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FY2010 - Oak Ridge National Laboratory

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Seed Money Fund—<br />

Energy and Transportation Science Division<br />

ENERGY AND TRANSPORTATION SCIENCE DIVISION<br />

05867<br />

Identification and Rapid Screening of New and Unique Plant Sources<br />

for Biofuels<br />

Bruce G. Bunting, Sam L. Lewis, Mike Bunce, and Blake L. Joyce<br />

Project Description<br />

In this project we evaluated a number of nontraditional plants for their ability to produce compounds that<br />

could be used as partial substitution for petroleum-derived fuels, in order to expand biofuels beyond<br />

commonly used ethanol and fatty acid methyl esters. This evaluation included plant selection, acquisition<br />

and characterization of the plant extracts, evaluation of fuel properties and specifications of the extracts,<br />

evaluation of emissions and combustion characteristics of the fuel blends, and generalization of our<br />

evaluation procedures into a recommended practice. This ORNL project has a parallel University of<br />

Tennessee–Knoxville (UTK) funded project in the Plant Sciences Department related to selection of the<br />

plants and obtaining samples of the extracts.<br />

Mission Relevance<br />

The plants discovered and techniques developed could potentially expand the range of biofuel source<br />

material available and could also serve as genetic roadmaps for improving plants to product more fueluseful<br />

extracts. DOE programs that could benefit would be the Office of Biomass (increased and more<br />

diverse supply combined with rapid screening techniques) and the Vehicle Technology Program<br />

(improved understanding of fuel chemistry and property effects). The experimental procedures used for<br />

evaluating the fuels can serve as standard procedures for evaluating new and emerging biofuels.<br />

We have not, as yet, procured follow-on funding. However, the techniques of this research have been<br />

used to support three research proposals: (1) partnering with the University of Georgia and others in the<br />

area of fuels from pyrolysis (did not win), (2) partnering with Johns Hopkins and others in the area of<br />

fuels from pyrolysis (awards not announced yet), and (3) an ORNL proposal to the U.S. Marine Corps to<br />

evaluate the local generation of biofuels in areas of military deployment (pending for 2011). Discussions<br />

were also held with ORNL program management related to matching this research into our DOE Office<br />

of Biomass research portfolio or our Department of Agriculture research portfolio, but no match was<br />

found. UTK is also exploring several funding avenues for continuing this research.<br />

Results and Accomplishments<br />

UTK identified six plants as having potential as biofuel sources and obtained samples. Two of the extracts<br />

were obtained in both a raw and partially refined form, resulting in a total of eight plant extracts. The<br />

plants were (1, 2) Copaifera, “diesel tree,” raw and steam distilled; (3) Aleurites moluccana, “kukui” or<br />

“candlenut”; (4, 5) Pittosporum resiniferum, “petroleum nut,” raw and cold stabilized; (6) Cymbopogon<br />

203

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