Chapter 4 - Jacobs University

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<strong>Chapter</strong> 9 Unpublished Results coordination numbers and geometries of three types of Cu are different from each other and the octahedral Cu exhibits Jahn–Teller distortion with axial elongation. We also performed TGA measurements on 6a from room temperature to 900 °C in order to confirm the number of crystal waters (Figure 9.2). Figure 9.3 Polyhedral/ball and stick type structural representation of 6. Color scheme Cu, P and WO 6 units are shown by turquoise, blue and red respectively. 9.1.1.2 Solution NMR We also investigated the solution properties of 6a by 31 P NMR spectroscopy at room temperature in D 2 O (400 MHz; JEOL ECX instrument). We observed a singlet at d = -29.2 ppm indicating that all eight phosphorus atoms in 6a are equivalent, which is in complete agreement with the 143
<strong>Chapter</strong> 9 Unpublished Results solid-state state structure (Figure 9.4). We have not yet obtained a good 183 W NMR spectrum for 6a (expected are three signals of equal intensity), probably due to solubility problems. Figure 9.4 31 P NMR of 6a in H 2 O/D 2 O at room temperature. 144
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Synthesis, Structure and Properties
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"The greatest book of philosophy, w
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system, space group I4/m, unit cell
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Acknowledgements The accomplishment
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teaching, and Professor Maravanji S
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2.1.2 Single crystal X-ray diffract
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5.5 Conclusion…………………
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9.1.6.1 Results and discussion…
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9.3.5 Synthesis of K 12 [Hf 4 (µ 2
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Crespo………………………
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Figure 5.4 ORTEP view of the asymme
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Figure 9.6 31 P NMR of 7a in H 2 O/
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Figure 9.34 TGA spectrum of 17a…
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Figure 9.62 FTIR spectrum of 23a…
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Table 9.6 Crystal data and structur
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Chapter 1 Introduction heteropolyan
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Chapter 1 Introduction 1.3 Structur
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Chapter 1 Introduction C) Keggin a-
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Chapter 1 Introduction shows no suc
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Chapter 1 Introduction α-[P 2 W 18
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Chapter 1 Introduction Figure 1.7 B
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Chapter 1 Introduction [P 2 W 18 O
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Chapter 1 Introduction 1.5.3 Medici
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Chapter 1 Introduction (17) Evans,
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Chapter 1 Introduction (48) Mizuno,
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Chapter 1 Introduction (84) Isabell
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Chapter 2 were block-diagonal least
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Chapter 2 Experimental 2.2.3 Synthe
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Chapter 2 Experimental 2.2.7 Synthe
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Chapter 2 Experimental 2.2.11 Synth
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Chapter 2 Experimental 2.3Reference
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Chapter 3 The Wheel-Shaped Cu 20 in
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Chapter 3 The Wheel-Shaped Cu 20 3.
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Chapter 3 The Wheel-Shaped Cu 20 Fi
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Chapter 3 The Wheel-Shaped Cu 20 Cu
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Chapter 3 The Wheel-Shaped Cu 20 20
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Chapter 4 16-Iron Metal Center Nano
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Chapter 9 Unpublished Results 9.2.4
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Chapter 9 Unpublished Results Table
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Chapter 9 Unpublished Results Table
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Curriculum Vitae SIB SANKAR MAL Dep
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EDUCATION PhD Jacobs University (20
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POSTER, ORAL PRESENTATION 1. Poster
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6. “Two Iron-Containing Tungstoge
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Appendix
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Appendix
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