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Hexavalent Chromium ATCM for Decorative and Hard Chrome

Hexavalent Chromium ATCM for Decorative and Hard Chrome

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Effective Date: October 24, 2007Appendix 5 - Smoke Test <strong>for</strong> <strong>Chrome</strong> Tank CoversSMOKE TEST TO VERIFY THE SEAL INTEGRITY OF COVERS DESIGNEDTO REDUCE CHROMIUM EMISSIONS FROM ELECTROPLATING ANDANODIZING TANKS1. Applicability <strong>and</strong> Principle2. Applicability. This alternative method is applicable to all hard chromiumelectroplating <strong>and</strong> anodizing operations where a chrome tank cover isused on the tank <strong>for</strong> reducing chromium emissions.3. Principle. During chromium electroplating or anodizing operations,bubbles of hydrogen <strong>and</strong> oxygen gas generated during the processrise to the surface of the tank liquid <strong>and</strong> burst. Upon bursting, tinydroplets of chromic acid (chromium mist) become entrained in the airabove the tank. Because the chrome tank cover completely enclosesthe air above the tank, the chromium mist either falls back into thesolution because of gravity or collects on the inside walls of the chrometank cover <strong>and</strong> runs back into the solution. A semi-permeablemembrane allows passage of the hydrogen <strong>and</strong> oxygen out of thechrome tank cover. A lit smoke device is placed inside the chrome tankcover to detect leaks at the membrane, joints, or seals.4. Apparatus5. Smoke device. Adequate to generate 500 to 1000 ft 3 of smoke/20 ft 2 oftank surface area (e.g., Model #1A=15 SECONDS from SuperiorSignal, New York).6. Small container. To hold the smoke device.7. ProcedurePlace the small container on a stable <strong>and</strong> flat area at center of thechrome tank cover (you can use a board <strong>and</strong> place it on the bussbars). Place the smoke device inside the container. After lighting thesmoke device, quickly close the access door to avoid smoke fromescaping. Let smoke device completely burn; entire space under thechrome tank cover will now be filled with the smoke. Observe <strong>for</strong> leaksof smoke from each seal, joint, <strong>and</strong> membrane of the chrome tankcover. Record these observations including the locations <strong>and</strong> aqualitative assessment of any leaks of smoke.When all seals, joints, <strong>and</strong> membranes have been observed, evacuatethe unit to remove the smoke from the chrome tank cover.51

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