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3rd meeting of young researchers at UP 1 - IJUP - Universidade do ...

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Incorpor<strong>at</strong>ion <strong>of</strong> a nanostructured m<strong>at</strong>erial into textile substr<strong>at</strong>es for<br />

development <strong>of</strong> high insul<strong>at</strong>ion m<strong>at</strong>erials<br />

L. Almeida 1 , B. Moura 2 , A. Carneiro 2 , M.F.R. Pereira 1<br />

1 Dep. de Engenharia Química, Faculdade de Engenharia, <strong>Universidade</strong> <strong>do</strong> Porto, Portugal.<br />

2 Centro de Nanotecnologia e M<strong>at</strong>eriais Técnicos, Funcionais e Inteligentes (CeNTI),<br />

V. N. Famalicão, Portugal.<br />

Thermal insul<strong>at</strong>ion is a key issue in many different applic<strong>at</strong>ions namely: clothing, construction,<br />

sports, aerospace and automotive. There are two ways <strong>of</strong> obtaining improved thermal<br />

insul<strong>at</strong>ion [1, 2]:<br />

• Increasing the thickness <strong>of</strong> the insul<strong>at</strong>ion, a method which has been used for the last 20<br />

years but which has various disadvantages, for example the loss <strong>of</strong> space, the increase<br />

<strong>of</strong> weight, etc.<br />

• Reducing the thermal conductivity <strong>of</strong> the insul<strong>at</strong>ion m<strong>at</strong>erial.<br />

The aim <strong>of</strong> this work consists in the incorpor<strong>at</strong>ion <strong>of</strong> a nanostructured silica based m<strong>at</strong>erial into<br />

different thin and lightweight textile substr<strong>at</strong>es, to improve their original thermal insul<strong>at</strong>ion<br />

properties. Different incorpor<strong>at</strong>ion procedures were studied and the developed m<strong>at</strong>erials were<br />

characterized by Scanning Electron Microscopy with X-ray Microanalysis (SEM/EDS),<br />

Fourier Transform Infrared Spectroscopy with Attenu<strong>at</strong>ed Total Reflectance (FTIR/ATR) and<br />

thermogravimetry (TG). The thermal resistance was measured by Swe<strong>at</strong>ing Guarded-Hotpl<strong>at</strong>e<br />

method (commonly named Skin Model) in accordance with the standard ISO 11092:1993<br />

[3,4].<br />

The results showed an expressive increase <strong>of</strong> the thermal insul<strong>at</strong>ion properties <strong>of</strong> the tre<strong>at</strong>ed<br />

textile substr<strong>at</strong>es.<br />

Acknowledgments: This work was partially funded by Projecto de Investigação Científica na Pré-<br />

Graduação 2009, U.P. and Santander Totta, and by FCT and FEDER (Portugal) through project<br />

PTDC/CTM/108820/2008.<br />

References:<br />

[1] IEA Energy Conserv<strong>at</strong>ion in Buildings & Community Systems,<br />

http://www.ecbcs.org/annexes/annex39.htm, accessed in January <strong>of</strong> 2010.<br />

[2] Papa<strong>do</strong>poulos, A. M. St<strong>at</strong>e <strong>of</strong> the art in thermal insul<strong>at</strong>ion m<strong>at</strong>erials and aims for future<br />

developments, Energy and Building, 37, 77-86 (2005)<br />

[3] ISO 11092, Textiles - Physiological effects - Measurements <strong>of</strong> thermal and w<strong>at</strong>er-vapour resistance<br />

under steady-st<strong>at</strong>e conditions (Swe<strong>at</strong>ing Guarded-Hotpl<strong>at</strong>e Test), Intern<strong>at</strong>ional Organiz<strong>at</strong>ion for<br />

Standardiz<strong>at</strong>ion, Geneva, 1993.<br />

[4] Moura, B. Desenvolvimento de m<strong>at</strong>eriais com eleva<strong>do</strong> isolamento térmico, Master Thesis,<br />

University <strong>of</strong> Porto, Portugal, 2009.<br />

410 3 rd <strong>meeting</strong> <strong>of</strong> <strong>young</strong> <strong>researchers</strong> <strong>at</strong> <strong>UP</strong>

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