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Chapter 1Introduction and Basic Con
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4-2 Energy Balance for Closed Syste
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7-2 The Increase of Entropy Princip
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Development of Gas TurbinesDeviatio
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ProblemsChapter 13Gas Mixtures13-1
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17-1 Stagnation Properties17-2 Spee
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Appendix 2Property Tables and Chart
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PREFACEBACKGROUNDThermodynamics is
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Preface | xixcoverage of oblique sh
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starts with the simplest case and a
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A CHOICE OF SI ALONE OR SI/ENGLISH
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Chapter 1INTRODUCTION AND BASIC CON
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particles to determine the pressure
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did not find universal acceptance u
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1 J 1 N # m (1-3)Chapter 1 | 7wher
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mN kgs 2andlbf 32.174 ftlbm s 2 C
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devices is best studied by selectin
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diameter) is much larger than the m
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A system is called a simple compres
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time in a periodic manner, and the
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points on a plane, these two measur
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We emphasize that the magnitudes of
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Chapter 1 | 23P gageP vacP atmP atm
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the pressure difference between poi
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Chapter 1 | 27Solution The reading
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Other Pressure Measurement DevicesA
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Chapter 1 | 31EXAMPLE 1-8Measuring
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Chapter 1 | 33Performing the integr
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Keep in mind that the solutions you
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Chapter 1 | 37which is an exact mat
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Chapter 1 | 39SUMMARYIn this chapte
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1-23C What is a steady-flow process
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60 NP atm = 95 kPam P = 4 kgChapter
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unknown density is poured into one
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1-96 The average temperature of the
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Chapter 1 | 491-112E Consider a U-t
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Chapter 2ENERGY, ENERGY TRANSFER, A
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Now if asked to name the energy tra
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Some Physical Insight to Internal E
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uranium-235 atom absorbs a neutron
- Page 84 and 85: gz b E # mech m # e mech m # a P
- Page 86 and 87: A process during which there is no
- Page 88 and 89: Heat and work are directional quant
- Page 90 and 91: Chapter 2 | 65Solution A well-insul
- Page 92 and 93: EXAMPLE 2-7Power Transmission by th
- Page 94 and 95: EXAMPLE 2-8Power Needs of a Car to
- Page 96 and 97: erty is the total energy. Note that
- Page 98 and 99: Chapter 2 | 73of a system during a
- Page 100 and 101: E in E out ¢E systemChapter 2
- Page 102 and 103: Chapter 2 | 777 cents per kWh, dete
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- Page 108 and 109: converted entirely from one mechani
- Page 110 and 111: Chapter 2 | 85Then the rate at whic
- Page 112 and 113: usually grouped as hydrocarbons (HC
- Page 114 and 115: Chapter 2 | 89a certain amount of a
- Page 116 and 117: mechanical energy, and thus electri
- Page 118 and 119: Chapter 2 | 93In solids, heat condu
- Page 120 and 121: Chapter 2 | 95In general, both e an
- Page 122 and 123: The energy flow rate associated wit
- Page 124 and 125: 2-23C What is the caloric theory? W
- Page 126 and 127: this escalator. What would your ans
- Page 128 and 129: espectively. If the pressure rise o
- Page 130 and 131: 700 W/m 2 and the surrounding air t
- Page 132 and 133: The water flow rate through the pum
- Page 136 and 137: Chapter 3PROPERTIES OF PURE SUBSTAN
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Chapter 4ENERGY ANALYSIS OF CLOSED
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Chapter 4 | 167This integral can be
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Chapter 4 | 169EXAMPLE 4-2Boundary
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GASPV n = C = const.P CV n (4-8)Ch
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Chapter 4 | 173Note that the work i
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Chapter 4 | 175P, kPaH 2 Om = 25 gP
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Chapter 4 | 177Assumptions 1 The sy
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do the same as the pressure is main
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Since u and h depend only on temper
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c p c v R1kJ>kg # K2 (4-29)Chapte
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Chapter 4 | 185Analysis We take the
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Chapter 4 | 187P, kPa2 AN 2P = cons
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4-5 INTERNAL ENERGY, ENTHALPY, AND
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Chapter 4 | 191EXAMPLE 4-12Cooling
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Chapter 4 | 193TOPIC OF SPECIAL INT
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Chapter 4 | 19518.0 MJ/kg for carbo
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Chapter 4 | 197will gain weight whe
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Chapter 4 | 199EXAMPLE 4-14 Burning
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The amount of energy needed to rais
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4-22E Hydrogen is contained in a pi
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QH 2 O200 kPa200°CFIGURE P4-38Chap
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4-62 A piston-cylinder device whose
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1.2 in.Furnace, 1300°FBrassplate,
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is done during this process, determ
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0°C and 333.7 kJ/kg, respectively,
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ture), (b) the boundary work, (c) t
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If the initial temperature of the e
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Chapter 5MASS AND ENERGY ANALYSISOF
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differential), but this is not the
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The net flow rate into or out of th
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Chapter 5 | 225Properties We take t
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To push the entire fluid element in
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Chapter 5 | 229EXAMPLE 5-3Energy Tr
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orE # in E # out dE system >dt 0
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5-4 ■ SOME STEADY-FLOW ENGINEERIN
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Chapter 5 | 235Substituting, we get
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Chapter 5 | 237Solution Air is comp
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3 Throttling ValvesThrottling valve
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EXAMPLE 5-9Mixing of Hot and Cold W
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Chapter 5 | 243at 25°C. Neglecting
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The velocities involved in pipe and
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ple, m i 0 if no mass enters the c
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⎫⎪⎬⎪⎭⎫⎪⎬⎪⎭Mass
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Chapter 5 | 251(b) Noting that the
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y the normal and shear components o
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Q # net,in W # shaft,net out d er
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educes to 0.5 in at the nozzle exit
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5-31 Reconsider Prob. 5-30. Using E
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circulating water through the compr
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and 212°F. Air enters at 14.7 psia
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5-103 A long roll of 2-m-wide and 0
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5-122 A rigid, insulated tank that
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5-136 A 0.2-m 3 rigid tank equipped
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about $4 per person per year (ASHRA
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to a final average temperature of 5
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only half of the energy that can po
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more air gets into the cylinder. Co
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Chapter 6THE SECOND LAW OF THERMODY
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Chapter 6 | 281to engineers, and th
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Chapter 6 | 283Energy source(such a
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Can We Save Q out ?In a steam power
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Chapter 6 | 287To supply energy at
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Then the COP relation becomesCOP R
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EXAMPLE 6-3Heat Rejection by a Refr
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Chapter 6 | 293High-temperature res
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Chapter 6 | 295Systemboundary·Q in
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Chapter 6 | 297Expansion Compressio
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and when the process is reversed, t
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heat transfer process. It continues
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while exchanging heat with a single
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Weights and Measures held in 1954,
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Chapter 6 | 307That is, this Carnot
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1COP R Q H >Q L 1 andCOP 1HP 1 Q
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Chapter 6 | 311Solution A heat pump
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Chapter 6 | 313Steel shellSteel or
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Chapter 6 | 315Solution The lightbu
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6-3C Describe an imaginary process
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6-45 Reconsider Prob. 6-44. Using E
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6-76 In tropical climates, the wate
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6-99 A Carnot heat pump is to be us
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it will take for the temperature in
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or decrease the total energy cost o
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(a) If the house loses heat to the
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Chapter 7ENTROPYIn Chap. 6, we intr
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dQ T 0 (7-1)Chapter 7 | 333It appe
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where T 0 is the constant temperatu
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Entropy is an extensive property, a
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Chapter 7 | 339The entropy change f
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Chapter 7 | 341EXAMPLE 7-3Entropy C
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and adiabatic (Fig. 7-14). A proces
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the area under the process curve on
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states of that system, called therm
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organized or low-entropy learning.
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Explicit relations for differential
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Chapter 7 | 353Therefore, the error
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2s 2 s 1 c v 1T2 dT T R v 2ln v
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Chapter 7 | 357P 2 = 600 kPaT 2 = 3
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Variable Specific Heats (Exact Anal
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Chapter 7 | 361Alternative Solution
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give a negative result when work is
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Chapter 7 | 365second T ds relation
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Chapter 7 | 367Isentropic (Pv k co
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Chapter 7 | 369P, kPaP 2 = 900 kPa9
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Isentropic efficiencies are defined
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Isentropic Efficiencies of Compress
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Chapter 7 | 375(b) The required pow
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Chapter 7 | 377or(b) The actual exi
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2dQS heat T Q ka T k(7-72)Chapter
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When evaluating the entropy transfe
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Chapter 7 | 383Analysis We first ta
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Chapter 7 | 385EXAMPLE 7-19Entropy
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Chapter 7 | 387Under the stated ass
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Chapter 7 | 389temperature change s
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Chapter 7 | 391TOPIC OF SPECIAL INT
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Chapter 7 | 393There are many ways
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Chapter 7 | 395The work needed to c
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specifications, on the other hand,
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Chapter 7 | 399much money will be s
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Isentropic process:where P r is the
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7-26 During the isothermal heat add
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7-51E A 1.2-ft 3 well-insulated rig
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Assuming the argon remaining inside
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the kinetic energy change of the st
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enter at 180°C at a rate of 2.2 kg
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opened, and one-half of the total m
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entropy generation during this proc
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7-182 The explosion of a hot water
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the entire system cools to the surr
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350 kW power is produced by the tur
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Chapter 8EXERGY: A MEASURE OF WORK
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Chapter 8 | 425The notion that a sy
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Chapter 8 | 427installed power), th
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Irreversibility can be viewed as th
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Chapter 8 | 431The irreversibility
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Chapter 8 | 433That is, engine A is
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Unlike energy, the value of exergy
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Chapter 8 | 437or, on a unit mass b
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Chapter 8 | 439The exergy content o
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Q1kJ2 Exergy transfer by heat: X he
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Exergy flow associated with a fluid
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orChapter 8 | 445X inXSystemoutX in
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Chapter 8 | 447Analysis We consider
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Chapter 8 | 449determine (a) the ex
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Chapter 8 | 451(d) Noting that the
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Chapter 8 | 453Thus,Integrating, we
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Chapter 8 | 455(c) The wasted work
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Chapter 8 | 457since KE PE 0 and
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Dividing Eq. 8-48 by ṁ gives the
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Chapter 8 | 461Assumptions 1 This i
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Chapter 8 | 463The maximum power ou
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Chapter 8 | 465andW rev,in m 2 f 2
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Chapter 8 | 467Children are born wi
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Chapter 8 | 469The arguments presen
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8-6C Consider a process that involv
- Page 498 and 499:
Now the partition is removed, and t
- Page 500 and 501:
process. Assume the surroundings to
- Page 502 and 503:
300°C. Liquid water enters the mix
- Page 504 and 505:
Chapter 8 | 479Water15°C4.6 kg/sSa
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8-114 A passive solar house that is
- Page 508 and 509:
entire process, including the conve
- Page 510:
Chapter 8 | 485Fundamentals of Engi
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488 | ThermodynamicsPotatoWATER175
- Page 515 and 516:
490 | ThermodynamicsPT2 33FIGURE 9-
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492 | ThermodynamicsTT Hq1 in2T L4
- Page 519 and 520:
494 | ThermodynamicsPMEPW net = MEP
- Page 521 and 522:
496 | ThermodynamicsT21v = const.q
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498 | Thermodynamicsfluid in actual
- Page 525 and 526:
500 | ThermodynamicsSparkplugAir-fu
- Page 527 and 528:
502 | ThermodynamicsP, psia14.7q in
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504 | ThermodynamicsWorking fluidEn
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506 | ThermodynamicsBoth the Stirli
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508 | ThermodynamicsFuelCombustionc
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510 | Thermodynamicsw turbinew comp
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512 | ThermodynamicsT, K130030021q
- Page 539 and 540:
514 | ThermodynamicsT, K13003002s12
- Page 541 and 542:
516 | Thermodynamicsη th,Brayton0.
- Page 543 and 544:
518 | Thermodynamics10Regenerator51
- Page 545 and 546:
520 | ThermodynamicsT 6 1300 K S h
- Page 547 and 548:
522 | ThermodynamicsT3P = const.q i
- Page 549 and 550:
524 | ThermodynamicsProcess 4-5 (is
- Page 551 and 552:
526 | ThermodynamicsFanLow pressure
- Page 553 and 554:
528 | Thermodynamicsexternal to the
- Page 555 and 556:
530 | ThermodynamicsTherefore, the
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532 | ThermodynamicsFIGURE 9-58Aero
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534 | Thermodynamicsthe vehicle’s
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536 | ThermodynamicsFIGURE 9-65Air
- Page 563 and 564:
538 | Thermodynamicsandh T w aw s
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540 | Thermodynamics9-20 An air-sta
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542 | Thermodynamics9-64E An ideal
- Page 569 and 570:
544 | Thermodynamics82 percent for
- Page 571 and 572:
546 | ThermodynamicsDiesel fuel2Com
- Page 573 and 574:
548 | ThermodynamicsThe pressure ra
- Page 575 and 576:
550 | Thermodynamics9-179 An ideal
- Page 577 and 578:
552 | Thermodynamics10-1 ■ THE CA
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554 | ThermodynamicsWater enters th
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w pump,in213 MPa75 kPaPumpBoilerFIG
- Page 584 and 585:
Chapter 10 | 559EXAMPLE 10-2 An Act
- Page 586 and 587:
To take advantage of the increased
- Page 588 and 589:
Chapter 10 | 563(a) This is the ste
- Page 590 and 591:
expansion process takes place in tw
- Page 592 and 593:
Chapter 10 | 567(b) To determine th
- Page 594 and 595:
sure (state 6). Some steam is extra
- Page 596 and 597:
Chapter 10 | 571TurbineBoilerConden
- Page 598 and 599:
Chapter 10 | 573State 3:State 4:P 3
- Page 600 and 601:
Chapter 10 | 575The fractions of st
- Page 602 and 603:
where T b,in and T b,out are the te
- Page 604 and 605:
food processing, and textile indust
- Page 606 and 607:
Cogeneration plants have proved to
- Page 608 and 609:
Chapter 10 | 583E # in E # outorm
- Page 610 and 611:
A 1350-MW combined-cycle power plan
- Page 612 and 613:
Chapter 10 | 5871. A high critical
- Page 614 and 615:
Chapter 10 | 589SUMMARYThe Carnot c
- Page 616 and 617:
10-12C Compare the pressures at the
- Page 618 and 619:
The Reheat Rankine Cycle10-29C How
- Page 620 and 621:
water leaves the heater at the cond
- Page 622 and 623:
and the condenser pressure is 2 psi
- Page 624 and 625:
Review Problems10-87 Show that the
- Page 626 and 627:
pressed liquid at 120°C. The mixtu
- Page 628 and 629:
turbine exit. The net power output
- Page 630:
also by contacting some condenser m
- Page 633 and 634:
608 | ThermodynamicsWARMenvironment
- Page 635 and 636:
610 | ThermodynamicsINTERACTIVETUTO
- Page 637 and 638:
612 | ThermodynamicsP34Q LQ H12W in
- Page 639 and 640:
614 | Thermodynamicsand the turbine
- Page 641 and 642:
616 | ThermodynamicsAnalysis The T-
- Page 643 and 644:
618 | Thermodynamicshalogenated CFC
- Page 645 and 646:
620 | Thermodynamicsa result of thi
- Page 647 and 648:
622 | Thermodynamics(In practice, t
- Page 649 and 650:
624 | ThermodynamicsIn this system,
- Page 651 and 652:
626 | ThermodynamicsKitchen airTQ H
- Page 653 and 654:
628 | ThermodynamicsThis and other
- Page 655 and 656:
630 | ThermodynamicsCOLDrefrigerate
- Page 657 and 658:
632 | ThermodynamicsTo understand t
- Page 659 and 660:
634 | Thermodynamicsdecreasing sour
- Page 661 and 662:
636 | ThermodynamicsHeatrejectedHea
- Page 663 and 664:
638 | Thermodynamicsthe cycle on a
- Page 665 and 666:
640 | Thermodynamicsand 60°C. The
- Page 667 and 668:
642 | Thermodynamics6Gas Refrigerat
- Page 669 and 670:
644 | Thermodynamics11-79C A copper
- Page 671 and 672:
646 | Thermodynamics334°C·Q HCond
- Page 673 and 674:
648 | Thermodynamicsthen cooled to
- Page 676 and 677:
Chapter 12THERMODYNAMIC PROPERTY RE
- Page 678 and 679:
even be replaced by differences, wh
- Page 680 and 681:
Partial Differential RelationsNow l
- Page 682 and 683:
Two of the Gibbs relations were der
- Page 684 and 685:
volume. That is, P sat f (T sat ).
- Page 686 and 687:
Chapter 12 | 661to obtain saturatio
- Page 688 and 689:
Equating the coefficients of dT and
- Page 690 and 691:
An alternative form of this relatio
- Page 692 and 693:
Chapter 12 | 667For an ideal gas P
- Page 694 and 695:
temperature. This presents a proble
- Page 696 and 697:
v ZRT/P and simplifying Eq. 12-56,
- Page 698 and 699:
ors 2 s 1 1s 2 s 1 2 ideal R 1Z
- Page 700 and 701:
For liquid-vapor and solid-vapor ph
- Page 702 and 703:
General Relations for du, dh, ds, c
- Page 704 and 705:
12-80 Reconsider Prob. 12-79. Using
- Page 706 and 707:
Chapter 13GAS MIXTURESUp to this po
- Page 708 and 709:
Chapter 13 | 683EXAMPLE 13-1Mass an
- Page 710 and 711:
Dalton’s and Amagat’s laws can
- Page 712 and 713:
y i b ikka m a a y i a 1>2i b2andb
- Page 714 and 715:
Chapter 13 | 689This is 33 percent
- Page 716 and 717:
where P i,2 y i,2 P m,2 and P i,1
- Page 718 and 719:
dh m T m ds m v m dP m each other
- Page 720 and 721:
Chapter 13 | 695critical temperatur
- Page 722 and 723:
Chapter 13 | 697Discussion This res
- Page 724 and 725:
Chapter 13 | 699ing processes, nega
- Page 726 and 727:
Chapter 13 | 701gory of ideal solut
- Page 728 and 729:
Chapter 13 | 703It can also be expr
- Page 730 and 731:
Chapter 13 | 705water capacity of o
- Page 732 and 733:
Chapter 13 | 707(d ) The osmotic pr
- Page 734 and 735:
Chapter 13 | 709REFERENCES AND SUGG
- Page 736 and 737:
13-42E A rigid tank contains 1 lbmo
- Page 738 and 739:
6.50 percent water vapor, 12.20 per
- Page 740:
13-102 One compartment of an insula
- Page 743 and 744:
718 | ThermodynamicsT, °C50T,°C-1
- Page 745 and 746:
720 | ThermodynamicsAIR25°C,1 atmm
- Page 747 and 748:
722 | ThermodynamicsTT 1T dp2P v =
- Page 749 and 750:
724 | ThermodynamicsThus,Energy bal
- Page 751 and 752:
726 | Thermodynamics(c) The enthalp
- Page 753 and 754:
728 | ThermodynamicsFIGURE 14-17We
- Page 755 and 756:
730 | ThermodynamicsMost air-condit
- Page 757 and 758:
732 | Thermodynamics1 atm, either o
- Page 759 and 760:
734 | ThermodynamicsThen,Water that
- Page 761 and 762:
736 | Thermodynamicsh 1h 3 - h 1ω
- Page 763 and 764:
738 | ThermodynamicsWARMWATERCOOLWA
- Page 765 and 766:
740 | ThermodynamicsThe enthalpy of
- Page 767 and 768:
742 | ThermodynamicsDew-Point, Adia
- Page 769 and 770:
744 | Thermodynamics14-71 Repeat Pr
- Page 771 and 772:
746 | Thermodynamicsat 22°C. Deter
- Page 773 and 774:
748 | Thermodynamics14-123E The U.S
- Page 775 and 776:
750 | ThermodynamicsDesign and Essa
- Page 777 and 778:
752 | ThermodynamicsCRUDEOILGasolin
- Page 779 and 780:
754 | ThermodynamicsReactantsFIGURE
- Page 781 and 782:
756 | Thermodynamicsoxygen, giving
- Page 783 and 784:
758 | ThermodynamicsAssumptions 1 C
- Page 785 and 786:
760 | ThermodynamicsThus,T dp T sa
- Page 787 and 788:
762 | ThermodynamicsATOMMOLECULENuc
- Page 789 and 790:
764 | Thermodynamics1 kmol C25°C,
- Page 791 and 792:
766 | ThermodynamicsEnthalpy at25°
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768 | Thermodynamics1500 K, determi
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770 | Thermodynamics(b) Noting that
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772 | ThermodynamicsAssumptions 1 T
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774 | ThermodynamicsTTs(T,P)∆s =
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776 | ThermodynamicsC77°F, 1 atmO
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778 | Thermodynamics(b) Noting that
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780 | ThermodynamicsThen the total
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782 | ThermodynamicsHybrid power sy
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784 | Thermodynamics15-6C What is t
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786 | Thermodynamicstemperature of
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788 | Thermodynamicsof the surround
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790 | Thermodynamicsthis fuel mixtu
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792 | ThermodynamicsThe entropy cha
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794 | ThermodynamicsCO 2 CO 2COO 2C
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796 | ThermodynamicsH 2 → 2H0.1H
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798 | ThermodynamicsEXAMPLE 16-1Equ
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800 | ThermodynamicsT, K10002000300
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802 | ThermodynamicsAssumptions 1 T
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804 | ThermodynamicsTheny 3 x 0.
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806 | ThermodynamicsSolving Eqs. (1
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808 | ThermodynamicsFIGURE 16-17Wet
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810 | ThermodynamicsT, PNH 3 + H 2
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812 | Thermodynamicsorory A,gas sid
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814 | ThermodynamicsAirEXAMPLE 16-9
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816 | Thermodynamicswhere ∆n n C
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818 | Thermodynamics16-21 Carbon mo
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820 | Thermodynamics16-60C Using th
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822 | Thermodynamics16-102 The equi
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824 | ThermodynamicsFIGURE 17-1Airc
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826 | ThermodynamicsTemperaturerise
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828 | Thermodynamicswhich yieldsdh
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830 | ThermodynamicsAssumptions 1 C
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832 | ThermodynamicsFluidFluidThroa
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834 | ThermodynamicsMa < 1P decreas
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836 | ThermodynamicsEXAMPLE 17-4Cri
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838 | Thermodynamicscritical ratio.
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840 | ThermodynamicsThe critical-pr
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842 | ThermodynamicsFIGURE 17-26Con
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844 | Thermodynamicscrosses the nor
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846 | ThermodynamicsMa 1 > 1FlowV 1
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848 | ThermodynamicsCombining Eqs.
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850 | ThermodynamicsDifferentiating
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852 | ThermodynamicsFIGURE 17-36Sch
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854 | ThermodynamicsT 22 [2 (k 1)
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856 | ThermodynamicsFIGURE 17-43Sti
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858 | ThermodynamicsFIGURE 17-47The
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860 | ThermodynamicsSolution We are
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862 | Thermodynamicsa state functio
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864 | ThermodynamicsTMa 1T maxdT
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866 | ThermodynamicsProperty Relati
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868 | ThermodynamicsQ .EXAMPLE 17-1
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870 | ThermodynamicshWilson line (x
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872 | Thermodynamics(b) The velocit
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874 | ThermodynamicsPROBLEMS*Stagna
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876 | Thermodynamicsvelocities at t
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878 | Thermodynamics17-97C On a T-s
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880 | Thermodynamics17-135 Helium e