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Etude de la combustion de gaz de synthèse issus d'un processus de ...

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Chapter 4<br />

are tested and discussed. The numerical co<strong>de</strong> <strong>de</strong>scribed above is then used to<br />

estimate the heat flux and quenching distance of syngas-air mixtures.<br />

4.2.3.1 Influence of the heat transfer mo<strong>de</strong>l<br />

In or<strong>de</strong>r to <strong>de</strong>fine the heat transfer mo<strong>de</strong>l to use, one first compare two formu<strong>la</strong>tions<br />

already mentioned above: the c<strong>la</strong>ssical Woschni (1967) corre<strong>la</strong>tion and the recent<br />

Rivère (2005) formu<strong>la</strong>tion. The comparison of both formu<strong>la</strong>tions is ma<strong>de</strong> in the figure<br />

4.39.<br />

tel-00623090, version 1 - 13 Sep 2011<br />

Pressure (bar)<br />

7<br />

6<br />

5<br />

4<br />

3<br />

2<br />

1<br />

0<br />

Experimental P<br />

Woschni P<br />

Rivère P<br />

Woschni Qw<br />

Rivère Qw<br />

0 10 20 30 40 50 60 70 80 90 100<br />

Time (ms)<br />

Figure 4.39 – Influence of the heat transfer mo<strong>de</strong>l – stoichiometric downdraft syngas-air, P=1.0<br />

bar.<br />

From figure 4.39 is possible to conclu<strong>de</strong> that the heat transfer mo<strong>de</strong>l has only marginal<br />

influence on pressure curve. However, the Rivère mo<strong>de</strong>l shows to better follow the<br />

500<br />

400<br />

300<br />

200<br />

100<br />

0<br />

Qw (kW/m 2 )<br />

pressure curve on the cooling si<strong>de</strong>. The reason is the higher value of the heat flux<br />

through the wall using this mo<strong>de</strong>l. This result is in agreement with Boust, (2006), who<br />

compared these mo<strong>de</strong>ls with experimental heat flux values for methane-air mixtures<br />

and conclu<strong>de</strong>d that Rivère mo<strong>de</strong>l is most suitable to simu<strong>la</strong>te the wall-f<strong>la</strong>me heat<br />

transfer and that Woschni mo<strong>de</strong>l is ina<strong>de</strong>quate in the absence of a strong flow. Thus,<br />

Rivère mo<strong>de</strong>l is applied throughout the following results.<br />

4.2.3.2 Influence of equivalence ratio<br />

The influence of the equivalence ratio in the burning velocity and pressure was<br />

experimentally <strong>de</strong>termined for the syngas compositions un<strong>de</strong>r study. It was seen that<br />

the pressure and burning velocity <strong>de</strong>creases when <strong>de</strong>parting from stoichiometric<br />

129

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