142 Advances in Polymer Science Editorial Board: A. Abe. A.-C ...

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140 K. Ito, S. Kawaguchi type star polymers, and block copolymerization of 8 and 15 produced a Janustype or two-faced star polymer. (15) (16a) (16b) Polymerization of ethylene oxide with an acetal-protected alkoxide afforded a-aldehyde-w-methacryloyl PEO macromonomer, 17, after termination with methacrylic anhydride followed by acid hydrolysis [24]. (17) Epoxide-terminated PEO macromonomer, 18 [25], and a mesogen-substituted PEO macromonomer, 19 [26], have been prepared and polymerized to liquid crystalline comb polymers. (18) (19)
Poly(macromonomers), Homo- and Copolymerization 141 3.5 Some Other New Macromonomers Polymerization of hexamethylcyclotrisiloxane with 3-butadienyllithium afforded butadienyl-ended polysiloxane macromonomer, 20 [27]. Polycondensation of a chiral methyl b-hydroxyisobutyrate at a temperature higher than 150 ˚C with Ti(O-nBu) 4 afforded directly a biodegradable polyester macromonomer, 21 [28]. (20) (21) Glycopeptide macromonomers, 22, were prepared from p-vinylbenzylamineinitiated ring-opening polymerization of sugar-substituted a-amino acid N-carboxyanhydrides [29]. They have been copolymerized with acrylamide to afford the corresponding sugar-grafts with molecular recognition ability. 4 Homopolymerization and Copolymerization of Macromonomers (22) Since macromonomers are already polymers with MW between 10 3 and 10 4 , their polymerization and copolymerization involves polymer-polymer reactions. Thus a question of continuing concern has been how and why a macromonomer is different in its reactivity from a corresponding conventional monomer of low MW.
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142 Advances in Polymer Science Edi
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Branched Polymers I Volume Editor:
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Volume Editor Dr. Jacques Roovers I
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Preface While books have been writt
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Contents Synthesis of Branched Poly
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Synthesis of Branched Polymers by C
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72 N. Hadjichristidis, S. Pispas, M
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Dendrimers and Dendrimer-Polymer Hy
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Author Index Volumes 101-142 Author
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Author IndexVolumes 101-142 231 Dun
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Author Index Volumes 101-142 233 Ka
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Author Index Volumes 101-142 235 Og
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Author Index Volumes 101-142 237 Su
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Subject Index Addition-fragmentatio
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Subject Index 241 Microphases 11z,
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142 Advances in Polymer Science Editorial Board: A. Abe. A.-C ...

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