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ethanol fuel production and use in kenya for sustainable ... - lumes

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evaporative emissions reacts with hydroxide ions is released (Grosjean, 2001). Brazil reliesheavily on <strong>ethanol</strong> which it <strong>use</strong>s as an additive to gasol<strong>in</strong>e <strong>and</strong> is the only country where<strong>ethanol</strong> is <strong>use</strong>d countrywide as a <strong>fuel</strong> <strong>and</strong> thus its urban air is has higher levels ofacetaldehyde emissions (Grosjean, 2001; Niven, 2004). Human exposure at high levels toacetaldehyde is reported to ca<strong>use</strong> respiratory irritation <strong>and</strong> it is suspected that it could becarc<strong>in</strong>ogenic to humans (Ahmed, 2001). In the environment, a percentage of the acetaldehydeproduced undergoes photochemical reactions to produce peroxyalacetate nitrate (PAN), acompound that <strong>in</strong> some cases could lead to severe lung lesions <strong>and</strong> damage the epithelium ofthe upper part of the respiratory tract <strong>in</strong> humans whereas <strong>in</strong> plants, it is to some extentmutagenic <strong>and</strong> a tox<strong>in</strong> (Ahmed, 2001).In as far as acetaldehyde emissions have negative impacts on both humans <strong>and</strong> theenvironment, when compared to the health <strong>and</strong> environmental damage ca<strong>use</strong>d by thepollutants emitted dur<strong>in</strong>g the combustion of fossil <strong>fuel</strong>s aldehyde emissions are by far lessharmful (Hsieh, 2001; Niven, 2004) In addition, (Niven, 2004) argues that high levels ofaldehydes <strong>for</strong> <strong>in</strong>stance <strong>in</strong> brazil, are not strictly the result of exhaust pipe emissions but morefrom higher evaporative losses that arises from the lack of control on <strong>fuel</strong> Reid VapourPressure (RVP). RVP is a st<strong>and</strong>ard laboratory method which measures the <strong>in</strong>herent tendencyto evaporate <strong>for</strong> <strong>in</strong>stance at 38°C <strong>for</strong> gasol<strong>in</strong>e (Emission Inventory Guidebook, 1999)..Ground water contam<strong>in</strong>ationApart from the <strong>in</strong>crease of aldehydes <strong>in</strong>to the atmosphere by <strong>ethanol</strong>, it is of concern that therisk of soil <strong>and</strong> ground water contam<strong>in</strong>ation is higher when gasol<strong>in</strong>e is blended with <strong>ethanol</strong>(Niven, 2004). This is due to its impact on other compounds <strong>and</strong> on the constituents ofpetroleum constituents (Niven, 2004). For <strong>in</strong>stance the contact of <strong>ethanol</strong> with water leads to areaction that ca<strong>use</strong>s the corrosion of steel <strong>use</strong>d <strong>in</strong> underground storage tanks thereby<strong>in</strong>creas<strong>in</strong>g the risk of leakage to surround<strong>in</strong>g soils (Niven, 2004). Further leakage to soilscomes from gas stations’ underground <strong>fuel</strong> feed l<strong>in</strong>es <strong>and</strong> from the <strong>use</strong> of certa<strong>in</strong> materialsthat corrode when <strong>use</strong>d to store or h<strong>and</strong>le <strong>ethanol</strong>; such material <strong>in</strong>cludes certa<strong>in</strong> metals suchas alum<strong>in</strong>ium <strong>and</strong> z<strong>in</strong>c <strong>and</strong> to some extent non metallic materials such as natural rubber <strong>and</strong>polyv<strong>in</strong>yl chloride which degrade depend<strong>in</strong>g on the percentage of <strong>ethanol</strong> (Niven, 2004). Oncontact with water <strong>ethanol</strong> <strong>in</strong>creases the solubility of gasol<strong>in</strong>e components such as benzene<strong>and</strong> toluene <strong>in</strong> water <strong>and</strong> also makes them non-biodegradable by <strong>in</strong>hibit<strong>in</strong>g theirbiodegradation thereby <strong>in</strong>creas<strong>in</strong>g contam<strong>in</strong>ation of water <strong>and</strong> soils (Niven, 2004; Ahmed,2001). Nevertheless s<strong>in</strong>ce it is known that <strong>ethanol</strong> <strong>use</strong> could <strong>in</strong>crease the risk of groundwater<strong>and</strong> soil contam<strong>in</strong>ation, it is possible to put strict measures that control the construction ofstorage tanks <strong>and</strong> the pipe system (Niven, 2004).Us<strong>in</strong>g <strong>ethanol</strong> could lead to a decl<strong>in</strong>e <strong>in</strong> environmental quality thus reduc<strong>in</strong>g its susta<strong>in</strong>ability.However with better control measures <strong>and</strong> technological improvement it has been noted, theseproblems could be prevented.4.1.2 Economic FactorsCost of EthanolThe major economic disadvantage of <strong>ethanol</strong> is that it is expensive to produce thereby mak<strong>in</strong>git a more expensive <strong>fuel</strong> as compared to petroleum <strong>fuel</strong>s mak<strong>in</strong>g it to depend heavily on18

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