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3rd meeting of young researchers at UP 1 - IJUP - Universidade do ...

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Incorpor<strong>at</strong>ion <strong>of</strong> nanocomposites m<strong>at</strong>erials in coverings for<br />

development <strong>of</strong> intumescent paints<br />

S. Rocha 1 , F.D. Magalhães 1,2.3 and J. Pimenta 2,3<br />

1 Department <strong>of</strong> Chemical Engineering, Faculty <strong>of</strong> Engineering, University <strong>of</strong> Porto, Portugal.<br />

2 LEPAE - Department <strong>of</strong> Chemical Engineering, Faculty <strong>of</strong> Engineering, University <strong>of</strong> Porto, Portugal<br />

3 Associ<strong>at</strong>ion Network for Competence in Polymers - Faculty <strong>of</strong> Engineering, University <strong>of</strong> Porto,<br />

Portugal<br />

A paint is a pigmented product (liquid, paste or powder) th<strong>at</strong> when applied in a particular<br />

m<strong>at</strong>erial forms a film with decor<strong>at</strong>ive, protective or other properties, [1]. The intumescent<br />

paints have a specific property: when in contact with high temper<strong>at</strong>ures (above 200 ºC) they<br />

form a carbonaceous foam with a density expansion <strong>of</strong> about forty times, which protects the<br />

substr<strong>at</strong>e from he<strong>at</strong>.<br />

The main objective <strong>of</strong> this work is the development <strong>of</strong> intumescent paints reinforced with<br />

nanosilica in order to increase their he<strong>at</strong> resistance, improving the mechanical strength and the<br />

thickness <strong>of</strong> the intumescent foam.<br />

The first step to make intumescent paints is the prepar<strong>at</strong>ion <strong>of</strong> the nanosilica dispersion in<br />

w<strong>at</strong>er, which is subject to some tests to characterize its quality. Then this dispersion is mixed<br />

with a polymeric emulsion, which constitutes the binder for the paint. Afterward, this emulsion<br />

is combined with the solid components (pigment and reactive additives th<strong>at</strong> will cause the<br />

development <strong>of</strong> the intumescence above a certain temper<strong>at</strong>ure). The final paint is then<br />

characterized to verify the quality <strong>of</strong> the formed carbonaceous foam after he<strong>at</strong> exposure.<br />

In conclusion, combining the properties <strong>of</strong> nanosilica particles with the polymeric emulsion,<br />

the homogeneity and mechanical strength <strong>of</strong> the carbonaceous foam increase. Therefore, it is<br />

possible to delay the raise <strong>of</strong> temper<strong>at</strong>ure in the protected m<strong>at</strong>erial.<br />

References:<br />

[1] Nogueira, J.L.; Noções Básicas de Tintas e Vernizes – Volume I; Colecção ARCP.<br />

3 rd <strong>meeting</strong> <strong>of</strong> <strong>young</strong> <strong>researchers</strong> <strong>at</strong> <strong>UP</strong> 409

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