Chapter 4 - Jacobs University

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<strong>Chapter</strong> 9 Unpublished Results Figure 9.29 Top: structure shows combination of polyhedral/ball-stick representation of 16.Color scheme: Y, C, Sb are represented by yellow, blue and green colors respectively. Red polyhedral structure represents one unit of WO 6 & WO 4 (only at center) units. Bottom: structure ball stick structure, Y, C, Sb, W, O are represented by yellow, blue, green, black, red respectively. No hydrogen atoms are shown for clarity. 179
<strong>Chapter</strong> 9 Unpublished Results 9.2.2.3 Solution NMR To complement our solid state XRD results on 16 with solution studies, we performed 1 H, 13 C and 89 Y NMR at room temperature on 16a redissolved in H 2 O/D 2 O. 1 H NMR (Figure 9.30) spectrum exhibits the one signal at 1.76ppm, and 13 C NMR (Figure 9.31) spectrum exhibit two signals 22.1 and 181 ppm and 89 Y NMR (Figure 9.32) spectrum exhibit two signals at 49.0 and 71.0 ppm which are fully consistent with the solid state structure. Figure 9.30 Solution 1 H NMR spectrum of freshly prepared 16a mixture dissolved in H 2 2O/D 2 O. 180
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Synthesis, Structure and Properties
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"The greatest book of philosophy, w
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system, space group I4/m, unit cell
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Acknowledgements The accomplishment
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teaching, and Professor Maravanji S
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2.1.2 Single crystal X-ray diffract
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5.5 Conclusion…………………
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9.1.6.1 Results and discussion…
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9.3.5 Synthesis of K 12 [Hf 4 (µ 2
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Crespo………………………
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Figure 5.4 ORTEP view of the asymme
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Figure 9.6 31 P NMR of 7a in H 2 O/
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Figure 9.34 TGA spectrum of 17a…
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Figure 9.62 FTIR spectrum of 23a…
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Table 9.6 Crystal data and structur
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Chapter 1 Introduction heteropolyan
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Chapter 1 Introduction 1.3 Structur
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Chapter 1 Introduction C) Keggin a-
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Chapter 1 Introduction shows no suc
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Chapter 1 Introduction α-[P 2 W 18
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Chapter 1 Introduction Figure 1.7 B
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Chapter 1 Introduction [P 2 W 18 O
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Chapter 1 Introduction 1.5.3 Medici
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Chapter 1 Introduction (17) Evans,
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Chapter 1 Introduction (48) Mizuno,
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Chapter 1 Introduction (84) Isabell
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Chapter 2 were block-diagonal least
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Chapter 2 Experimental 2.2.3 Synthe
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Chapter 2 Experimental 2.2.7 Synthe
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Chapter 2 Experimental 2.2.11 Synth
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Chapter 2 Experimental 2.3Reference
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Chapter 3 The Wheel-Shaped Cu 20 in
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Chapter 3 The Wheel-Shaped Cu 20 3.
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Chapter 3 The Wheel-Shaped Cu 20 Fi
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Chapter 3 The Wheel-Shaped Cu 20 Cu
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Chapter 3 The Wheel-Shaped Cu 20 20
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Chapter 4 16-Iron Metal Center Nano
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Chapter 5 Organoruthenium POM Chapt
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Chapter 5 Organoruthenium POM 5.2 S
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Chapter 5 Organoruthenium POM 5.3 X
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Chapter 5 Organoruthenium POM 5.4 R
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Chapter 5 Organoruthenium POM The f
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Chapter 5 Organoruthenium POM On th
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Chapter 5 Organoruthenium POM Figur
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Chapter 5 Organoruthenium POM (11)
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Chapter 6 U-peroxo-Polyoxometalate
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Chapter 7 Pt-containing Polyoxometa
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Chapter 7 Pt-containing Polyoxometa
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Chapter 9 Unpublished Results 9.3.7
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Chapter 9 Unpublished Results Table
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Curriculum Vitae SIB SANKAR MAL Dep
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EDUCATION PhD Jacobs University (20
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POSTER, ORAL PRESENTATION 1. Poster
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6. “Two Iron-Containing Tungstoge
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Appendix
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Appendix
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