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Coating - Aimcal

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Executive Summaries • A Look Ahead<br />

vacuum Deposition<br />

Considering the general economic gloom, I look back<br />

over the last 12 months and am excited about the<br />

developments that entered the roll-to-roll, vacuumdeposition<br />

marketplace which, I am sure, will provide and<br />

improve products for many years to come.<br />

In metallizing, it has been tough but, even so, the global<br />

consumption of metallized film has increased. Similar to<br />

recent years, India, China, South America and Russia<br />

are higher-growth regions, with north America and<br />

Europe being static or very low growth. Even in areas<br />

with sluggish markets, there are sectors of larger growth.<br />

The biggest of these uses metallizers for the production<br />

of transparent barrier films. The perceived wisdom was<br />

that adding oxygen to aluminum metallizers would create<br />

problems, and it was impossible to produce transparent<br />

aluminum oxide in this way. Years ago, one company<br />

quietly challenged this wisdom, modified a metallizer<br />

and, some years ago, began producing transparent<br />

barrier material. The big change has been that a couple<br />

of machine suppliers have developed systems with a<br />

turnkey process to produce transparent aluminium-oxide<br />

barrier coatings. This year saw the first of these systems<br />

delivering material into the market.<br />

Using an in-vacuum polymer-deposition process, coating<br />

onto the polymer before or after the metallization or both<br />

has gained renewed interest. Previously, the only way of<br />

depositing the polymer was by feeding monomer in from<br />

outside the vacuum system, vaporizing the monomer,<br />

condensing the vapor on the substrate and curing it.<br />

The change this year was the news that one company<br />

simplified the deposition using in-vacuum printing capable<br />

of depositing polymers either pre- or post-deposition of<br />

the aluminum.<br />

104 | 2012 AIMCAL SourceBook<br />

Both of these process developments look to offer plenty<br />

of potential for opening up new markets in the future,<br />

as they both appear to be cost-competitive technology<br />

improvements.<br />

Looking further to the future is the use of atomic layer<br />

deposition for the production of barrier coatings. This<br />

technology is well understood for coating discrete<br />

substrates, and so the chemistry and process is well<br />

developed. Laboratory-scale roll-to-roll systems have<br />

been built with a variety of technological solutions. I would<br />

expect that over the next year these will yield results that<br />

will guide someone to produce a specification for a larger<br />

pilot-production system to be built within the next two<br />

years.<br />

Sputtering or the high added-value coating markets over<br />

the year have appeared somewhat more erratic. What<br />

hit the headlines was the failure of some of the thin-film<br />

photovoltaic companies. The PV market is bound to be<br />

volatile as it is growing so rapidly during a time of global<br />

economic instability. Governments starting and stopping<br />

feed-in tariffs have made this market even less stable.<br />

What it has not changed is the underlying trend that the<br />

PV market continues to grow rapidly. The result has been<br />

that companies that planned for smooth growth have had<br />

to adapt their strategy. Thus expansion is delayed for a<br />

time to react to the dip in growth. This is only a delay, and<br />

substantial growth will return and continue for many years<br />

to come. n<br />

By charles A. Bishop, Ph.D., president, c.A. Bishop<br />

consulting, Ltd., +44-1509-502076, email: cabuk8@<br />

btinternet.com

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