Modern Polymer Spect..

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4.12 Reftrences 235 [ 131 Kuzmany, H.. Mokromol. Chern., iMacronzo/. svriip. 1990, 37, 8 1-97. [14] Harada, I., Furukawa; Y., in: l’ibrcitiorzul Spectiti atid Structure: Durig, J. R. (Ed.). Amsterdam: Elsevier, 1991; Vol. 19, pp. 369-469. [I 5) Gussoni, M., Castiglioni, C., Zerbi, G., in: Athwices in Spectro.mp,v: Clark, R. J. H., Hester, R. E. (Eds.). Chichester: John Wiley & Sons, 1991; Vol. 19, pp. 251-353. [ 161 Bredas, J. L., Silbey. R. (Eds.), Conjirgured Polymers. Netherlands: Kluwer Academic Publishers, 1991. [I71 Tsukamoto, J., Ad;. Ph~,.s. 1992, 41, 509-546. 1181 Su. W. P., Schrieffer, J. R., Heeger. A. J., Phys. Rev. Lett. 1979. 43, 1698-1701. (191 Su, W. P.. Schrieffer, J. R., Heeger, A. J., Phys. Rev. B 1980, 22, 2099-2111. [20] Su, W. P., Schrieffer, J. R., Proc Ntrtl. Actid Sci. 1ISA 1980, 77, 5626-5629. [211 Brazovskii, S. A., Kirova, N. N., Sozi. P/i]’s. JETP Lett. 1981, 33, 4-8. [22J Bishop, A. R., Campbell, D. K., Fesser, K., Mo/. Cr~ist. Liq. Crysl. 1981, 77, 253-264. [23] Bredas, J. L., Chance, R. R., Silbey, R., iMol. Crjvt. Liq. Cryst. 1981, 77, 319-332. [24] Ikehata, S., Kaufer, J., Woerner, T., Pron, A,, Druy, M. A., Sivak, A., Heeger, A. J., Mac- Diarmid, A. G., P/ij.s. Rev. Lett. 1980, 45, 1123-1126. [25] Chung, T.-C., Moraes, F., Flood, J. D., Heeger, A. J., Pliys. Rev. B 1984, 29, 2341-2343. 1261 Park, Y. W., Denenstein, A,, Chiang, C. K., Heeger, A. J., MacDiarinid, A. G., Solid Sttrte CO/~IIIIUTI. 1979, 29, 747-75 1. [27] Tanaka, M., Watanabe, A,, Tanaka, J., Bid. Ckm. Soc. 4117. 1980, 53, 3430-3435. [28] Kume, K., Mizuno, K., Mizoguchi, K., Nomura, K., Maniwa, Y., Moo(. Cryst. Liq. Cryst. 1982, 83, 285-290. [2Y] Moraes, F., Davidov, D., Kobayashi, M., Chung, T. C., Chen, J., Heeger, A. J., Wudl, F., Synth. Met. 1985, 10. 169-179. [30] Kaneto, K., Hayashi, S., Ura, S., Yoshino, K., J. Pl7ys. So(,. Jpn. 1985, 54, 1146-1153. [31] Mizoguclii, K., Misoo, K., Kume, K., Kaneto, K., Shiraishi, T., Yoshino, K., Sjwfh. Met. 1987, 18, 195-198. [32J Logdlund. M., Lazzaroni, R., Stafstrom, S., Salaneck, W. R., Bredas, J. L., Phys. Rev. Lett. 1989, 17, 1841-1844. 1331 Masubuchi, S., Kazania, S., Swzth. Met., 1995, 74, 151-158. [34] Ginder, J. M., Richter, A. F., MacDiarmid, A. G., Epstein, A. J., Solid Store Conimziri. 1987. 63, 97-101. [35] Mizoguchi, K., Obana, T., Ueno, S., and Kume, K., Syiith. Met. 1993, 55, 601-606. [36] Salem, L., The Molecultu Orbitol Tlzcorp of” Co@pted Si1sterir.s. New York: Benjamin, 1966. [37] Kohler, B. E., in: Coi?jtigated Po1yiiier.s: Bredas, J. L. and Silbey, R. (Eds.). Dordrecht: Kluwer Academic Publishers, 1991; pp. 405-434. [38] Fmcher, Jr., C. R., Chen, C.-E., Heeger, A. J., MacDiarniid, A. G., Hasting, J. B., Plzys. Rev. Lett. 1982, 48, 100-104. [39] Yannoni, C. S., Clarke, T. C., Phys. Rev. Lett. 1983, 51, 1191-1193. [40] Villar, H. O., Dupuis, M., Watts, J. D., Hurst, G. J. B., Clementi. E., J. Clzenz. Phys. 1988, 88, 1003-1009. [41] Hirata, S., Torii, H., Tasumi, M., J. Cl7enz. Pliys. 1995, 103, 8964-8979. 1421 Castiglioni, C., Gussoni. M., Zerbi, G., Syntli. Met. 1989, 29, ElLE6. [43] Cuff, L., Kertesz, M., Mocroii7olecuke.s 1994, 27, 762-770. [44] Ohtsuka, H., Master’s Thesis, The University of Tokyo, 1993. [45] Longuet-Higgins, H. C., Salem, L., Proc. Roj~. Soc. A 1959, 251. 172-185. [46] Pople, J. A,, Walmsley. S. H., Mo/. Pliys. 1962, 5, 15-20. [47] Takayama, H., Lin-Liu, Y. R., Maki. K., Plzys. Reo. B 1980, 31, 2388-2393. 1481 Fesser, K,, Bishop, A. R., Campbell, D. K.: Pkys. Reu. B 1983, 27, 4804-4825. 1491 Onodera, Y., Pliys. Rex:. B 1984, 30, 775-785. [50] Zerbi, G., Gussoni, M., Castiglioni, C., in: Copjrgated Pdyrners: Bredas, J. L. and Silbey, R. (Eds.). Dordrecht: Kluwer Academic Publishers, 1991; pp. 435-507. [S 11 Horovitz, B., Solid Stntc. Contmi//7. 1982, 41. 729-734. 1521 Vardeny, Z., Ehrenfreund, E., Brafman, 0.. Horovitz, B., PliI,s. Rea. Lert. 1983.51,23176-2329. [53] Ehrenfreund, E., Vardeny, Z., Brafman, O., Horovitz, B., Pliys. Rev. B 1987, 36, 1535- 1553.
236 4 I’ihratioiznl Spectroscopy of Intact nizd Doped Conjirpted Polj~iiwrs [54] Castiglioni, C., Navarrete, J. T. L., Zerbi. G., Gussoni, M., Solid St~ite Coninirrn. 1988, 65. 625-630. [55] Wilson, E. B., Decius, J. C., Cross, P. C., Molecular Vibra/ions. New York: MacGraw Hill. 1955. [56] Furukawa, Y., Springer Ser. Solid-Stute Sci. 1992, 107, 137-143. [57] Furukawa, Y., Sakanioto, A., Ohta, H.. Tasumi, M., Svnrh. Ale/. 1992, 49, 335-340. [58] Hirschfeld, T., Chase, B., Appl, Spectrosc. 1986, 40, 133-137. (591 Fujiwara. M., Hamaguchi, H., Tasumi, M., Appl. Spectrosc. 1986, 40, 137-139. 1601 Furukawa, Y., Ohta, H.. Sakamoto, A,, Tasumi, M., Spectrochirn. Actrr 1991,474 1367-1373. [hl] Trotter, J.. ilctri Cryst. 1961, 14. 1135-1340. [62] Hargreaves, A,, Rizvi, S. H., Act0 Cryst. 1962, 15, 365-373. [63] Baudour, J. L., Cailleau, H., Yelon, W. B., Acta Cryst. 1977, B33, 1773-1780. [64] Delugeard, Y., Desuche, J., Baudour, J. L., Actci Cribst. 1976, B32, 702-705. [65] Tabata, M., Satoh, M., Kaneto, K., Yoshino, K., J. Phj?,~. Soc. Jpn. 1986, 55, 1305-1310. [66] Satoh, M., Tabata, M., Uesugi, F., Kaneto, K., Yoshino, K., Sj’nth. Met. 1987. 17, 595-600. [67] Gillam, A. E., Hey, D. H., J. Chern. Soc. 1939, 1170-1177. 1681 Dale, J., rlctu Clien?. Scnnd. 1957, 11, 650-659. [69] Balk, P., Hoijtink, G. J., Schreurs, J. W. H., Rec. Trrrv. Chiin. 1957. 76, 813-823. [70] Furukawa. Y., Ohtsuka, H., Tasumi, M., SJnth. Met. 1993, 55, 516-523. [71] Fichou, D., Horowitz, G., Xu, B., Garnier, F., Synth. Met. 1990, 39, 243-259. [72] Furukawa, Y., Yokonuma, N., Tasumi, M., Kuroda. M., Nakayama, J., Mol. C~J’.S/. Lfq. Crysf. 1994, 256, 113-120. [73] Yokonuma, N., Furukawa, Y., Tasumi, M., Kuroda, M., Nakayania, J., C/ie/n. Phys. Lett. Chein. Pliys. Lett. 1996, 255, 431-436. [74] Deussen, M., Bassler, H., Chenz. Phjx 1992, 164, 247-257. [75] Sakamoto, A,, Furukawa, Y., Tasunii, M., J. Phys. Chem. 1994, 98, 4635-4640; J. P/ij,x Chenz. 1997, 101, 1726-1732; Furukawa, Y., Sakamoto, A,, Tasunii, M. Mucrornol. Symp 1996, 101, 95-102. [76] Spangler, C. W., Hall, T. J., Synth. Met. 1991, 44, 85-93. [77] Dewar, M. J. S.,TrinajstiC, N., Czech. Cheni. Cowviitm. 1970, 35. 3136-3189. [78] Zahradnik, R., Carsky, P., J. Phys. Chen7. 1970, 74, 1240-1248. [79] Furukawa, Y., SJint/7. Mct., 1995, 69, 629-632; J. Plrys. Chenz. 1997, 100, 15644-15653. [SO] Shacklette, L. W., Chance, R. R., Ivory, D. M., Miller, G. G., Bauglman, R. H., Spth. Met. 1979. 1, 307-320. [81] Krichene, S., Lefrant, S., Froyer, G., Maurice, F., Pelous, Y., J. Plzys Colloq. 1983, 44, 733- 736. [82] Krichene, S., Buisson, J. P., Lefrant, S., Slvth. Met. 1987, 17, 589-594. [83] Furukawa, Y., Ohtsuka, H., Tasumi. M., Wataru, I., Kanbara, T, Yaniamoto, T., J. Runicin Spectrosc. 1993, 24, 551-554. [84] Ohtsuka, H., Furukawa, Y., Tasumi, M., Wataru, I., Yamanioto, T., unpublished work. [85] Rakovic, D., Bozovic, I., Stepanyan, S. A,, Gribov, L. A,, Solid Stare Commun. 1982, 43, 127-129. [86) Zannoni, G., Zerbi, G., J. Chern. Phys. 1985, 82, 31-38. 1871 Buisson, J. P., Krichene, S., Lefrant, S., Synrh. Met. 1987, 21, 229-234. [88] Ohtsuka, H., Furukawa, Y., Tasumi, M., Spectrochinq. Act0 1993, 49A, 731-737. [89] Tang, J., Albrecht, A. C., in: Rnniaiz Spectroscopy: Szynianski, H. [Ed.). New York: Plenum, 1970; Vol. 2, pp. 33-68. [90] Inagaki, F., Tasumi, M., Miyazawa, T., J. Mol. Spectrosc. 1974, 50, 286-303. [91] Warshel, A., Dauber, P., J. C/ierii. Ph?~s. 1977, 66, 547775488, 1921 Yaniaguchi, S.? Yoshimizu. N., Maeda, S., J. Phys. Clzeni. 1978, 82, 1078-1080. 1931 Peticolas, W. L., Blazej, D. C., Chein. Plzys. Le/t. 1979, 43, 604-608. [94] Kakitani, H., Clienz. Phys. Lett. 1979, 64, 344-347. [95] Cuff, L., Kertestz, M., J. Phys. Chern. 1994, 98, 12223-12231. [96] Takahashi, C., Maeda, S., Clieni. Phys. Lett. 1974, 24, 584-588. [97] Aleksandrov, I. V., Bobovich, Ya. S., Maslov, V. G., Sidorov, A. N., Opt. Spectrosc. 1975. 38, 387-389.
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Modern Polymer Spectroscopy Edited
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Modern Polymer Spectroscopy Edited
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Preface For unfortunate reasons the
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However, theory and calculations yi
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Contents 1 Two-Dimensional Infrared
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Con ten t~ xi Index 5.2 Force Field
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Contributors M. Del Zoppo Dipartime
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1 Two-Dimensional Infrared (2D IR)
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1.2 Brick~qrorrnrl 3 . Figure 1-3.
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1.0 , Figure 1-6. The in-phtrse and
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1.2 Bcrckgroinizd 7 where AA (i~) i
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1.2 Background 9 1.2.5 Two-Dimensio
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1.3 Bnsic Properties of 20 IR Corre
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2D IR spectrometer coupled with a d
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1.5 Applirtrtions 15 Unlike a dispe
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\ '\ Melliyleiie 1'7- -3000 Posiliv
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11 Amorphous Crystalline ,...." I F
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1.5 Applications 21 / I 1430 Figure
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1.5 Appliccitioiis 23 Methylene Fig
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1.5 Ajqdicrrtions 25 3024 Figure 1-
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1.5 Applicutions 27 Furthermore. th
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1.7 Coizclirsions 29 derived in a s
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1.9 References 31 [9] Colthup, N. B
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2 Segmental Mobility of Liquid Crys
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SRMPLE/DETECTOR e3 ‘retardation
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2.4 Srvuc me-Dependenr Alignment 37
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2.5 Electric Field-Innductid Orirnt
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2.5 Electric Field-nclticetl Orient
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a -@ COWER SRHPLE ._ 2.5 Elec tric
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2.5 Electric Field-Itzduced Orienta
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2.5 Electric Field-IwrElrced Orient
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2.5 Electric Field-Im/irced Orientu
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2.5 Electric Field-Induced Orientli
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2.5 Electric Field-Induced Orientat
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2.5 Electric Field-Induced Orienfat
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2.5 Elrc tric Field-Iiidircwl Orim
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2500 2008 I s00 WRVtNdMRtR CM-I Fig
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-3.6 Aligmient OJ' Side- Clinin Liy
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~ polyester 2.6 Alignnient qf Side-
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I." 0.9 0.8 Figure 2-34. FTlR 0.7 p
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induced alignment of the investigat
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2.7 Orientation oj Liquid Ci:i,stal
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2.7 Orieritation of Liquid Ciysttrl
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0 8 18 16 1 a W u z a m a 0 Ln m Q
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2.7 Orientation oj Liquid Crystals
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2.7 Orientation of Liquid Crjvtals
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2.7 Orientatioiz of Liquid Crystals
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2.8 Conclusions 81 strain. As A0 is
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3. I0 Refcreiice.r 83 [I 71 Hoffina
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2.10 References 85 [92] Wiesner, U.
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t Order/Disorder in Chain Molecules
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onds which hold atoms together thro
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3.2 The Dyriamical Case qf Simll ar
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3.2 The Dyrinniical Case of Sinnll
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3.4 S11or.f- and Loizg-Rcrizye Vibr
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3.4 Slzort- and Loiig-Range Vibrati
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eyularity), e.g., 2. During the pol
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3.5 Towards Lnrger Molecules: From
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3.5 TOIIYW~ Laiyer Molertiles: Fvoi
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3.5 Towmu" Larger Molecules: F~om O
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1700 - CIO --- ca c 22 _- c 12 l l
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3.6 From Dynamics to Vibrational Sp
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3.6 Froin Dynaiiiics to T’ihratio
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3.7 The Case of Isotactic Polypropy
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3.7 The Cuse of Isotactic Polypvop.
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3.8 Density of Vibrational States a
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3.8 Dtvz.sit,v of L’ihrntioizal S
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3.8 Driisity of Vibratioiid StLitrs
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3 9 Mouiiiq ToIvmds Rerrlitv: From
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3.9 Moving Towards Reality: From Or
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3.9 Moving Towards Reality: Froin O
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3.10 Wlmt Do We Learn from Cnlcailc
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+ 3.11 A Very Siriiple Ccrse: Latti
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3 I1 A Yey) Siiiiple Case: LLittice
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3.11 A Vq> Siiiiplc Crrw: Luttice D
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Figure 3-22. Sample eigenvectors in
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3.12 CIS-trans Opening @the Double
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3.13 Defect Modes cis Structtrr.al
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3.13 Defect Mo&s cis Structurcil Pr
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0 3.14 Case Studies N 0 d - Y N o m
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3.14 Case Studies 147 OC 60 58 57.
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3.14 Case Studies 149 GI A V E N U
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3.14 Case Studies 15 1 correspond t
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3.14 Case Studies 153 (I10 + 200) +
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3.14 Case Studies 155 1500 1480 146
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3.14 Case Studies 157 the molecular
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17E (ir 1, R): (iii) z = 4, t = 1,
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3.16 Stnictural Znlioi~zogeneity an
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3.1 7 Fermi Resonancrs 163 stants.
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3.1 7 Femi Resorinnces 165 2 L 1 29
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lowing. The CHl-bending mode 6 [cer
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3.17 Ferini Re.sonrriire.s 169 a Fi
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3. I7 Fernii Resoiiances 17 1 terin
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3.18 Band Broadening and Confonnati
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3.18 Bmd Brourleiziriy md Cmforrnat
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3.18 Band Bvoaderiing arid Conjonna
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3.18 Band Broadening and Confornmti
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3.19 A Worked E.utinple 181 pre-mel
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3.19 A Wovh-ecl E.uanzple 183
Page 200 and 201: 3.19 A Worked Example 185 19 5°C 2
Page 202 and 203: 3.19 A Workrd Example 187 Figure 3-
Page 204 and 205: 3.19 A Worked E.rcnniplr 189 LAM I
Page 206 and 207: 3.19 A Worked E.xuniple 191 Figure
Page 208 and 209: 3.19 A Worked E.vnn~yle 193 Figure
Page 210 and 211: 3.19 A Worked E.vnrqde 195 009.1 00
Page 212 and 213: 3.19 A Worked Example 197 existence
Page 214 and 215: 3.1 9 A Worked Example 199 The soli
Page 216 and 217: 3.20 References 201 very important,
Page 218 and 219: 3.20 References 203 [41] M. Gussoni
Page 220 and 221: 3.20 Refeeveiicrs 205 [I 171 P. Jon
Page 222 and 223: 4 Vibrational Spectroscopy of Intac
Page 224 and 225: 4.3 Georrietvy oj Intuct Po1vniev.r
Page 226 and 227: 1'45 4.4 Geometric Chunges I?zditce
Page 228 and 229: 4.4 Geometric Chmges Iiid~lrcecl bj
Page 230 and 231: 4 5 Mer1iodolog.v of Raiii~11 Studi
Page 232 and 233: 4.7 Poly(p-pheiq.lene) 217 with an
Page 234 and 235: 4.7 Pol)~(p-pheiz~~lene) 219 ENERGY
Page 236 and 237: is worthwhile pointing out that the
Page 238 and 239: ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ 801 Table 4-3
Page 240 and 241: 4.7 Poly(y-phenylene) 225 Figure 4-
Page 242 and 243: Table 4-4. Observed Raman frequenci
Page 244 and 245: 4.8 Other Polwieys 229 Table 4-5. T
Page 246 and 247: under various models. According to
Page 248 and 249: 4. I0 Mechnriism oj Charge. Transpo
Page 252 and 253: 4.12 References 237 [98j Matsunuma,
Page 254 and 255: 5 Vibrational Spectroscopy of Polyp
Page 256 and 257: 5.2 FOYCC Fields 241 such calculati
Page 258 and 259: 5.2 Force Fields 243 accounts for o
Page 260 and 261: 5.2 Force Fields 245 centers of the
Page 262 and 263: 5.2 Force Fields 247 ture with conf
Page 264 and 265: 5.3 Amide Modes 249 to the nh initi
Page 266 and 267: 5.3 Ainide Modes 251 Table 5-1. Ami
Page 268 and 269: Table 5-2. Some amide modes of four
Page 270 and 271: 5.3 Amidc Modes 255 Figure 5-1. Opt
Page 272 and 273: 5.4 Polypeptides 257 nonhydrogen-bo
Page 274 and 275: 5.4 Polvpeptida 259 Figure 5-2. Ant
Page 276 and 277: I 5.4 Polypeptides 261 )I .- + $ 80
Page 278 and 279: 1226M 1222s (1 1165W 1167s (1 1120V
Page 280 and 281: 135s 9 1 Ms1i 122Wbr 147 NH ob(37)
Page 282 and 283: 5.4 Polypeptides 267 glycine residu
Page 284 and 285: 5.4 Polypeptides 269 Raman bands in
Page 286 and 287: 5.4 Polypeptides 271 Figure 5-7. St
Page 288 and 289: Frequency (cm-'1 100% b 700 500 300
Page 290 and 291: 5.4 Polypptidt~s 215 Table 5-9. Obs
Page 292 and 293: ~~ ~~ ~~~ ~ ~ ~~ 5.4 Polypeptides 2
Page 294 and 295: 5.4 Poliyeptides 219 Table 5-11. Co
Page 296 and 297: Table 5-12. Aniide mode frequencies
Page 298 and 299: 1351 Lifson, S., Stern, P. S., J. C
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5.6 Refeverices 285 [130] Tiffany,
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Index Amide modes 249 Amorphous pol
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Step-scan FTIR spectroscopy 14,34 -
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