27.12.2013 Views

Etude de la combustion de gaz de synthèse issus d'un processus de ...

Etude de la combustion de gaz de synthèse issus d'un processus de ...

Etude de la combustion de gaz de synthèse issus d'un processus de ...

SHOW MORE
SHOW LESS

You also want an ePaper? Increase the reach of your titles

YUMPU automatically turns print PDFs into web optimized ePapers that Google loves.

Experimental and numerical <strong>la</strong>minar syngas <strong>combustion</strong><br />

A number of other workers (Huang et al., 2004; Hassan et al., 1997; Prathap et al.,<br />

2008; Natarajan et al., 2007) have published <strong>la</strong>minar burning velocity data over a range<br />

of equivalence ratios at 1.0 bar and room temperature for various other H 2 /CO fuels<br />

(with and without excess nitrogen or carbon dioxi<strong>de</strong>), which could bring more insightful<br />

un<strong>de</strong>rstanding of the syngas burning velocity behaviour. The results obtained in these<br />

various studies are compared in Fig.4.24.<br />

2.0<br />

tel-00623090, version 1 - 13 Sep 2011<br />

S 0 u (m/s)<br />

1.8<br />

1.6<br />

1.4<br />

1.2<br />

1.0<br />

0.8<br />

0.6<br />

40H 2 -40CO-20CO 2<br />

28H 2 -25CO-47N 2<br />

50H 2 -50CO<br />

40H 2 -40CO-20N 2<br />

25H 2 -75CO<br />

30H 2 -30CO-40N 2<br />

10H 2 -90CO<br />

5H 2 -95CO<br />

0.4<br />

20H 2 -20CO-60N 2<br />

Downdraft (17H 2 -21CO-13CO 2 -1CH 4 -48N 2 )<br />

0.2<br />

Updraft (11H 2 -24CO-9CO 2 -3CH 4 -53N 2 )<br />

0.0<br />

0.6 0.8 1.0 1.2 1.4 1.6 1.8 2.0<br />

Equivalence ratio<br />

Figure 4.24 - Comparison of <strong>la</strong>minar burning velocity for different fuels: syngas (this work). H 2 -<br />

CO mixtures (Hassan et al., 1997), H 2 -CO-N 2 mixtures (Prathap et al., 2008), 40H 2 -40CO-<br />

20CO 2 (Natarajan et al., 2007) and 28H 2 -25CO-47CO 2 (Huang et al., 2004).<br />

The continuous lines in Fig. 4.24 show the <strong>la</strong>minar burning velocity values for a range<br />

of H 2 /CO mixtures obtained by Hassan et al., (1997); these data clearly show that<br />

increases proportionally with H 2 /CO ratio at any given equivalence ratio.<br />

0<br />

S<br />

u<br />

The dashed lines in Fig. 4.24 show the <strong>la</strong>minar burning velocity values for a range of<br />

H 2 /CO/N 2 mixtures obtained by Prathap et al., (2008); these data clearly show that<br />

<strong>de</strong>creases as dilution by N 2 increases but not proportionally. The reason for this<br />

behaviour is the contribution of nitrogen dilution in reducing the thermal diffusivity and<br />

f<strong>la</strong>me temperature of the mixture. Also a shift to higher equivalence ratios in the<br />

burning velocity peak is observed. By crossing both collections of curves one can say<br />

that the effect of dilution is to reduce the burning velocity and the shift to <strong>la</strong>tter<br />

equivalence ratios of the burning velocity peak is primarily due to the amount of CO in<br />

the mixture.<br />

0<br />

S<br />

u<br />

110

Hooray! Your file is uploaded and ready to be published.

Saved successfully!

Ooh no, something went wrong!