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TEXTURAL AND MICROANALYSIS OF IGNEOUS ROCKS: TOOLS ...

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kbar), high temperature (>1200 ◦ C) crystallization environment favors An-rich<br />

plagioclase growth from known compositions of magmas parental to Kwaimbaita<br />

basalt.<br />

2.6.1.3 An-rich OJP Plagioclase: Influence of Water<br />

Sano and Yamashita [123] invoked a role for water in the genesis of low-MgO,<br />

An-rich OJP plagioclase crystals, which they envisaged to form in a water-rich<br />

(and presumably incompatible trace element-rich) crystal mush layer. Their in-<br />

terpretation is consistent with the hydrous experimental data of Sisson and Grove<br />

[126]. However, while the plagioclase observed by Sisson and Grove [126] grown<br />

in H2O saturated parent magmas were low-MgO and An-rich, the crystals they<br />

observed were more An-rich (generally An90) and lower MgO (< 0.2 wt.% MgO)<br />

than OJP plagioclase crystals (< An90, and > 0.2 wt.% MgO) reported in this<br />

study or by Sano and Yamashita [123] (Table 2.1). Plagioclase data from the<br />

anhydrous experiments of Grove et al. [61] and Bartels et al. [3] produced a neg-<br />

ative correlation of MgO with An content, which was also documented for OJP<br />

plagioclase xenolith crystals and phenocrysts ( [123]; this study; Fig. 2.8). The<br />

experiments of Bartels et al. (1991) were run at 10-20 kbar, and the experiments<br />

of Grove et al. (1982) run at 10-3 kbar. The lower pressure experiments of Grove<br />

et al. [61] produced crystals with MgO and An contents similar to natural OJP<br />

plagioclase observed in this study and by Sano and Yamashita [123]. While I can-<br />

not rule out the influence of H2O, MELTS modeling and previous experimental<br />

studies provide evidence that crystallization of low MgO, An-rich OJP plagioclase<br />

from low pressure, high temperature magmas can account for my observations<br />

without a significant role for H2O. It is, however, impossible to determine un-<br />

73

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