Chapter 4 - Jacobs University

5.5 Conclusion…………………………………………………………………………….……102
5.6 References…………………………………………………………………………………..103
Chapter 6: Actinide Polyoxometalates: Incorporation of Uranyl-Peroxo in U-Shaped 36-
Tungsto-8-Phosphate 106
6.1 Introduction…………………………………………………………………………………106
6.2 Synthesis……………………………………………………………………………………109
6.3 X-ray crystallography………………………………………………………………………111
6.4 Results and discussion…………………………………………………………………...…113
6.4.1 Synthesis and structure………………………………………………………...…113
6.4.2 Solution NMR………………………………………………………………...…..117
6.5 Conclusion………………………………………………………………………………….119
6.6 References…………………………………………………………………………………..120
Chapter 7: Facile Incorporation of Platinum (IV) into Polyoxometalate Frameworks:
Preparation of [H 2 Pt IV V 9 O 28 ] 5- and 195 Pt NMR 123
7.1 Introduction…………………………………………………………………………………123
7.2 Synthesis................................................................................................................................125
7.3 X-ray crystallography………………………………………………………………………127
7.4 Results and discussion……………………………………………………………………...129
7.4.1 Synthesis and structure…………………………………………………………...129
7.4.2 Solution NMR……………………………………………………………………131
7.5 Conclusion………………………………………………………………………………….135
7.6 References………………………………………………………………………………….136
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