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Institute for Sanitary Engineering, Water Quality and Solid Waste ...

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Chair of <strong>Waste</strong> Management <strong>and</strong> Emissions<br />

Monitoring of bentzotriazole in the Stuttgart<br />

water sanitation plant, extended by degradation<br />

experiments of carbamazepine.<br />

The concentrations of 1-H-benzotriazol, 4-methyl-1-<br />

H-benzotriazol <strong>and</strong> 5-methyl-1-H-benzotriazol were<br />

monitored in the Stuttgart water sanitation plant. There<strong>for</strong>e<br />

a new HPLC-MS method was developed in the<br />

labioratories of the L<strong>and</strong>eswasserversorgung in Langenau.<br />

Samples from all five water sanitations plants in Stuttgart<br />

were examiened. The results showed, that 4-methyl-1-H-benzotriazol<br />

is not degraded, while 1-H-benzotriazol<br />

<strong>and</strong> 5-methyl-1-H-benzotriazol is eliminated<br />

up to 70%.<br />

tryptone <strong>and</strong> glucose. Citrate was identified as a suitable<br />

electron donor used by CRM100 during the biological<br />

Cr(VI) reduction achieving the hightest Cr(VI)<br />

reduction (99.7%) within a period of 7 days under 100<br />

mg/L. The results suggested that the isolated strain<br />

CRM100 can be used <strong>for</strong> treating industrial wastewater<br />

containing chromium hexavalent.<br />

Diego Salamanca (WAREM) 2009<br />

Supervisor: Dr. N. Strunk<br />

Master Thesis<br />

In parallel it was tried to enrich a bacterial strain or<br />

community, which mineralize or trans<strong>for</strong>m carbamazepine.<br />

This substrate possesses only a low solubility<br />

in water. Hence, no bacterial strain, which uses carbamazepine<br />

as sole source of carbon <strong>and</strong> energy could<br />

be enriched. But it was possible to identify one strain,<br />

which uses carbamazepine as source of nitrogen.<br />

Ngoc Diep Van (Umweltschutztechnik) 2009<br />

Supervisor: Dr. N. Strunk<br />

Independent Study<br />

The strain CRM100 growth on citrate <strong>and</strong> chromium(VI).<br />

Visible is the production of Cr(III) compounds.<br />

Structure of the substrates<br />

Physiology <strong>and</strong> possible industrial application of<br />

Cr(VI) reduction using biological systems<br />

Treatment of hexavalent chromium contaminated<br />

wastewater<br />

“Treatment of hexavalent chromium contaminated<br />

wastewater”. A Bacterial strain (CRM100) isolated<br />

from a mixture of wastewater <strong>and</strong> soil taken from the<br />

treatment plant <strong>and</strong> boundaries of ISWA department<br />

respectively, was capable to reduce Cr(VI) concentration<br />

from an initial concentration 100 mg/L Cr(VI) to<br />

0.27 mg/L Cr(VI) using citrate as carbon source. Moreover,<br />

experiments were carried out to determine the<br />

growth of bacteria <strong>and</strong> the Cr(VI) reduction in presence<br />

of different carbon sources such as lactate, pyruvate,<br />

citrate, acetate, glycerol, D-xylose, acetone,<br />

The study was conducted to evaluate the biological reduction<br />

of Cr(VI) as a possible treatment in industrial<br />

wastewater. The bacterial strain CRM100 was resistant<br />

to 1800 mg/L Cr(VI) <strong>and</strong> able to reduce 99.8% of 100<br />

mg/L Cr(VI) using citrate as carbon source under anaerobic<br />

conditions. CRM100 reduced 78% of 1000 mg/L<br />

Cr(VI) within a period of 18 days. The biological Cr(VI)<br />

resistance of CRM100 was compared with P. putida.<br />

CRM100 was 180 times more resistant than P. putida.<br />

The growth of P. putida was inhibited by Cr(VI) concentrations<br />

higher than 10 mg/L Cr(VI). The influence<br />

of factors as pH, initial concentration of carbon source<br />

<strong>and</strong> Cr(VI) concentration was evaluated to determine<br />

the optimal reduction process using bacterial strain<br />

CRM100. The biological growth was affected when the<br />

112

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