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Cadmium Substitution - garteur

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GARTEUR LIMITED<br />

Type A:<br />

Type B:<br />

electrical resistance across the complete lap joint<br />

electrical resistance between one end of lap joint<br />

and the fastener<br />

The aim of the work was to determine whether a conducting path could be established<br />

through the coated fastener.<br />

B.2.3<br />

Coating adhesion<br />

B.3 Results<br />

A low temperature tensile test method was employed by NLR to determine the adhesion<br />

of the coatings to the steel substrate. Details of the test procedure are given in reference<br />

[B1]. The tensile specimens used in these tests were tapered to give a gradual plastic<br />

strain distribution along the specimen axis as a result of tensile testing. After testing<br />

cross sections provided information on the crack density as a function of increasing<br />

plastic strain.<br />

B.3.1<br />

B.3.1.1<br />

Microstructure and composition<br />

Microstructure<br />

The microstructures of the eight coatings evaluated are shown in figures B2 and B3.<br />

SermeTel CR984/985<br />

The topcoat of the SermeTel CR984/985 is cracked. It can be seen that the SermeTel<br />

coating consists of two layers and the outer layer has been burnished to obtain electrical<br />

conductivity of the coating. The aluminium particles in the inorganic matrix are visible.<br />

The SermeTel coating is not completely dense and shows pores, also along the interface<br />

of the two sprayed layers.<br />

Electrodeposited zinc-cobalt-iron coatings<br />

Figure B2 shows the microstructure of the zinc-cobalt-iron coatings. The passivation<br />

layer is cracked and shows some features, which might originate from the passivation<br />

process. The cross sections show a columnar microstructure without cracks.<br />

Electrodeposited zinc-nickel coatings<br />

Some cracks through the coating down to the steel substrate can be seen. Remnants of<br />

the grit blasting process using alumina lead to subsurface cracks in the steel.<br />

Electrodeposited cadmium coatings<br />

The passivation layer is cracked. The cross sections of non-passivated and passivated<br />

coatings show different microstructure and the thickness of the non-passivated coating is<br />

two to three times the thickness of the passivated coating.<br />

Ion vapour deposited aluminium coatings<br />

Coatings supplied showed the normal porous structure (figure B3) found with ion vapour<br />

deposited coatings. Glass bead peening applied after plating tends to densify the coating<br />

Unbalanced magnetron sputtered aluminium magnesium coatings<br />

The aluminium coatings produced by unbalanced magnetron sputtering are very dense<br />

as indicated by the microgaph in figure B2 obtained using scanning electron microscopy.<br />

Electrodeposited aluminium coatings<br />

On the examination of cross sections using scanning electron microscopy, the electrodeposited<br />

aluminium coatings appear extremely dense as illustrated in figure B3.<br />

Page 48<br />

GARTEUR SM/AG17 TP128

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