Modern Polymer Spect..

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3.20 Refeeveiicrs 205 [I 171 P. Jona, M. Gussoni and G. Zerbi. J. Appl. Phys., 1985 57, 834. [118] M. Gussoni, P Jona and G. Zerbi. J. Mol. Struct., Theochem, 1985 119, 329; ibid. p. 347. [119] T. Shimanouchi, J. Phys. Chem. Ref: Data, 1973 2, 225. [120] G. Zerbi, G. Gallino, N. Del Fanti and L. Baini, Polymer.. 1989 30, 2324. [I211 G. Avitnbile, R. Napolitano, R. Pinozzi, K. D. Rouse, W. Thomas and B. T. M. Willis, Polvn1. Lett.. 1975 13, 371. [I221 S. Abbate, M. Gussoni and G. Zerbi, J. Cheni. Phj~x, 1979 70, 3577. [I731 E. Agosti, G. Zerbi and I. M. Ward, Polymer 1992 33, 4219. [124] G. Zerbi, G. Conti, G. Minoni, S. Pison and A. Bigotto. J. Phys. Chenz. 1987 91, 2386. [125] M. Del Zoppo and G. Zerbi, Polymer, 1990 31, 658. [ 1261 D. Chapmann, Thc Structi/re of Lipids, Methuen, London, 1965. 11271 C. Almirante, G. Minoni and G. Zerbi, J. Phys., Cheni., 1986 YO, 852. 11281 L. Basini, A. Rafhelli and G. Zerbi, C11ein. Motel-. 1990 2, 679. [129] G. Ferrdri and G. Zerbi, J. Rrmiczn Spectroscopy, 1994 25, 713. [I301 For a discussion on the structure of PVC see, for instance, F. A. Bovey, F. P. Hood, E. W. Anderson and R. L. Kornegay, J. Phys. Clzem. 1967 71, 312; L. Cavalli, G. C. Borsini, G. Carraro and G. Confalonieri, J. Po/jm Sci., Part A-1. 1970 8, 801. 11311 R. F. Schaufele and T. Shimanouchi, J. Chem. Phys. 1967 47, 3605. 11321 T. Shimanouchi, Piwe and Appl. Chem., 1973 36, 93. 11331 G. Minoni and G. Zerbi, J. Phys. Chem., 1982 86, 4791. 11341 G. Minoni and G. Zerbi, J. Pdym. Sci. Polyni. Lett., 1984 22, 533. [I351 E. Fermi, Z. Physik, 1931 71, 250. [136] J. Lavalley and N. Sheppard, Spectrochim. Acta, Part A. 1972 28, 845. [137] S. Wunder, M. Bell and G. Zerbi, J. Chem. Phys., 1986 85, 3827. 11381 R. G. Snyder, S. L. Hsu and S. Krimm. Spectroclzini. Am, Part A, 1978 31, 395. 11391 R. G. Snyder and J. R. Scherer, J. Chem. Phys., 1979 71, 3271. [140] S. Abbate, G. Zerbi and S. L. Wunder, J. Pkjx Chenz., 1982 86, 3140. [I411 S. Abbate, S. L. Wunder and G. Zerbi, J. Phys. C/zeni.. 1984 88, 593. 11421 L. Ricard, S. Abbate and G. Zerbi. J. Phys. Cheni., 1985 89, 4793. [143] G. Zerbi and S. Abbate, Chem. Phys. Lett., 1981 80, 455. [144] M. Del Zoppo and G. Zerbi, Polymer, 1991 32, 1581. 11451 G. Zerbi, P. Roncone, G. Longhi and S. L. Wunder, J. Chem. Phys., 1988 89, 166. 11461 R. G. Snyder, J. R. Scherer and P. Gaber. Biochinz. Biophjx Acta, 1980 601, 47. [147] W. G. Rotschild, Dyirtiniics of'Molecukrr Liqiiitls. Wiley, New York, 19S4. [148] B. G. Sumpter, D. W. Noid and B. Wunderlich, J. Chem. Phys. 1990 93, 6875; G. L. Liang, D. W. Noid, B. G. Sumpter and B. Wunderlich, Actu Polymer., 1993 44, 319. [149] M. Kobayashi, T. Kobayashi, Y. Cho and F. Kaneko, J. Chem. Phys. 1986 84,4636. [I501 1. W. Levin, in Adoances in IR arid Rantan Spectroscopy, Wiley, New York. 1984, Vol 11. [151] B. P. Gaber and W. Peticolas, Biochim. Biophys. Acta 1977 465, 260. 11521 A. Muller, Proc. Royrl Soc., London Ser. 1930 A127, 417. 11531 M. Broadhurst, J. Res. Nut/. Btrr. Stand Sect 1962 A66, 241. [ 1541 K. Larsson, Nature (London) 1967 213, 383. [155] G. Zerbi, R. Piazza and K. Holland-Moriytz, Polymer, 1982 23, 1921. [156] G. Ungar and A. Keller, Colloid Pol~vi. Sci., 1979 257, 90. [157] F. Guillaume, C. Sourisseau and A. J. Dianoux, J. Cheni. Phys., 1990 93. 3536. [158] P. Jona, B. Bassetti, V. Benza and G. Zerbi, J. Chenz. Phys., 1987 86, 1561. 11591 M. L. Klein, J. Client Soc. Farada~ Trans., 1992 13, 1701. 11601 L. Askadskaya and J. P. Rabe, Phys. Reo. Lett., 1992 69, 1395. [lhl] For review on model calculations see D. W. McClure, J. C/iern. Phys., 1968 49, 1530. [162] H. G. Olf and A. Peterlin, J. Poly. Sci., 1970 A2, 791. [ 1631 B. Ewen and D. Richter, J. Cheni. Pliys. 1978 69, 2954. [164] J. D. Barnes, J. Chern. Phys., 1973 58. 5193. [165] R. L. McCullough, J. Macromol. Sci.. Phys., 1974 9, 97. 11661 M. Mansfield and R. H. Boyd, J. PO/~YJI. Sci.. Polyni. Pliys. Ed.., 1978 16, 1227. 11671 M. L. Mansfield, CIIenz. Plijx Lett., 1980 69, 383.
206 3 Vibratiord Spectra cis a Prohr of StrirctLiral Order [168] J. L. Skiiiiiei- and P. J. Wolynes, Chm. Phys, 1980 73, 4015. [169] G. Zerbi aiid M. Del Zoppo, J. Clzern. SOC. Fur.crday T~nr7s., 1992 88, 1835. [ 1701 H. Dwey-Aharon, T. S. Slucking, P. L. Taylor and A. J. Hopfinger, Phys. Rev. Sw. B, 1980 21. 11711 G. Borionetti, G. Zaiiiioni and G. Zerbi, J. Mol. Srvircf. 1990 12.1, 425 [I721 S. Radice, N. Del Fanti and G. Zerbi, Po/ynirr, 1997 35, 2753.
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Modern Polymer Spectroscopy Edited
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Modern Polymer Spectroscopy Edited
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Preface For unfortunate reasons the
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However, theory and calculations yi
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Contents 1 Two-Dimensional Infrared
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Con ten t~ xi Index 5.2 Force Field
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Contributors M. Del Zoppo Dipartime
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1 Two-Dimensional Infrared (2D IR)
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1.2 Brick~qrorrnrl 3 . Figure 1-3.
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1.0 , Figure 1-6. The in-phtrse and
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1.2 Bcrckgroinizd 7 where AA (i~) i
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1.2 Background 9 1.2.5 Two-Dimensio
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1.3 Bnsic Properties of 20 IR Corre
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2D IR spectrometer coupled with a d
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1.5 Applirtrtions 15 Unlike a dispe
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\ '\ Melliyleiie 1'7- -3000 Posiliv
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11 Amorphous Crystalline ,...." I F
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1.5 Applications 21 / I 1430 Figure
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1.5 Appliccitioiis 23 Methylene Fig
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1.5 Ajqdicrrtions 25 3024 Figure 1-
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1.5 Applicutions 27 Furthermore. th
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1.7 Coizclirsions 29 derived in a s
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1.9 References 31 [9] Colthup, N. B
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2 Segmental Mobility of Liquid Crys
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SRMPLE/DETECTOR e3 ‘retardation
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2.4 Srvuc me-Dependenr Alignment 37
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2.5 Electric Field-Innductid Orirnt
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2.5 Electric Field-nclticetl Orient
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a -@ COWER SRHPLE ._ 2.5 Elec tric
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2.5 Electric Field-Itzduced Orienta
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2.5 Electric Field-IwrElrced Orient
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2.5 Electric Field-Im/irced Orientu
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2.5 Electric Field-Induced Orientli
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2.5 Electric Field-Induced Orientat
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2.5 Electric Field-Induced Orienfat
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2.5 Elrc tric Field-Iiidircwl Orim
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2500 2008 I s00 WRVtNdMRtR CM-I Fig
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-3.6 Aligmient OJ' Side- Clinin Liy
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~ polyester 2.6 Alignnient qf Side-
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I." 0.9 0.8 Figure 2-34. FTlR 0.7 p
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induced alignment of the investigat
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2.7 Orientation oj Liquid Ci:i,stal
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2.7 Orieritation of Liquid Ciysttrl
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0 8 18 16 1 a W u z a m a 0 Ln m Q
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2.7 Orientation oj Liquid Crystals
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2.7 Orientation of Liquid Crjvtals
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2.7 Orientatioiz of Liquid Crystals
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2.8 Conclusions 81 strain. As A0 is
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3. I0 Refcreiice.r 83 [I 71 Hoffina
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2.10 References 85 [92] Wiesner, U.
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t Order/Disorder in Chain Molecules
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onds which hold atoms together thro
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3.2 The Dyriamical Case qf Simll ar
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3.2 The Dyrinniical Case of Sinnll
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3.4 S11or.f- and Loizg-Rcrizye Vibr
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3.4 Slzort- and Loiig-Range Vibrati
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eyularity), e.g., 2. During the pol
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3.5 Towards Lnrger Molecules: From
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3.5 TOIIYW~ Laiyer Molertiles: Fvoi
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3.5 Towmu" Larger Molecules: F~om O
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1700 - CIO --- ca c 22 _- c 12 l l
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3.6 From Dynamics to Vibrational Sp
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3.6 Froin Dynaiiiics to T’ihratio
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3.7 The Case of Isotactic Polypropy
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3.7 The Cuse of Isotactic Polypvop.
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3.8 Density of Vibrational States a
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3.8 Dtvz.sit,v of L’ihrntioizal S
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3.8 Driisity of Vibratioiid StLitrs
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3 9 Mouiiiq ToIvmds Rerrlitv: From
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3.9 Moving Towards Reality: From Or
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3.9 Moving Towards Reality: Froin O
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3.10 Wlmt Do We Learn from Cnlcailc
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+ 3.11 A Very Siriiple Ccrse: Latti
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3 I1 A Yey) Siiiiple Case: LLittice
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3.11 A Vq> Siiiiplc Crrw: Luttice D
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Figure 3-22. Sample eigenvectors in
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3.12 CIS-trans Opening @the Double
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3.13 Defect Modes cis Structtrr.al
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3.13 Defect Mo&s cis Structurcil Pr
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0 3.14 Case Studies N 0 d - Y N o m
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3.14 Case Studies 147 OC 60 58 57.
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3.14 Case Studies 149 GI A V E N U
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3.14 Case Studies 15 1 correspond t
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3.14 Case Studies 153 (I10 + 200) +
Page 170 and 171: 3.14 Case Studies 155 1500 1480 146
Page 172 and 173: 3.14 Case Studies 157 the molecular
Page 174 and 175: 17E (ir 1, R): (iii) z = 4, t = 1,
Page 176 and 177: 3.16 Stnictural Znlioi~zogeneity an
Page 178 and 179: 3.1 7 Fermi Resonancrs 163 stants.
Page 180 and 181: 3.1 7 Femi Resorinnces 165 2 L 1 29
Page 182 and 183: lowing. The CHl-bending mode 6 [cer
Page 184 and 185: 3.17 Ferini Re.sonrriire.s 169 a Fi
Page 186 and 187: 3. I7 Fernii Resoiiances 17 1 terin
Page 188 and 189: 3.18 Band Broadening and Confonnati
Page 190 and 191: 3.18 Bmd Brourleiziriy md Cmforrnat
Page 192 and 193: 3.18 Band Bvoaderiing arid Conjonna
Page 194 and 195: 3.18 Band Broadening and Confornmti
Page 196 and 197: 3.19 A Worked E.utinple 181 pre-mel
Page 198 and 199: 3.19 A Wovh-ecl E.uanzple 183
Page 200 and 201: 3.19 A Worked Example 185 19 5°C 2
Page 202 and 203: 3.19 A Workrd Example 187 Figure 3-
Page 204 and 205: 3.19 A Worked E.rcnniplr 189 LAM I
Page 206 and 207: 3.19 A Worked E.xuniple 191 Figure
Page 208 and 209: 3.19 A Worked E.vnn~yle 193 Figure
Page 210 and 211: 3.19 A Worked E.vnrqde 195 009.1 00
Page 212 and 213: 3.19 A Worked Example 197 existence
Page 214 and 215: 3.1 9 A Worked Example 199 The soli
Page 216 and 217: 3.20 References 201 very important,
Page 218 and 219: 3.20 References 203 [41] M. Gussoni
Page 222 and 223: 4 Vibrational Spectroscopy of Intac
Page 224 and 225: 4.3 Georrietvy oj Intuct Po1vniev.r
Page 226 and 227: 1'45 4.4 Geometric Chunges I?zditce
Page 228 and 229: 4.4 Geometric Chmges Iiid~lrcecl bj
Page 230 and 231: 4 5 Mer1iodolog.v of Raiii~11 Studi
Page 232 and 233: 4.7 Poly(p-pheiq.lene) 217 with an
Page 234 and 235: 4.7 Pol)~(p-pheiz~~lene) 219 ENERGY
Page 236 and 237: is worthwhile pointing out that the
Page 238 and 239: ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ 801 Table 4-3
Page 240 and 241: 4.7 Poly(y-phenylene) 225 Figure 4-
Page 242 and 243: Table 4-4. Observed Raman frequenci
Page 244 and 245: 4.8 Other Polwieys 229 Table 4-5. T
Page 246 and 247: under various models. According to
Page 248 and 249: 4. I0 Mechnriism oj Charge. Transpo
Page 250 and 251: 4.12 Reftrences 235 [ 131 Kuzmany,
Page 252 and 253: 4.12 References 237 [98j Matsunuma,
Page 254 and 255: 5 Vibrational Spectroscopy of Polyp
Page 256 and 257: 5.2 FOYCC Fields 241 such calculati
Page 258 and 259: 5.2 Force Fields 243 accounts for o
Page 260 and 261: 5.2 Force Fields 245 centers of the
Page 262 and 263: 5.2 Force Fields 247 ture with conf
Page 264 and 265: 5.3 Amide Modes 249 to the nh initi
Page 266 and 267: 5.3 Ainide Modes 251 Table 5-1. Ami
Page 268 and 269: Table 5-2. Some amide modes of four
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5.3 Amidc Modes 255 Figure 5-1. Opt
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5.4 Polypeptides 257 nonhydrogen-bo
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5.4 Polvpeptida 259 Figure 5-2. Ant
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I 5.4 Polypeptides 261 )I .- + $ 80
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1226M 1222s (1 1165W 1167s (1 1120V
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135s 9 1 Ms1i 122Wbr 147 NH ob(37)
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5.4 Polypeptides 267 glycine residu
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5.4 Polypeptides 269 Raman bands in
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5.4 Polypeptides 271 Figure 5-7. St
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Frequency (cm-'1 100% b 700 500 300
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5.4 Polypptidt~s 215 Table 5-9. Obs
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~~ ~~ ~~~ ~ ~ ~~ 5.4 Polypeptides 2
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5.4 Poliyeptides 219 Table 5-11. Co
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Table 5-12. Aniide mode frequencies
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1351 Lifson, S., Stern, P. S., J. C
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5.6 Refeverices 285 [130] Tiffany,
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Index Amide modes 249 Amorphous pol
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Step-scan FTIR spectroscopy 14,34 -
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