Fugacity: It is derived from Latin, expressed as fleetness or escaping ...

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Maximum Tem – Min pressure Azeotropes Calculation of VLE for ideal solution Ideal solution: Ideal solution is one which obeys Raoults law. Raoults law states that the partial pressure is equal to product of vapor pressure and mole fraction in liquid phase. PA PVAx A PA- Partial pressure PVA- Vapor pressure
Page 1 and 2: Fugacity: It is derived from Latin,
Page 3 and 4: II method Using compressibility fac
Page 5 and 6: 50 ln f ln 9. 86 10 1 f=26.7
Page 7 and 8: d ln a R dT P o H H This equa
Page 9 and 10: Measuring of partial molar properti
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Page 13 and 14: Suppose partial molar properties of
Page 15 and 16: G 1 3 2 18x1 35x1 16x1 101 G 102.
Page 17 and 18: For binary solution G x11 x2 2 Ef
Page 19 and 20: i P T , n V i This equation
Page 21 and 22: Modifying equation (a) RT V dP
Page 23 and 24: For non ideal solutions f i i xik
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Page 27 and 28: Phase Equilibrium in single compone
Page 29 and 30: dP dT T Q V V g l Vg>>>Vl (Gas
Page 31 and 32: 1 2 c dn dn dn 1 2 c 1
Page 33 and 34: Effect of pressure on VLE The boili
Page 35: Non ideal solution An ideal solutio
Page 39 and 40: Problem: The binary system acetone
Page 41 and 42: B x ln 1 1 ln 2 1 x2 ln 2 2
Page 43 and 44: When A=B 2 ln Ax , 1 2 ln Ax 2 2
Page 45 and 46: x i dG dx 1 i 0 -----(3) Gi RT ln
Page 47 and 48: dP P x 1 dy y 1 1 x 2 dy y 2 2 y
Page 49 and 50: Problem Verify whether the followin
Page 51 and 52: Heat effects of chemical Reaction:
Page 53 and 54: G G G Re action At equilibriu
Page 55 and 56: For the reasction C2H4 + ½ O2 ↔
Page 57 and 58: Feed contains 50 mole% SO2 and O2.T
Page 59 and 60: 0 o 0 We have G and 0 298 H S S
Page 61 and 62: THERMODYNAMIC FEASIBILITY OF REACTI
Page 63 and 64: HCN is produced by the reaction N2
Page 65 and 66: Δf 0 f (J) ΔG 0 f (J) ΔG 0 298 =
Page 67: x x Y Y x k or 1.3191 = or x =

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