GC COLUMNS | PACKED/MICROPACKED COLUMNSSpecialty Packed ColumnsAromatics AnalysisfreeliteratureResolve Benzeneand Toluene inSpark Ignition FuelsContaining EthanolDownload your freecopy fromwww.restek.comlit. cat.# 580227D3606 Application Column (2 column set)• Complete separation of ethanol and benzene, with a resolution value > 3.00.• Accurate quantification of benzene and toluene.• Fully conditioned two column set—ready to use out of the box.• A chromatogram is provided with each column set demonstrating conformance tothe revised ASTM method.Conforms to the specifications established in ASTM method D3606-07 for the quantitationof benzene and toluene in spark ignition fuel containing ethanol.Description cat.#* priceD3606 Application Column (2 column set)**Column 1: 6' (1.8m), 1 /8" OD, 2.0mm ID, nonpolar Rtx-1Column 2: 16' (4.9m), 1 /8" OD, 2.0mm ID, proprietary packing material 83606-*Please add column instrument configuration suffix number to cat.# when ordering. See page 143.**The column set is designed to accommodate both valve injection and/or syringe injection. Column 1 isconfigured with a 2" inlet void to facilitate on-column injection. The inlet is identified on both column 1 andcolumn 2. Note: The inlet of column 2 is identified for proper orientation for connection to the valve.Gasoline containing ethanol on a D3606 Application Column set.1. ethanol2. benzene3. 2-butanol4. tolueneGC_PC01079Column: D3606 Application Column (2 column set, cat.# 83606-800)Column 1: nonpolar Rtx ® -1, 6' (1.8m), 1 /8" OD, 2.0mm IDColumn 2: proprietary packing material, 16' (4.9m), 1 /8" OD, 2.0mm IDSample: 1.5µL gasoline with internal standardInj.: 200°CBackflush: 3 min.Carrier gas: helium, constant flowFlow rate: 20mL/min.Oven temp.: 135°C, isothermalDet.: TCD @ 200°CChromatogram courtesy of Boguslaw Dudek, Conoco Phillips, Linden, NJ.128 www.restek.comWebsite : www.chromtech.net.au E-mail : info@chromtech.net.au TelNo : 03 9762 2034 . . . in AUSTRALIA Mar 2011
Light Hydrocarbon AnalysisSpecial Columns for Unsaturated Light Hydrocarbons• Faster separations of C1 to C4 hydrocarbons.• Res-Sil® packing replaces Porasil materials.n-Octane on Res-Sil® C Packed ColumnThis packed column has unique selectivity for resolving unsaturatedlight hydrocarbons (Figure 1).OPN on Res-Sil® C Packed ColumnThis column separates the light hydrocarbons, and baselineresolves cis-2-butene from 1,3-butadiene (Figure 2).2abc Refinery Gas Column SetThis 3-column set is finely tuned to resolve light hydrocarbons.When used in the proper valving system, it will elute C5+ hydrocarbonsahead of C1 through C4 hydrocarbons. (Figure 3)Description cat.#* pricen-Octane on Res-Sil C, 80/100 (20', 2.0mm ID,1/8" Silcosmooth OD) 80436-OPN on Res-Sil C, 80/100 (12', 2.0mm ID, 1 /8" Silcosmooth OD) 80437-2abc Refinery Gas Column Set (3 column set)** 88000-*Please add column instrument configuration suffix number to cat.# whenordering. See page 143.**This column set is for a valving system; therefore, packing material is filled toends of <strong>columns</strong>.Figure 1 n-Octane on Res-Sil® C packing has uniqueselectivity for unsaturated light hydrocarbons.142,3 5 78for more info6min. 0 2 4 691011121. methane2. ethane3. ethylene4. acetylene5. propane6. propylene7. isobutane8. n-butane9. 1-butene10. pentane11. isobutylene12. 1,3-butadiene13. 1-pentene14. trans-2-pentene15. cis-2-pentene16. 2-methylbutene-2n-octane 80/100 Res-Sil ® C20', 1 /8" OD x 2mm ID, SilcoSmooth ® tubing (cat. # 80436)Oven temp.: 60°CInj. temp.: 150°CDet. temp: 150°C FIDFlow rate: 30mL/min. HeSample: refinery gas C1-C5Sample size: 20µLSee page 135 for more information on Res-Sil® packing materials.1314158 10 12GC_PC0037216GC COLUMNS | PACKED/MICROPACKED COLUMNSSpecialty Packed ColumnsFigure 2 OPN on Res-Sil® C packing has uniqueselectivity for cis-2-butene and 1,3-butadiene.Retention1 2 4 536789101112Indices1. methane 1002. ethane/ethylene 2003. acetylene 2604. propane 3005. propylene 3216. propadiene 3457. isobutane 3868. butane 4009. 1-butene 42210. isobutylene/trans-2-butene 43411. cis-2-butene 44312. 1,3-butadiene 45413. isopentane 48814. pentane/3-methyl-1-butene 50315. 1-pentene 52216. trans-2-pentene 53317. cis-2-pentene 54018. 2-methyl-2-butene 5491314min. 0 5 10cis-2-butene/1,3-butadieneresolved to baseline15 16 17 18OPN on Res-Sil ® C, 80/100 mesh, 12' x 2mm ID x 1 /8" OD in SilcoSmooth ®tubing (cat.# 80437). 20µL on-column injection of refinery gas.Concentration: 0.1-6 absolute mole %Oven temp.: 50°CInj. & det. temp.: 200°CCarrier gas: heliumFlow rate: 30mL/minReference standard courtesy of AC Analytical Controls, Bensalem, PA.GC_PC00373Figure 3 Refinery gas calibration standard on a Restekrefinery gas packed column set.3,4 5216789101112131415161. C5=C6+2. methane3. ethane4. ethylene5. propane6. acetylene7. propylene8. cyclopropane9. isobutane10. propadiene11. n-butane12. 1-butene13. isobutene14. trans-2-butene15. cis-2-butene16. 1,3-butadiene17. isopentane18. n-pentanemin. 10 20 30 GC_PC003742abc Refinery Gas Column Set (cat.# 88000-875) (3 column set)Oven temp.: 60°CInj. temp.: 150°CDet. temp: 150°C FIDFlow rate: 30mL/min., heliumSample: refinery gasSample size: 1cc1718www.restek.com 129Website : www.chromtech.net.au E-mail : info@chromtech.net.au TelNo : 03 9762 2034 . . . in AUSTRALIA Mar 2011