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Evaluation of Septic Tank and Subsurface Wetland for

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Biological Nitrification Reaction (Crites et al., 1998).<br />

NH4 + +1.731O2 +1.962HCO3 - → 0.038C5H7NO2 +0.962NO3 - +1.077H2O +1.769H2CO3<br />

Biological Denitrification Reaction (Crites et al., 1998).<br />

NO3 - + 1.183CH3OH + 0.273H2CO3 0.091C5H7NO2 + 0.454N2 + 1.820H2O + HCO3 -<br />

→<br />

Biologically nitrifying 1.0 g <strong>of</strong> ammonia nitrogen consumes 7.01 g <strong>of</strong> alkalinity <strong>and</strong><br />

denitrifying 1.0 g <strong>of</strong> nitrate nitrogen produces 3.57 g alkalinity (Crites et al., 1998).<br />

Following the above reactions, if 1.0 g <strong>of</strong> ammonia nitrogen is nitrified then<br />

3.57g CaCO3 0.962g NO3-N 1.0g NO3-N × or 3.43 g <strong>of</strong> alkalinity is produced during denitrification.<br />

The 7.01 g <strong>of</strong> alkalinity consumed in nitrification minus the 3.43 g <strong>of</strong> alkalinity produced<br />

by denitrification yields a net 3.58 grams <strong>of</strong> alkalinity consumed <strong>for</strong> every gram <strong>of</strong><br />

ammonia nitrogen converted to cell tissue <strong>and</strong> nitrogen gas. There<strong>for</strong>e the required mass<br />

ratio <strong>of</strong> alkalinity to ammonia is 3.58:1 assuming all nitrate converts to nitrogen gas. At<br />

Pisgah the 8.1 mg/l alkalinity to 58 mg/l ammonia ratio <strong>of</strong> 0.14:1 is sufficient <strong>for</strong><br />

converting only 2.3 mg/l <strong>of</strong> ammonia. This is based on the assumption that the toilet<br />

flushing water is the sole source <strong>of</strong> alkalinity to the system. The Retrieve wetl<strong>and</strong><br />

influent alkalinity to ammonia ratio <strong>of</strong> 210:5.8 (36:1) is adequate <strong>for</strong> complete<br />

conversion. There<strong>for</strong>e the primary mechanism <strong>for</strong> ammonia removal at Pisgah was not<br />

biological nitrification <strong>and</strong> denitrification but must have been uptake by the wild cane<br />

<strong>and</strong> adsorption by the rock media. Ammonia removal at Retrieve may have been a<br />

combination <strong>of</strong> biological removal, plant uptake <strong>and</strong> perhaps media absorption.<br />

Total Phosphorus<br />

The results <strong>for</strong> the total phosphorus tests are presented in Table 5-7. The average total<br />

phosphorus concentrations in the Pisgah sanitation system were measured to be 12.8 mg/l<br />

entering the septic tanks, 9.6 mg/l entering the wetl<strong>and</strong> <strong>and</strong> 0.4 mg/l at the mid-wetl<strong>and</strong><br />

sample point. The average total phosphorus concentrations in the Retrieve sanitation<br />

47

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