142 Advances in Polymer Science Editorial Board: A. Abe. A.-C ...

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2 B. Charleux, R. Faust 2.2.2.3 2.2.2.4 2.2.2.5 2.3 Poly(isobutylene-b-p-methylstyrene) n . . . . . . . . . . . . . . . . . Poly(isobutylene-b-THF) n . . . . . . . . . . . . . . . . . . . . . . . . Poly(isobutylene-b-methyl methacrylate) n . . . . . . . . . . . . . . Synthesis Using a Multifunctional Coupling Agent . . . . . . . . . 29 29 29 30 2.3.1 2.3.1.1 2.3.1.2 2.3.2 2.3.2.1 2.3.2.2 2.3.3 2.3.3.1 2.3.3.2 An-Type Star Homopolymers . . . . . . . . . . . . . . . . . . . . . . Poly(vinyl ethers) n . . . . . . . . . . . . . . . . . . . . . . . . . . . . Poly(isobutylene) n . . . . . . . . . . . . . . . . . . . . . . . . . . . . (AB) n-Type Star Block Copolymers . . . . . . . . . . . . . . . . . . Poly(vinyl ether-b-vinyl ether) n . . . . . . . . . . . . . . . . . . . . Poly( a-methylstyrene-b-2-hydroxyethyl vinyl ether) n . . . . . . . . AnBm-Type Star Copolymers . . . . . . . . . . . . . . . . . . . . . . Poly(isobutylene) 2-Star-Poly(methyl vinyl ether) 2 . . . . . . . . . . Poly(isobutylene)-Star-Poly(ethylene oxide) m . . . . . . . . . . . . 31 31 34 38 38 38 39 39 40 3 Graft (co)Polymers . . . . . . . . . . . . . . . . . . . . . . . . . . . . 41 3.1 “Grafting From” Technique . . . . . . . . . . . . . . . . . . . . . . . 41 3.1.1 Synthesis of the Backbone by Cationic Polymerization . . . . . . . 41 3.1.1.1 Poly(vinyl ether) Backbone . . . . . . . . . . . . . . . . . . . . . . . 41 3.1.1.2 Poly(isobutylene) Backbone . . . . . . . . . . . . . . . . . . . . . . 41 3.1.2 Synthesis of the Branches by Cationic Polymerization . . . . . . . 42 3.1.2.1 Poly(vinyl ether) Branches . . . . . . . . . . . . . . . . . . . . . . . 42 3.1.2.2 Poly(silyl vinyl ether) Branches . . . . . . . . . . . . . . . . . . . . . 43 3.1.2.3 Poly(isobutylene) Branches . . . . . . . . . . . . . . . . . . . . . . . 43 3.1.2.4 Poly(styrene) and poly( a-methylstyrene) Branches . . . . . . . . . 44 3.2 “Grafting Onto” Technique . . . . . . . . . . . . . . . . . . . . . . . 44 3.2.1 Synthesis of the Backbone by Cationic Polymerization . . . . . . . 45 3.2.1.1 Poly(vinyl ether) Backbone . . . . . . . . . . . . . . . . . . . . . . . 45 3.2.1.2 Poly(p-bromomethylstyrene-IB-p-bromomethylstyrene) Triblock Copolymer Backbone . . . . . . . . . . . . . . . . . . . . . 45 3.2.2 Synthesis of the Branches by Cationic Polymerization: Poly(styrene) Branches . . . . . . . . . . . . . . . . . . . . . . . . . 47 3.3 Macromonomers . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 48 3.3.1 Synthesis of Macromonomers by Living Cationic Polymerization . . . . . . . . . . . . . . . . . . . 48 3.3.1.1 Synthesis Using a Functional Initiator . . . . . . . . . . . . . . . . . 48 3.3.1.2 Synthesis Using a Functional Capping Agent . . . . . . . . . . . . . 53 3.3.1.3 Chain End Modification of Poly(isobutylene) . . . . . . . . . . . . 57 3.3.2 Cationic Polymerization of Macromonomers . . . . . . . . . . . . . 64 3.3.2.1 Vinyl Ether Polymerizable Group . . . . . . . . . . . . . . . . . . . 64 4 Hyperbranched Polymers . . . . . . . . . . . . . . . . . . . . . . . . 65 5 Conclusion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 67 6 References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 67
Synthesis of Branched Polymers by Cationic Polymerization 3 List of Symbols and Abbreviations a-MeS a-methylstyrene AcOVE 2-acetoxyethyl vinyl ether AIBN azobisisobutyronitrile ATMS allyltrimethylsilane BDTEP 2,2-bis[4-(1-tolylethenyl)phenyl]propane BMS bromomethylstyrene BVE n-butyl vinyl ether BzOVE 2-(benzoyloxy)ethyl vinyl ether CA-PIB poly(isobutenyl) a-cyanoacrylate CEVE 2-chloroethyl vinyl ether CMS chloromethylstyrene DIPB diisopropenylbenzene DRI differential refractive index DPn DTBP number-average degree of polymerization 2,6-di-tert-butylpyridine DVB divinylbenzene EO ethylene oxide EPDM ethylene-propylene-diene monomers EVE ethyl vinyl ether f average number of arms Fn HEMA number-average end functionality 2-hydroxyethyl methacrylate HOVE 2-hydroxyethyl vinyl ether IB isobutylene IBVE isobutyl vinyl ether Ieff LCP initiator efficiency living cationic polymerization MA-PIB poly(isobutenyl) methacrylate MeVE methyl vinyl ether MMA methyl methacrylate Mn Mv Mw MW number-average molecular weight viscosity-average molecular weight weight-average molecular weight molecular weight MWD molecular weight distribution ODVE octadecyl vinyl ether p-MeS p-methylstyrene PEO poly(ethylene oxide) PIB poly(isobutylene) PMMA poly(methyl methacrylate) p-MOS p-methoxystyrene PS poly(styrene) S styrene SEC size exclusion chromatography
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Page 3 and 4: Branched Polymers I Volume Editor:
Page 5 and 6: Volume Editor Dr. Jacques Roovers I
Page 7 and 8: Preface While books have been writt
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Synthesis of Branched Polymers by C
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Author Index Volumes 101-142 Author
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Author IndexVolumes 101-142 231 Dun
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Author Index Volumes 101-142 233 Ka
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Author Index Volumes 101-142 237 Su
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Subject Index Addition-fragmentatio
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Subject Index 241 Microphases 11z,
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