Fugacity: It is derived from Latin, expressed as fleetness or escaping ...
Fugacity: It is derived from Latin, expressed as fleetness or escaping ...
Fugacity: It is derived from Latin, expressed as fleetness or escaping ...
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The hydration of Ethylene to alcohol <strong>is</strong> given by C2H2 + H2O C2H5OH<br />
Temperature 0 C 145 6.8 x 10 -2<br />
Equilibrium Constant 320 1.9 x 10 -3<br />
The heat capacity data f<strong>or</strong> the component can be<br />
represented by Cp = a + bT where T <strong>is</strong> in kelvin<br />
and Cp <strong>is</strong> in cal / g mol 0 C<br />
Develop general expression f<strong>or</strong> the equilibrium constant and standard Gibb’s free<br />
energy change <strong>as</strong> function of temperature.<br />
<br />
a a a = 6.99(2.83 7.3) 3.14 <br />
Pr oducts Re ac tan ts<br />
<br />
b b b 39.741x10(28.6 10 x 2.46 10) x 8.68 10 x<br />
Pr oducts Re ac tan ts<br />
a b c<br />
I<br />
lnK = ln<br />
R 2R 6R<br />
RT<br />
2<br />
T T T M<br />
3 3 3 3<br />
3<br />
3.14<br />
8.68x10 I<br />
lnK = lnT<br />
T M<br />
2 2x2 2T<br />
3<br />
-2 3.14<br />
8.68x10 I <br />
At 418 K,<br />
ln 6.8x10 = ln 418 418 M <br />
2 2x2 2x418 <br />
Solving,<br />
I = -9655.807 & M = -5.667<br />
3<br />
-3 3.14<br />
8.68x10 I<br />
593 K, ln 1.9x10 ln593 593<br />
At M <br />
2 2x2 2x593 <br />
3<br />
3.14<br />
8.68x10 -9655.807<br />
lnK = lnT<br />
T <br />
-5.667<br />
2 2x2 2T<br />
3<br />
3.14 8.68x10 -9655.807 <br />
But G = -2T lnT T -5.667<br />
2 2x2 2T<br />
<br />
-3 2<br />
G = 3.14T ln T - 4.34x10 T 9655.807 11.334T<br />
Component a bx10 3<br />
C2H4 2.83 28.601<br />
H2O 7.3 2.46<br />
C2H5OH<br />
6.99 39.741
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