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Etude de la combustion de gaz de synthèse issus d'un processus de ...

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Experimental and numerical <strong>la</strong>minar syngas <strong>combustion</strong><br />

this is endorsed to no spherical propagation as shown above by schilieren f<strong>la</strong>me<br />

images.<br />

Tests runs with initial pressures of 0.5, 2.0, 5.0, and in some cases 6.0 bar were also<br />

performed in or<strong>de</strong>r to increase the burning velocity range of pressures. At initial<br />

pressure of 7.0 bar and room temperature (293 K) all typical syngas-air mixtures fail to<br />

ignite.<br />

4.1.2.2 Burning velocity<br />

tel-00623090, version 1 - 13 Sep 2011<br />

Figures 4.29 - 4.31 shows stretched burning velocity for typical syngas-air mixtures for<br />

various equivalence ratios using Eq. (4.14). At this stage all the range of points are<br />

shown to emphasize the inaccuracy of the burning velocity calcu<strong>la</strong>tion due to the<br />

pressure <strong>de</strong>rivative fluctuation in the early stage of f<strong>la</strong>me propagation, where the<br />

pressure does not change to much. After this stage a fast increase in pressure makes<br />

the burning velocity to increase rapidly up to a stable value. Afterwards, a nearly linear<br />

increase in burning velocity is observed. In some cases there is a sud<strong>de</strong>n increase in<br />

burning velocity, which according to Saeed and Stone, (2004) is attributed to the<br />

<strong>de</strong>velopment of cellu<strong>la</strong>r f<strong>la</strong>me. In the final stage burning velocity start to <strong>de</strong>crease due<br />

to inflection in the pressure curve which gives p<strong>la</strong>ce to lower pressure <strong>de</strong>rivatives. The<br />

highest pressure <strong>de</strong>rivative <strong>de</strong>fines the upper limit of the inquiry region.<br />

Workers such as Gül<strong>de</strong>r (1984), Metghalchi and Keck, (1982), and Ryan and Lestz<br />

(1980) who used the constant-volume method for the <strong>de</strong>termination of the burning<br />

velocities have assumed that the f<strong>la</strong>me front is smooth, with no cellu<strong>la</strong>r or wrinkling<br />

f<strong>la</strong>mes. However, cellu<strong>la</strong>r f<strong>la</strong>mes can be formed un<strong>de</strong>r certain conditions, and in the<br />

present study cellu<strong>la</strong>rity was found for syngas f<strong>la</strong>mes. When cellu<strong>la</strong>rity triggers, the<br />

increase in the surface area leads to a sud<strong>de</strong>n increase in the burning velocity and any<br />

inclusion of these data points would lead to higher burning velocity predictions. This is<br />

due to the transformation of the smooth spherical f<strong>la</strong>me front to the polyhedral f<strong>la</strong>me<br />

structures which increase the surface area of the f<strong>la</strong>me front, thereby invalidating the<br />

smooth f<strong>la</strong>me assumption of Eq. (4.14). Therefore, in this work the sud<strong>de</strong>n increase of<br />

burning velocity was removed from the inquiry region.<br />

114

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