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analysis of water injection into high-temperature mixture of ...

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68The following is the derivative version <strong>of</strong> the equations modified based onKreiger and Borman [19] which using for determination <strong>of</strong> two-zone <strong>of</strong> burned zoneand <strong>water</strong> <strong>injection</strong> zone to analyze the rate <strong>of</strong> <strong>temperature</strong>, pressure and mass transferbased on equally volume <strong>of</strong> a spark ignition engine. Consider the schematic <strong>of</strong> anengine cylinder while combustion products are occurring in expansion strokeseparating the burned zone and the <strong>water</strong> zone as in figure B-1Q • mWP, V,mbbR , T , ub b bP , V,mWWR , T , uW W WΔQ • b( P + )WP dVbFIGURE B-1 Schematic <strong>of</strong> burned zone and <strong>water</strong> zone model based on equallyvolumeAssumptions:•• •1) Volume,V , in the burned and <strong>water</strong> zones is equal V = VW= V•b2) There is heat transfer between the burned and <strong>water</strong> zones.3) No chemical reactions take place in the <strong>water</strong> zone (zone is said to be frozen)∂xW ∂xW ∂MW ∂RW ∂MW ∂RW ∂uWi.e. = = 0⇒ = = = = = 0 Eq.B-1∂T ∂P ∂T ∂T ∂P ∂P ∂P4) The total cylinder volume and mass is taken up by the burned and <strong>water</strong>volumes and masses only, Determining is defined from Dalton’s law.P= Pb+ PW and m= mb+ m WEq.B-2From Eq.B-2 we can writeW1 W2b2• •mbm −Δ m= m and m −Δ m= m which leads to − mW=Eq.B-3b1The ideal gas law statesPV = mRTEq.B-4From which we can writemRTb b bmWRWTWV = P= bPEq.B-5WDifferentiating Eq.B-4 givesPdV + VdP = mRdT + mTdR + RTdmEq.B-6

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