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Institute for Sanitary Engineering, Water Quality and Solid Waste ...

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Chair of <strong>Waste</strong> Management <strong>and</strong> Emissions<br />

Development of new technologies <strong>for</strong> production<br />

<strong>and</strong> application of plastics from renewable resources.<br />

The annual output of petrochemical plastics of the global<br />

production from crude oil is more than 300 million<br />

tonnes. Plastics are used in numerous applications <strong>for</strong><br />

our daily life. But after their useful life as plastics materials<br />

they will be disposed in l<strong>and</strong>fills, dumpsites, or<br />

delivered to composting plants or to incinerators. The<br />

degradability in general is very slow, in the case of<br />

l<strong>and</strong>fills we are expecting to last hundreds of years. In<br />

incinerators they are used <strong>for</strong> producing energy, but<br />

with this oxidising process plastics from crude oils are<br />

contributing to increasing amounts of the greenhouse<br />

gas carbon dioxide (CO 2<br />

).<br />

Degradability of plastics is known as a non biotic process<br />

with the influence of UV, light <strong>and</strong> oxygen. A second<br />

way <strong>for</strong> degradation is the biological influence<br />

of micro organisms. Also some of the petrochemical<br />

plastics can be biologically degraded, e.g. polyesters.<br />

But also in this case we will have increasing amounts<br />

of the greenhouse gas CO 2<br />

.<br />

Degradability of lignin based bioplastic - Respirometric<br />

Test<br />

There<strong>for</strong>e during the last years new plastics were developed,<br />

plastics from renewable resources <strong>and</strong> biologically<br />

degradable by micro organisms.<br />

Our own project research was done with a very new<br />

degradable plastic from lignin, a by-product in the cellulose<br />

pulping process <strong>for</strong> papermaking .The degradability<br />

of this new product based on lignin was tested<br />

in aerobic conditions with respirometric tests <strong>and</strong> also<br />

in a composting process. The velocity of the degradation<br />

process is depending on the composition of the<br />

plastics. In the respirometric tests we found <strong>for</strong> the<br />

different products a degradation rate of about 30% up<br />

to 80 % in a time of 80 days, using longer testing time,<br />

the degradation rate was increasing up to 50 % up to<br />

100 % in 120 days.<br />

Plastics have an important impact on the environment.<br />

Bioplastics can be produced from renewable raw material<br />

<strong>and</strong> are partially biologically degradable. Currently<br />

the production of bioplastics is relatively low. In the<br />

case of bigger amounts this material should be integrated<br />

in the waste management. The new bioplastics<br />

based on lignin that we have analyzed could be considered<br />

as well degradable in the respirometric tests.<br />

The usability <strong>for</strong> many applications seems to be really<br />

good. As it is a material from renewable resources, the<br />

degradation process will not give any influence to the<br />

greenhouse effect.<br />

Degradability of lignin based bioplastic - Respirometric<br />

Test<br />

Sponsorship:<br />

AIF<br />

Projekt partner:<br />

• Fa. Tecnaro GmbH<br />

• Fa. Bauer Kunststofftechnik<br />

• Institut für Siedlungswasserbau, Wassergüteund<br />

Abfallwirtschaft; Lehrstuhl für Abfallwirtschaft<br />

und Abluft (ISWA, AFW)<br />

Duration:<br />

April 2008 - March 2010<br />

Contact:<br />

Dr.-Ing. Klaus Fischer<br />

Dipl.-Ing. Jingjing Huang<br />

76

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