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142 Advances in Polymer Science Editorial Board: A. Abe. A.-C ...

142 Advances in Polymer Science Editorial Board: A. Abe. A.-C ...

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160 K. Ito, S. Kawaguchi<br />

Several other hydrophilic macromonomers <strong>in</strong>clud<strong>in</strong>g 38–44 have been successfully<br />

applied to the dispersion polymerization [117–122]. These macromonomers<br />

were synthesized by radical polymerization <strong>in</strong> the presence of appropriate<br />

cha<strong>in</strong> transfer agents, followed by transformation of the end group, as was<br />

previously summarized [1]. Akashi et al. [121] used PNIPAM macromonomer 42<br />

<strong>in</strong> ethanol and have prepared thermosensitive microspheres 0.4–1.2 µm <strong>in</strong> diameter<br />

consist<strong>in</strong>g of a PSt core and PNIPAM branches on their surface. The particles<br />

are particularly useful for many biomedical applications. Indeed, the particles<br />

have been reported to flocculate with <strong>in</strong>creas<strong>in</strong>g temperature together<br />

with the change <strong>in</strong> the light transmittance.<br />

(38)<br />

(39)<br />

(40)<br />

(41)<br />

(42)

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