Fugacity: It is derived from Latin, expressed as fleetness or escaping ...
Fugacity: It is derived from Latin, expressed as fleetness or escaping ...
Fugacity: It is derived from Latin, expressed as fleetness or escaping ...
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0<br />
-----(4)<br />
Since the whole system <strong>is</strong> closed it should sat<strong>is</strong>fy the m<strong>as</strong>s conservation equation<br />
dn<br />
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1<br />
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2<br />
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C<br />
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0<br />
----(5)<br />
The variation in number of moles dni <strong>is</strong> independent of each other. However the sum of<br />
change in mole in all the ph<strong>as</strong>es must be zero. F<strong>or</strong> the criterion of equilibrium <strong>is</strong> that the<br />
chemical potential of each component must be equal in all ph<strong>as</strong>es.<br />
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At constant temperature and pressure the general criterion f<strong>or</strong> thermodynamic<br />
equilibrium in closed system f<strong>or</strong> heterogeneous multi component system<br />
At constant T and P<br />
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i <br />
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i<br />
i<br />
f<strong>or</strong> i=1,2,3--------C<br />
Since G RT ln f <br />
i i<br />
i<br />
The above equation <strong>is</strong> also sat<strong>is</strong>fied in terms of fugacity<br />
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i<br />
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f i f i f<strong>or</strong> i=1,2,3--------C<br />
f
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