26.09.2012 Aufrufe

Beste Agroline Vorprojekt PM7 - CPH Chemie + Papier Holding AG

Beste Agroline Vorprojekt PM7 - CPH Chemie + Papier Holding AG

Beste Agroline Vorprojekt PM7 - CPH Chemie + Papier Holding AG

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also being extended to include countries such as Kazakhstan,<br />

Uzbekistan etc., which are joining this pipeline network.<br />

We have recently heard that Switzerland is buying gas from<br />

Iran. How does this work? The answer is that gas is put<br />

into the pipeline network in Iran, where a series of large<br />

pipelines carries the gas north through Turkey, across<br />

the Balkans, Austria, Germany and Switzerland.<br />

In the Middle East, however, the chosen method of transportation<br />

is to liquefy this gas.<br />

In order to do this, a plant is constructed which purifies the<br />

natural gas to largely methane only and cools this gas down<br />

to around -200°C, when the gas liquefies. It is then pumped<br />

away to storage in massive tanks at a low temperature AND<br />

at a low pressure. The temperature MUST be kept very low<br />

to prevent the pressure building up. If the natural gas were<br />

allowed to warm up to normal temperatures, the pressure<br />

would be up to round 100 barg.<br />

From these large cold tanks the LNG carriers are loaded on<br />

specially built piers; and the ships use gas which boils off to<br />

power the ship’s engines to the destination port in Europe,<br />

North America, Japan or Korea.<br />

Present day feeder terminals are sited in Qatar, Algeria,<br />

Oman, Egypt, Indonesia, Malaysia, Australia and Nigeria.<br />

One of the early steps in the plant to make the LNG is the<br />

purification of the feed gas. This includes dehydration using<br />

molecular sieve and CO2 removal, generally with an amine.<br />

Hence Zeochem molecular sieve plays an important part in<br />

the preparation of the gas for liquefaction. The gas is successively<br />

compressed, cooled, and then recompressed<br />

using a series of chilling cycles. It is like a massive deep<br />

freezer, working down to -200°C.<br />

The Egyptian LNG plant at Idku is on the Mediterranean<br />

coast. It is one of two plants in Egypt, and has been running<br />

successfully with Zeochem molecular sieve for around<br />

three years.<br />

Just recently Zeochem was asked to be present to check<br />

the running of the molecular sieve adsorbers and then to<br />

oversee and inspect the recharge.<br />

Peter Hawes was on-site with Mohamed Fouad from our<br />

Egyptian agents.<br />

Breakthrough testing<br />

In order to check the working of the molecular sieve, an instrument<br />

called a hygrometer is used, which can measure<br />

moisture contents down to fractions of a part per million.<br />

The pictures give a panorama of the site<br />

This instrument must be correctly calibrated before being<br />

connected to the adsorbers on site. Round-the-clock monitoring<br />

ensures that the breakthrough of moisture is seen<br />

immediately, so no moisture passes through into the cryogenic<br />

part of the plant.<br />

Shut-down<br />

Once this test was completed, the plant was shut down for<br />

its three-yearly inspection.<br />

As part of this shut-down, the molecular sieve adsorbers<br />

are emptied, inspected and then refilled with a fresh molecular<br />

sieve. Packing a column with tiny beads and ensuring<br />

that no leaks can occur during the next three years is work<br />

which needs thorough checking.<br />

In this case the work was done by a company from Saudi<br />

Arabia that specialises in changing out adsorbents and catalysts.<br />

Our specialist has to get inside the vessel to inspect<br />

the vessel itself, as well as the completed work.<br />

Cranes then haul the 600 kg big bags up to the top of the<br />

vessel where they are emptied into the clean vessel.<br />

Including inert balls as special protection, there were a total<br />

of six layers of packing in the column. All had to be levelled<br />

off before the next layer was poured into the column.<br />

Zeochem <strong>AG</strong><br />

Peter Hawes

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