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Thermal Food Processing

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14 <strong>Thermal</strong> <strong>Food</strong> <strong>Processing</strong>: New Technologies and Quality Issues<br />

Equation 1.13 gives a rough estimate of the specific heat above the freezing point<br />

of the product.<br />

An empirical equation for the calculation of c p of some different foods is given as 43<br />

c p = 4187 [x w + (γ + 0.001T)(1 – x w) – β exp(–43x w 2.3 )], (1.14)<br />

where the temperature T is in degrees Centigrade (°C) and the numerical values<br />

of the coefficients in Equation 1.14 for some foods are<br />

γ beef = 0.385, b beef = 0.08<br />

γ white bread = 0.350, b white bread = 0.09<br />

γ sea fish = 0.410, b sea fish = 0.12<br />

γ low-fat cheese = 0.390, b low-fat cheese = 0.10.<br />

If detailed composition data are not available, the following simpler model<br />

can be used: 44<br />

c p = 4190 – 2300x s – 628x s 3 , (1.15)<br />

where x s is the mass fraction of solids, and c p is in Joules per kilogram degrees<br />

Centigrade (J/kg °C).<br />

Gupta 45 developed the following correlation to predict the specific heat of<br />

foods as a function of moisture content and temperature considering 15 types of<br />

foods: 10<br />

c p = 2476.56 + 2356x w – 3.79T, (1.16)<br />

where T is in Kelvin (K), and c p is in Joules per kilogram Kelvin (J/kg K), and<br />

x w ranges from 0.001 to 0.80 and T from 303 to 336 K. Equation 1.16 gives fairly<br />

good values for substances like sugar, wheat flour, starch, dry milk, rice, etc. For<br />

substances containing higher moisture (more than 80%), Equation 1.16 shows<br />

higher deviations from reported values.<br />

The specific heat is related to the dielectric properties and the temperature<br />

increase (∆T) through the following equation: 28<br />

πtf ε ε′ tanδV2<br />

∆T =<br />

,<br />

ρ<br />

2 0<br />

cp (1.17)<br />

where t is the temperature rise time (sec), e 0 is the dielectric constant of free<br />

space, and V, the electric field strength, is equal to voltage/distance between<br />

plates (V/cm). Equation 1.17 shows that the specific heat affects the resulting ∆T.

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