polypeptides 261 )I .- + $ 80
Page 278 and 279:
1226M 1222s (1 1165W 1167s (1 1120V
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135s 9 1 Ms1i 122Wbr 147 NH ob(37)
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5.4 Polypeptides 267 glycine residu
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5.4 Polypeptides 269 Raman bands in
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5.4 Polypeptides 271 Figure 5-7. St
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Frequency (cm-'1 100% b 700 500 300
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5.4 Polypptidt~s 215 Table 5-9. Obs
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~~ ~~ ~~~ ~ ~ ~~ 5.4 Polypeptides 2
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5.4 Poliyeptides 219 Table 5-11. Co
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Table 5-12. Aniide mode frequencies
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1351 Lifson, S., Stern, P. S., J. C
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5.6 Refeverices 285 [130] Tiffany,
Page 302 and 303:
Index Amide modes 249 Amorphous pol
Page 304 and 305:
Step-scan FTIR spectroscopy 14,34 -
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