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Cadmium Substitution - garteur

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GARTEUR LIMITED<br />

Abstract<br />

A series of commercially produced aluminium and zinc based coatings have been<br />

evaluated as potential replacements for cadmium plating for use on aerospace<br />

components and fasteners manufactured from steel. Coatings examined included<br />

electrodeposited zinc-nickel and zinc-cobalt iron, aluminium coatings produced by ion<br />

vapour deposition and electrodeposition from an organic bath and metallic-ceramic<br />

coatings containing zinc and aluminium flakes. An experimental aluminium - magnesium<br />

coating produced by unbalanced magnetron sputtering was also included in the<br />

programme. Tests have been conducted to establish the corrosion resistance and<br />

tribological properties of the coatings and to compare their resistance to aircraft fluids<br />

with cadmium plating. Studies have been made of the effects of the coatings on fatigue<br />

performance and stress corrosion cracking resistance of a high strength steel. Other<br />

coating properties examined include paint adhesion, electrical conductivity and galvanic<br />

compatibility with aerospace aluminium alloys. The general conclusions are that none of<br />

the coatings examined match the overall performance of cadmium plating. Estimates of<br />

the relative costs of the coatings have been made. An environmental survey has also<br />

been undertaken to compare the potential risks to workers involved in the manufacture<br />

and maintenance of aircraft and to assess their impact on the environment. Areas for<br />

future research are identified.<br />

GARTEUR SM/AG17 TP128<br />

Page v

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