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142 Advances in Polymer Science Editorial Board: A. Abe. A.-C ...

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Synthesis of Branched <strong>Polymer</strong>s by Cationic <strong>Polymer</strong>ization 67<br />

5<br />

Conclusion<br />

This review covered recent developments <strong>in</strong> the synthesis of branched (star,<br />

comb, graft, and hyperbranched) polymers by cationic polymerization. It<br />

should be noted that although current examples <strong>in</strong> some areas may be limited,<br />

the general synthetic strategies presented could be extended to other monomers,<br />

<strong>in</strong>itiat<strong>in</strong>g systems etc. Particularly promis<strong>in</strong>g areas to obta<strong>in</strong> materials<br />

formerly unavailable by conventional techniques are heteroarm star-block copolymers<br />

and hyperbranched polymers. Even without further examples the<br />

number and variety of well-def<strong>in</strong>ed branched polymers obta<strong>in</strong>ed by cationic polymerization<br />

should conv<strong>in</strong>ce the reader that cationic polymerization has become<br />

one of the most important methods <strong>in</strong> branched polymer synthesis <strong>in</strong><br />

terms of scope, versatility, and utility.<br />

Acknowledgements. This review could not have been written without support from CNRS<br />

(France) and NSF (USA) (INT-Grant No. 9512834) that made collaboration between the two<br />

laboratories possible.<br />

6<br />

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