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TEXTURAL AND MICROANALYSIS OF IGNEOUS ROCKS: TOOLS ...

TEXTURAL AND MICROANALYSIS OF IGNEOUS ROCKS: TOOLS ...

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of components needed for later stage clinopyroxene crystallization e.g., [98]. As<br />

clinopyroxene crystallizes the incompatibility of La in clinopyroxene relative to<br />

Y results in relative depletion of Y and enrichment of La, which will yield a<br />

higher La/Y residual liquid (e.g., Table 2.2; Fig. 2.9b-c). Since the trace elements<br />

considered here are highly incompatible in olivine, crystallization of this phase<br />

yields minimal change in the ratios of any of these elements c.f., [6, 7]. Trace<br />

element enrichments and depletions not encountered in whole-rock basalt data<br />

include: 1) An80−86 xenolith and phenocryst zones that were derived from parent<br />

magmas with greater Sr, Y, and Eu, lower La/Y and Ba/Sr, and lower Ba and<br />

LREE abundances extending to overall more primitive compositions than whole-<br />

rock data (Fig. 2.9; Table 2.2). These compositional characteristics suggest that<br />

parent magmas of the An-rich zones experienced less clinopyroxene and plagio-<br />

clase crystallization than lower An zones (Fig. 2.9). The resorption feature in<br />

the Unit 7 xenolith 64R2X-1 provides textural and chemical evidence of exposure<br />

to more primitive magma, where the parent magma of the zone grown after re-<br />

sorption is more An-rich, has lower La/Y, and has greater Sr and Y abundances<br />

(Figs. 2.2b, 2.9, 2.10), and 2) An65−79 phenocryst and xenolith exterior zones with<br />

lower Sr, Y, and Eu, higher La/Y and Ba/Sr, and higher Ba and LREE abun-<br />

dance parental magma compositions that extend to more evolved compositions<br />

than whole-rock data (Figs. 2.9, 2.10). Included in this group are a small number<br />

of phenocrysts, a xenolith exterior zone, and a single resorption feature in the<br />

Unit 6 xenolith that indicate crystallization from magma(s) that had experienced<br />

relatively extreme plagioclase and clinopyroxene fractionation. In Figures 2.9a<br />

and 2.9c vectors for clinopyroxene and plagioclase crystallization are shown as<br />

arrows. Generation of the highest La/Y ratio I observed in a plagioclase par-<br />

75

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