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Volcanoes - Ministry of Civil Defence and Emergency Management

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Vertical deformation in the caldera<br />

volcanoes is monitored using a lake-levelling<br />

technique, in which the whole lake acts as<br />

a level. Nearly 30 years <strong>of</strong> record from Lake<br />

Tarawera <strong>and</strong> Lake Taupo have shown regional<br />

deformation <strong>of</strong> several millimetres per year,<br />

analogous to deep sighing <strong>of</strong> these volcanoes.<br />

CHEMICAL MEASUREMENTS<br />

Volcanic regions emit gases both<br />

during <strong>and</strong> between eruptions, <strong>and</strong> changes in<br />

emission rates <strong>and</strong> chemistry <strong>of</strong> volcanic gases<br />

can help us to predict changes in volcanic<br />

activity. Volcanic gases emit through the<br />

main volcanic conduits to form fumaroles <strong>and</strong><br />

volcanic plumes, <strong>and</strong> also diffuse through soils.<br />

Some components <strong>of</strong> the gas stream react with<br />

groundwater <strong>and</strong> are essentially scrubbed<br />

when passing through crater lakes or shallow<br />

aquifers. Thus, when monitoring the volcano<br />

chemistry, it is important to consider the<br />

different emission pathways, <strong>and</strong> monitor both<br />

the gas <strong>and</strong> fluid phases.<br />

The two most abundant gases emitting<br />

from volcanoes following water vapour are<br />

carbon dioxide (CO 2<br />

) <strong>and</strong> sulphur dioxide<br />

(SO 2<br />

). These two volcanic gases behave<br />

differently in magmas, <strong>and</strong> thus, each gas<br />

provides information about activity at different<br />

depths. Carbon dioxide, for instance, has a<br />

relatively low solubility in magma compared<br />

to sulphur dioxide <strong>and</strong> water vapour. Thus,<br />

as magma starts to move from deep (~35<br />

km) in the crust toward the surface, CO 2<br />

will<br />

become progressively supersaturated in the<br />

magma <strong>and</strong> be released before other gases.<br />

When monitored periodically using airborne<br />

or ground-based techniques, increases in CO 2<br />

emissions will provide the first indication<br />

that there is magma movement at depth. For<br />

example, in 2000 at Usu Volcano in Japan, a<br />

group <strong>of</strong> scientists observed a tenfold increase<br />

over typical background levels in diffuse soil<br />

emissions prior to an eruption. The techniques for<br />

measuring CO 2<br />

through soils <strong>and</strong> in volcanic plumes<br />

have improved dramatically over the last 10 years, <strong>and</strong><br />

are being utilised to provide more insight about the<br />

behaviour <strong>of</strong> CO 2<br />

emissions preceding volcanic eruptions<br />

in New Zeal<strong>and</strong>.<br />

Sulphur dioxide emissions are easy to measure<br />

using remote techniques (COSPEC) from airborne<br />

platforms. SO 2<br />

is released from magmas at shallower<br />

depths <strong>and</strong> can also be used to detect magma movement<br />

toward the surface (within a few km <strong>of</strong> the surface). For<br />

Measuring temperatures at the Mt. Ruapehu Crater Lake. Photo: GNS.<br />

instance, preceding the 1995 eruption <strong>of</strong> Ruapehu there<br />

was an 18% increase in the concentration <strong>of</strong> sulphate<br />

ions in the crater lake over a period <strong>of</strong> 5-6 weeks,<br />

suggesting an increase <strong>of</strong> at least one thous<strong>and</strong> tonnes/<br />

day <strong>of</strong> SO 2<br />

over this time period.<br />

Changes in the ratio <strong>of</strong> gas abundances can also<br />

be used to detect changes within the volcanic system.<br />

Sampling <strong>and</strong> chemical analysis <strong>of</strong> gases from individual<br />

fumaroles as well as crater lakes can provide detailed<br />

information about the trace abundance <strong>of</strong> gases emitting<br />

from the volcano. For example, for the six months prior<br />

to the eruption at Ruapehu in 1995, scientists observed<br />

15<br />

TEPHRA<br />

June 2004

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