TEXTURAL AND MICROANALYSIS OF IGNEOUS ROCKS: TOOLS ...

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3.5.4 Major Elements Major element compositions measured by EPMA and Ti abundances measured by LA-ICP-MS in plagioclase crystals from each Unit are reported in table 3.3 and illustrated in figure 3.9. 3.5.4.1 Site 1203 Unit 3 I noted variations in An content apparent in backscatter electron images that correlate with zoning patterns. Unit 3 Population A crystal cores fall into two groups in terms of An content. The higher An group (An74−79) overlaps the population B cores (An78−81) (Fig. 3.9a). The cores of population B crystals extend to higher An contents (up to An81) than population A crystals. There is no obvious variation in Mg # (measured in plagioclase) between population A and B crystals or with An content. 3.5.4.2 Site 1203 Unit 14 The cores of population A crystals from Unit 14 also fall into two groups in terms of An content. The more An rich population A group have An77−82 cores that overlap the compositions of population B cores, and the lower An population A group have An64−76 cores. The cores of population B crystals have a higher range of An content (An81−87), but a single population B crystal with a core composition of An73−74 was observed. There is no obvious variation in Mg # (Mg/Mg+total Fe measured in plagioclase) between population A and B crystals or with An content, but a single Unit 14 crystal rim (An56) has the lowest overall Mg # (Fig. 3.9d). 113
3.5.4.3 Site 1203 Unit 31 and Site 884 Unit 8 The cores of population A crystals from Site 1203 Unit 31 define a single An67−77 group. The cores of Site 123 Unit 31 population B crystals are An-rich (An80−86), define a single group of compositions, and do not overlap population A cores. The cores of the two Site 884 Unit 8 population B crystals I examined are An85−86. There is no obvious variation in Mg # (measured in plagioclase) between population A and B crystals or with An content. Of all crystals examined with An82−86 zones, the two Site 884 Unit 8 crystals tend to have the highest Mg #’s (Fig. 3.9d). 3.5.4.4 Ti variations between crystal populations and Units There is a strong negative correlation of Ti abundance with An content that is apparent for crystals from each Site examined, however there seems to be min- imal correlation at An contents greater than ∼ An72 (Fig. 3.9e). In the An80−87 range Unit 3 population B crystals have greater Ti abundances than population B crystals from all other Units examined, and population B crystals from Site 884 Unit 8 have the lowest overall Ti abundance (Fig. 3.9e). 114
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TEXTURAL AND MICROANALYSIS OF IGNEO
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TEXTURAL AND MICROANALYSIS OF IGNEO
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DEDICATION This work is dedicated t
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CHAPTER 2: MAGMA EVOLUTION REVEALED
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3.6.3.1 Crystal Population Origins
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FIGURES 1.1 Magma Chambers . . . .
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TABLES 2.1 MAJOR AND TRACE ELEMENT
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thus been debate within the volcano
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Cambrian schist) including a crysta
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explosive eruption vs. mild effusiv
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tiation (e.g., [84, 98]; Fig. 1.3).
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defined as having crystallinities b
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12 Figure 1.4: Large Igneous Provin
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distribution of crystal sizes (e.g.
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investigating magmatic evolution us
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length dispersive spectroscopy(WDS)
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microdrilling, a pre-cleaned square
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1.7.2 Detroit Seamount, Part of the
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lations. Reprocessing of intrusive
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nucleated homogenously and grew thr
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With accurate partition coefficient
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uniform composition of large volume
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Figure 2.2. Hand sample and thin se
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2.3.1 A Cogenetic Relationship Betw
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Figure 2.4. Stratigraphic section o
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Figure 2.5. Backscatter electron im
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studies of Kwaimbaita basalt by San
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42 Crystal Zone An (mol%) TABLE 2.1
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44 Crystal Zone An (mol%) 63R2 phen
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along the xenolith margins (e.g., F
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are more abundant in phenocrysts fr
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54 Crystal Zone 5 ML-X1 xenolith TA
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56 TABLE 2.2 Continued Crystal Zone
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Page 75 and 76: Figure 2.7. Measured major and trac
Page 77 and 78: 2.5.3.2 Trace Elements It is diffic
Page 79 and 80: Figure 2.9. Trace element ratio plo
Page 81 and 82: 2.5.4 Resorption Features in Site 1
Page 83 and 84: should, however, be noted that in t
Page 85 and 86: 2.6.1.2 An-rich OJP Plagioclase: In
Page 87 and 88: equivocally the roles of H2O, press
Page 89 and 90: ent magma requires significant clin
Page 91 and 92: tion driven plumes, or stirring by
Page 93 and 94: Yamashita, [123], and thus did not
Page 95 and 96: erally extensive crystal-mush netwo
Page 97 and 98: asalt at Site 1185 of ODP Leg 192 [
Page 99 and 100: CHAPTER 3 SHALLOW MAGMA EVOLUTION D
Page 101 and 102: magma compositions [23, 39, 98]. A
Page 103 and 104: Figure 3.2. Stratigraphy of basalts
Page 105 and 106: [118]. No volcaniclastic rocks were
Page 107 and 108: magmatic crystallization. Using the
Page 109 and 110: Figure 3.3. A cross polarized light
Page 111 and 112: 3.4.5 Major and Trace Element Data
Page 113 and 114: 3.4.6.1 Partition coefficients for
Page 115 and 116: 3.5.1.2 Site 884 CSDs I measured pl
Page 117 and 118: Figure 3.5. Plagioclase CSDs of ODP
Page 119 and 120: 106 TABLE 3.2 CSD RESULTS Sample OD
Page 121 and 122: ln (n) [mm -4 ] ln (n) [mm -4 ] 10
Page 123 and 124: ulation A crystals are unzoned (An6
Page 125: Figure 3.8. a) The majority of Site
Page 129 and 130: 3.5.5 Trace Elements 3.5.5.1 Measur
Page 131 and 132: Unit 31 > Site 884 Unit 8 (Table 3.
Page 133 and 134: 3.6 Discussion 3.6.1 Evidence of Cr
Page 135 and 136: 3.6.1.1 Site 1203 Alkalic Basalts a
Page 137 and 138: etween the different crystal popula
Page 139 and 140: Unit 14 and 31 magmas accumulated o
Page 141 and 142: sition is similar to parent magmas
Page 143 and 144: Sr - low La/Ce population A parent
Page 145 and 146: The Unit 31 plagioclase CSD is kink
Page 147 and 148: was dominated by late stage clinopy
Page 149 and 150: pressure, and growth of An-rich pla
Page 151 and 152: 138 TABLE 3.3 PLAGIOCLASE PHENOCRYS
Page 153 and 154: 140 TABLE 3.3 Continued Sample Zone
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164 TABLE 3.4 Continued Sample Zone
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KP has been done via drilling at 11
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and over time crustal wall-rocks be
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flow [33]. I selected a single samp
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4.3.4 Major and Trace Element Data
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B) C) parafilm splash guard A) tape
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of these elements are the better co
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5 mm 5 mm Figure 4.4. Cross polariz
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4.4.2 Electron Probe Microanalysis
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An (mol %) An (mol %) An (mol %) An
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study exhibit their highest An at t
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4.4.3 LA-ICP-MS - Trace Elements An
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87 86 Sr/ SrI = 0.705722(8) Ba/Sr =
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and Rb (Fig. 4.11d,e). 4.4.3.3 Yttr
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Sr (ppm) Y (ppm) La (ppm) Ce (ppm)
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Unit 4 plagioclase rims plagioclase
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204 TABLE 4.4 UNIT 4 PLAGIOCLASE PA
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4.5 Discussion 4.5.0.1 Origin of Ma
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4.5.0.2 Insights from Trace Element
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that other factors influenced the a
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C A/B / D A/B C A/B / D A/B Unit 4
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Magma chambers tend to form at hori
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whole-rock basalt data. Cumulate xe
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over short time spans but may be ea
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lowing initial Elan Bank magma empl
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BIBLIOGRAPHY 1. C. Allegre, A. Prov
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22. B. Charlier, J. Davidson, O. Ba
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46. J. Fitton and M. Godard, Origin
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68. M. Higgins, Measurement of crys
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89. J. Longhi, D. Walker and J. Hay
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100 of Geophysical Monograph, pages
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129. J. Tarduno, W. Sliter, L. Kroe
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