SOMMAIRE

J.MAR.CHIM.HETEROCYCL. Volume 1, N° 1 Décembre 2002
Table III. La RMN du 13 C de la benzodiazépine 1 et les composés glucosylés correspondants.
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Partie benzodiazépine Partie sucre
Produit _____________________________________________________________________________________________________________________________________
C-2 C-4 C-3 C-6 C-9 C-7 C-8 C-11 C-10 C-1 C-2 C-3 C-4 C-5 C-6 CMe2 CMe2 OC-1 CH3
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1 a 166.6 166.9 44.5 124.3 124.9 125.0 125.9 136.5 136.7
5a b 166.4 167.2 44.6 123.8 124.2 127.0 127.3 133.9 137.7 105.0 84.9 74.1 81.2 66.6 50.1 111.4 26.1
74.5 81.5 67.2 52.9 111.6 26.8
166.0 166.9 44.4 123.5 124.2 126.5 126.9 134.0 138.0 105.1 81.4 83.8 81.0 66.8 49.6 111.3 26.0 57.9
5b b
105.0 81.3 83.7 53.3 111.5 26.6
5c b 166.6 167.5 44.9 124.1 124.7 127.1 127.5 134.7 138.6 105.5 82.6 83.1 81.4 67.3 50.5 111.9 26.6 71.3 14.5
82.7 81.6 68.2 54.5 112.2 27.2 71.4
8a b 164.6 164.9 44.0 124.4 124.9 125.2 126.2 136.6 136.8 96.7 67.7.1–76.1 51.9, 52.3
91.9, 92.1 48.8, 49.6
8b b 164.6 164.7 44.6 124.4 125.0 126.2 126.2 136.6 136.8 96.7, 85.9 66.9-74.6 51.8, 52.0 59.7-59.8
164.8 164.9 92.0, 92.2 82.8 48.9, 49.4
8c b 167.1 167.3 44.9 124.8 124.8 127.6 127.6 135.3 138.2 97.1 84.1 69.9-74.9 52.0 71.0 14.5
92.4 81.1-82.1 48.5
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a
Dans le CDCl3 + TFA.
b
Dans le CDCl3.
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