Jozef Hodyl PhD Thesis - Theses - Flinders University

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81. P. A. Gale, ed., The Encyclopaedia of Supramolecular Chemistry,Dekker, New York, 2004.82. S. I. Kondo, Y. Hiraoka, N. Kurumatani and Y. Yano, Chem. Commun.,2005, 1720-1722.83. M. A. Hossain, S. O. Kang, D. Powell and K. Bowman-James, Inorg.Chem., 2003, 42, 1397-1399.84. T. Zielinski and J. J. P. Dydio, Tetrahedron, 2008, 64, 568-574.85. F. Troisi, A. Russo, C. Gaeta, G. Bifulco and P. Neri, Tetrahedron Lett.,2007, 48, 7986-7989.86. S. J. Brooks, S. E. Garcia-Garrido, M. E. Light, P. A. Cole and P. A.Gale, Chem. Eur. J., 2007, 13, 3320-3329.87. R. Martinez-Manez and F. Sancenon, Chem. Rev., 2003, 103, 4419-4476.88. H. J. Kim, S. K. Kim, J. Y. Lee and J. S. Kim, J. Org. Chem., 2006, 71,6611-6614.89. P. S. Vermersch, D. D. Lemon, J. J. G. Tesmer and F. A Quiocho,Biochemistry, 1991, 30, 6861-6866.90. D. K. Smith, Org. Biomol. Chem., 2003, 1, 3874-3877.91. S. Ghosh, A. R. Choudhury, T. N. G. Row and U. Maitra, Org. Lett.,2005, 7, 1441-1444.92. M. Staffilani, K. S. B.Hancock, J. W. Steed, K. T. Holman, J. L.Atwood, R. K. Juneja and R. S. Burkhalter, J. Am. Chem. Soc., 1997,119, 6324-6335.170
93. C. B. Smith, A. K. W. Stephens, K. S. Wallwork, S. F. Lincoln, M. R.Taylor and K. P. Wainwright, Inorg. Chem., 2002, 41, 1093-1100.94. C. B. Smith, K. S. Wallwork, J. M. Weeks, M. A. Buntine, S. F. Lincoln,M. R. Taylor and K. P. Wainwright, Inorg. Chem., 1999, 38, 4986-4992.95. C. B. Smith, M. A. Buntine, S. F. Lincoln and K.P. Wainwright, DaltonTrans., 2003, 3028-3033.96. C. B. Smith, M. A. Buntine, S. F. Lincoln, M. R. Taylor and K. P.Wainwright, Aust. J. Chem., 2006, 59, 123-128.97. C. B. Smith, S. F. Lincoln, M. R. Taylor and K. P. Wainwright, ActaCrystallogr., 2002, E58, m33-m35.98. P. J. Davies, S. F. Lincoln, C. B. Smith, M. R. Taylor, K. P. Wainwrightand K. S. Wallwork, Acta Crystallogr., Sect C: Cryst. Struct. Commun.,2000, C56, 28-30.99. R. D. Hancock, Chem. Rev., 1989, 89, 1875-1914.100. R. D. Hancock, M. S. Shaikjee, S. M. Dobson and J. C. A. Boeyens,Inorg. Chim. Acta, 1988, 154, 229-238.101. M. Subat, K. Woinaroschy, C. Gerstl, B. Sarkar, W. Kaim and B.Koenig, Inorg. Chem., 2008, 47, 4661-4668.102. A. S. Delephine, R. Tripier and H. Handel, Org. Biomol. Chem., 2008, 6,1743-1750.103. A. de Castries, A. Escande, H. Fensterbank, E. Magnier, J. Marrot andC. Larpent, Tetrahedron, 2007, 63, 10330-10336.104. P. S. K. Chia, A. Ekstrom, I. Liepa, L. F. Lindoy, M. McPartlin, S. V.Smith and P. A. Tasker, Aust. J. Chem., 1991, 44, 737-746.171
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Silica Immobilised MetalIon Activat
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ABSTRACTImmobilisation of functiona
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DECLARATIONI certify that this thes
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EtOHGPDMSGPDMESGPSGPTSethanolglycid
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CHAPTER ONEINTRODUCTION
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The focus of this work was to prepa
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sequestering anions has proved to b
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ange of pH due to its high basicity
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nitrophenol or p-nitrophenolate wit
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It has been shown by NMR and crysta
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within the cavity of a p-tert-butyl
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60 in 0.5% DMSO-MeCN (v/v). 82 The
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synthesised bi- tri- and tetra - π
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adopt a trans-III conformation, whe
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amide oxygen atoms on the pendant a
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apparent there is, nonetheless, evi
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However, hetero-N-substitution on t
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Si-OH +- OH SiO - + H 2 OFor surfac
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35This material was obtained with a
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OOSiOHOROR OSiOHOOOSiOSiOSiOSiOSiOS
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Tetraaza metal complexes immobilise
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CHAPTER TWOSYNTHESIS OF MACROCYCLIC
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In addition, successful immobilisat
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3233Figure 2.3Reaction of 3-(glycid
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The methodology chosen was adapted
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agreed with literature values. 109R
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XS HO O H61, n = 262, n = 3n+ClOSO6
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anhydrous ethanol, Scheme 2.7. The
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75Figure 2.5 Structure of (S)-(-)-p
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metal ion coordination the pendant
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CHAPTER THREEGUEST MOLECULE INCLUSI
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3.1 where K A is the association, o
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0.5cχG∆δ∆δGbaχ GFigure 3.1S
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χG∆δ∆δGFigure 3.4 Job's Plot
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The downfield movement of the guest
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arm framework. The relative magnitu
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This phenomenon correlates well wit
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non-classical hydrogen bonding is g
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The full set of logK values obtaine
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such that they would indicate precl
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CHAPTER 4MODIFICATION OF THE SILICA
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Chemical modification of the silica
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GPTSGPDMESFigure 4.4Schematic depic
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GPS, 33, linker material with an ex
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free νOHτSiOHνSi-O-SiδH 2 Oasym
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224, 225the surface silanol groups.
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esonances, the spectrum for Si-GPS-
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increase in surface coverage from t
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and, more so due to the larger size
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CHAPTER 5METAL ION UPTAKE STUDIES W
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Scheme 5.1 Metal(II) ion coordinati
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linker material, Si-GPS, 33; endcap
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[Cd(Trac)](ClO 4 ) 2 , 94, or Si-GP
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CHAPTER 6GUEST MOLECULE INCLUSION S
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and D-histidinate. Guest inclusion
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Table 6.2Percent inclusion data for
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contains two hydroxy groups in the
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methoxy group, as portrayed by the
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these guest molecules with receptor
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only about half of that taken up by
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Percent inclusion values for these
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Table 6.7Percent guest inclusion of
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6.1.7 Guest inclusion studies with
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A1 3542Neutral GuestBAnionic GuestH
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A1 46 7532 Anionic Guest8BCHostHost
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extent, meta-positioned hydroxy gro
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δ obs (ppm)6.2146.2136.2126.2116.2
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CHAPTER 7EXPERIMENTAL7.1 General Ex
Page 139 and 140: inding constants (logK values) and
Page 141 and 142: delay time of 4 s. 13 C CPMAS NMR s
Page 143 and 144: C, -CH 2 - CH 2 OSO 2 ); 68.11 (1 C
Page 145 and 146: A solution of 69 (2.00 g, 10.1 mmol
Page 147 and 148: Bn, meta); 127.79 (1 C, Bn, para);
Page 149 and 150: added in a single portion. The mixt
Page 151 and 152: dioxane): δ 158.67 (1 C, C=O); 135
Page 153 and 154: 1-(benzyloxycarbonyl)-4,7,10-tris-(
Page 155 and 156: 1,4,7-tris-((S)-2-hydroxy-3-phenoxy
Page 157 and 158: 1,4,7-tris(S)-2-hydroxy-3-[4-((2-(2
Page 159 and 160: 1,4,7-tris(S)-2-hydroxy-3-[4-(2-(2-
Page 161 and 162: 1-(2-hydroxypropyl)-4,7,10-tris-((S
Page 163 and 164: 7.11 Preparation of the silica mate
Page 165 and 166: To a suspension of 33 (1.48 g, 1.1
Page 167 and 168: gel-like suspension that was cooled
Page 169 and 170: Si-GPS-Tri-Trac, 4545The title comp
Page 171 and 172: APPENDIX ABINDING CONSTANT DETERMIN
Page 173 and 174: 1.01000.880δ obs (ppm)0.60.4logK =
Page 175 and 176: APPENDIX BDETERMINATION OF STOICHIO
Page 177 and 178: 0.5χG∆δGFigure B.2χ GSimulated
Page 179 and 180: 13 C CPMAS NMR SPECTRA OF SOME HIGH
Page 181 and 182: Si-GPS-[Cd(Trac)(2,5-diydroxybenzoa
Page 183 and 184: REFERENCES
Page 185 and 186: 15. D. Tzalis and Y. Tor, Tetrahedr
Page 187 and 188: 42. A. P. Davis and R. S.Wareham, A
Page 189: 69. R. J. Bergeron, M. A. Channing
Page 193 and 194: 118. D. D. Dischino, E. J. Delaney,
Page 195 and 196: 144. X. Huang, X. Chang, Q. He, Y.
Page 197 and 198: 169. J. M. Klunder, T. Onami and K.
Page 199 and 200: 197. K. A. Connors, Binding Constan
Page 201 and 202: 221. J. Blumel, J. Am. Chem. Soc.,
Page 203: 247. W. Likussar and D. F. Botz, An
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Jozef Hodyl PhD Thesis - Theses - Flinders University

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