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Thermal Food Processing

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324 <strong>Thermal</strong> <strong>Food</strong> <strong>Processing</strong>: New Technologies and Quality Issues<br />

In Brazil, Garrido and coworkers 132 investigated the presence of M1 and M2<br />

aflatoxins in 60 UHT and 79 pasteurized commercial milk samples collected from<br />

supermarkets. None of the milk samples were found to be contaminated with<br />

aflatoxin M2, but aflatoxin M1 was detected in 29 samples (20.9%) at levels of<br />

50 to 240 ng/l. Occurrence of aflatoxin M1 was high in both commercial pasteurized<br />

and UHT milk. The contamination level, according to MERCOSUR<br />

Technical Regulations, should not be considered a serious public health problem,<br />

even if in some cases it exceeded the limit (50 ng/l) permitted by the EU.<br />

10.5.3 CHEMICAL CONTAMINATION<br />

Environmental contamination caused by human activities (industrial processing,<br />

packaging procedures, accidents during transport, storage before consumption)<br />

can affect milk safety. Chemical pollution, in particular by organic substances<br />

(e.g., polychlorinated biphenyls (PCBs)), is one of the major problems. This is<br />

a well-known concern, and worldwide, quality control structures focus on identifying<br />

hazards and periodically surveying milk all along the supply chain. While<br />

data on chemical contamination of breast milk are abundant in the international<br />

scientific literature, food chain monitoring results are seldom published. This is<br />

unfortunate, as availability of these results would be useful for the whole scientific<br />

community.<br />

Milk and cheeses, collected from Washington, D.C., area retail stores, have<br />

been analyzed for polychlorinated dibenzo-p-dioxin and dibenzofuran contamination.<br />

133 Contaminants were identified and quantified, and expressed in international<br />

toxic equivalent (I-TEQ). Milk contamination ranged from 0.05 to 0.12 I-<br />

TEQ. Similar values have been observed in milk collected in rural areas with no<br />

apparent sources of contamination. 134 In particular, the I-TEQ values found for<br />

the Washington milk samples are higher than the I-TEQ values of German milk. 135<br />

In Italy, Fabietti and coworkers 136 examined 35 commercial milk samples for<br />

the presence of the principal aromatic hydrocarbons (benzene, toluene, ethylbenzene,<br />

xylenes). Milk samples were collected from different dairies and included pasteurized<br />

whole, semiskimmed, and skim milk, and UHT whole and semiskimmed milk.<br />

Levels of the two most common aromatic hydrocarbons (benzene and toluene) were<br />

relatively low (0.12 to 100 µg/kg), while levels of ethylbenzene and total xylenes<br />

(meta + ortho + para) were below the detection limit of 0.05 µg/kg. Benzene and<br />

toluene levels were higher in whole and semiskimmed milk than in skim milk. No<br />

differences were observed between pasteurized and UHT milk with similar fat<br />

contents. Results indicate that levels of aromatic hydrocarbons in commercial milk<br />

in Italy are similar to those found in other foods and are sufficiently low to consider<br />

milk safe from the point of view of chemical contamination. 136<br />

10.6 SENSORY QUALITY<br />

UHT milk, either freshly prepared or stored, has a sensorial characteristic called<br />

cooked note. Stale and oxidized flavors occur due to formation of aldehydes<br />

and ketones.

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