41 st EGAS CP 112 Gdańsk 2009 Theoretical study of the vibrational and electronic structure of the KLi dimer ̷L. Mi¸adowicz 1 , P. Jasik 2,∗ , J.E. Sienkiewicz 2 1 Students’ Scientific Group of Physics, Faculty of Applied Physics and Mathematics, Gdańsk <strong>University</strong> of Technology, ul. Gabriela Narutowicza 11/12, 80-233 Gdańsk, Poland 2 Department of Theoretical Physics and Quantum Information, Faculty of Applied Physics and Mathematics, Gdańsk <strong>University</strong> of Technology, ul. Gabriela Narutowicza 11/12, 80-233 Gdańsk, Poland ∗ Corresponding author: p.jasik@mif.pg.gda.pl, Alkali homo- and heteronuclear dimers have attracted attention of experimentalists and theoreticians for many years. Nowadays, cold molecular physics and chemistry are based mainly on these molecules. We report theoretical study of the vibrational and electronic structure of the KLi dimer. All calculated adiabatic potential energy curves are performed by means of the MOLPRO program package [1]. We present singlet and triplet, Σ, Π and ∆ electronic states, which correlate to ground and several low-lying excited atomic asymptotes. Spectroscopic parameters for all states are also determined. We present comparisons between our results and other theoretical and experimental ones [2-4]. To calculate with very high precision our long range adiabatic potential energy curves of the KLi dimer, we use multiconfigurational self-consistent field/complete active space selfconsistent field (MCSCF/CASSCF) method and multi-reference configuration interaction (MRCI) method. References [1] MOLPRO is a package of ab initio programs written by H.-J. Werner, P.J. Knowles, R. Lindh, F.R. Manby, M. Schütz, P. Celani, T. Korona, A. Mitrushenkov, G. Rauhut, T.B. Adler, R.D. Amos, A. Bernhardsson, A. Berning, D.L. Cooper, M.J.O. Deegan, A.J. Dobbyn, F. Eckert, E. Goll, C. Hampel, G. Hetzer, T. Hrenar, G. Knizia, C. Köppl, Y. Liu, A.W. Lloyd, R.A. Mata, A.J. May, S.J. McNicholas, W. Meyer, M.E. Mura, A. Nicklaß, P. Palmieri, K. Pflüger, R. Pitzer, M. Reiher, U. Schumann, H. Stoll, A.J. Stone, R. Tarroni, T. Thorsteinsson, M. Wang, A. Wolf [2] S. Rousseau, A.R. Allouche, M. Aubert-Frécon, S. Magnier, P. Kowalczyk, W. Jastrzȩbski, Chem. Phys. 247, 193 (1999) [3] H. Salami, A.J. Ross, P. Crozet, W. Jastrzȩbski, P. Kowalczyk, R.J. Le Roy, J. Chem. Phys. 126, 194313 (2007) [4] Z. Jȩdrzejewski-Szmek, D. ̷Lubiński, P. Kowalczyk, W. Jastrzȩbski, Chem. Phys. Lett. 458, 64 (2008) 172
41 st EGAS CP 113 Gdańsk 2009 Angular distributions of atomic photoelectrons ejected by strong laser field A. Bechler ∗ , M. Ślȩczka Institute of Physics, <strong>University</strong> of Szczecin, ul. Wielkopolska 15, 70 - 451 Szczecin, Poland ∗ Corresponding author: adamb@univ.szczecin.pl , We consider a charged particle, initially bound by an atomic potential, which is ejected from an atom by very short and strong laser pulses described in the dipole approximation by the electric field. When the external field is very strong the conventional time dependent perturbation theory cannot be used and no solution of the Time Dependent Schödinger Equation (TDSE) can be found in a closed form without some approximations. In this case, laser-atom interaction can be described by S-matrix formalism [1] and Strong Field Approximation (SFA) where the Coulomb potential is taken into account as a perturbation. We calculate direct ionization amplitude, when the electron does not experience the binding potential, and first correction to this approximation which corresponds to rescattering when the electron, after ionization, back to parent ion and scatters elastically. This calculation has been performed analytically and semi-analytically. We present angular distribution of ejected electron in the tunnelling regime. It can be observed that for the high photon energy the angular distributions show more complicated structure. References [1] H.R. Reiss, Phys. Rev. A 22, 1786-1813 (1980) [2] D.B. Milo˘sević, G.G. Paulus, D. Bauer, W. Becker, J. Phys. B: At. Mol. Opt. Phys. 39, (2006) R203-R262 [3] S. Borbély, K. Tökési, L. Nagy, Phys. Rev. A 77, 033412 (2008) 173