Jozef Hodyl PhD Thesis - Theses - Flinders University

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131. V. Boldrini, G. B. Giovenzana, R. Pagliarin, G. Palmisano and M. Sisti,Tetrahedron Lett., 2000, 41, 6527-6530.132. F. Barbette, F. Rascalou, H. Chollett, J. L. Babouhot, F. Denat and R.Guilard, Anal. Chim. Acta, 2004, 502, 179-187.133. P. K. Jal, R. K. Dutta, M. Sudarshan, A. Saha, S. N. Bhattacharyya, S. N.Chintalapudi and B. K. Mishra, Talanta, 2001, 55, 233-240.134. R. K. Dey, U. Jha, A. C. Singh, S. Samal and A. R. Ray, Anal. Sci.,2006, 22, 1105-1110.135. N. L. Dias Filho, Y. Gushikem, W. L. Polito, J. C. Moreira and E. O.Ewrin, Talanta, 1995, 42, 1625-1630.136. P. K. Jal, S. Patel and B. K. Mishra, Talanta, 2004, 62, 1005-1028.137. P. Qiaosheng, S. Qiaoyu, H. Zhide and S. Zhixing, Analyst, 1998, 123,239-243.138. J. S. Kim, S. Chah and J. Yi, Korean J. Chem. Eng., 2000, 17, 118-121.139. A. T. Yordanov and D. M. Roundhill, Coord. Chem. Rev., 1998, 170,93-124.140. W. Szczepaniak and A. Szymanski, Acta Chromatogr., 1993, 2, 7-20.141. M. E. Mahmoud, Anal. Chim. Acta, 1999, 398, 297-304.142. M. M. A. Akl, I. M. M. Kenawy and R. R. Lasheen, Microchem. J.,2004, 78, 143-156.143. T. Meyer, S. Spange, S. Hesse, C. Jager and C. Bellman, Macromol.Chem. Phys., 2003, 204, 725-732.174
144. X. Huang, X. Chang, Q. He, Y. Cui, Y. Zhai and N. Jiang, J. Hazard.Mater., 2008, 157, 154-160.145. N. V. Deorkar and L. L. Tavlarides, Ind. Eng. Chem. Res., 1997, 36,399-406.146. R. S. Paredes, N. S. Valera and L. F. Lindoy, Aust. J. Chem., 1986, 39,1071-1079.147. F. Zipoli, D. Donadio and M. Bernasconi, J. Phys.: Condens. Matter,2008, 20, 224011/224011-224011/224016.148. R. K. Iler, The Chemistry of Silica: Solubility, Polymerisation, Colloidand Surface Properties, and Biochemistry, John Wiley and Sons, NewYork, 1979.149. J. Nawrocki, J. Chromatogr. A, 1997, 779, 29-72.150. M. E. Essington, Soil and Water Chemistry: An Integrative Approach,CRC Press, Routledge, U.S.A., 2003.151. K. E. Bij, C. Horvath, W. R. Melander and A. Nahum, J. Chromatogr.,1981, 203, 65-84.152. E. P. Plueddemann, Silane Coupling Agents, 2nd edn., Plenum Press,New York, 1991.153. V. Dudler, L. F. Lindoy, D. Sallin and C. W. Schlaepfer, Aust. J. Chem.,1987, 40, 1557-1563.154. T. N. T. Phan, M. Bacquet and M. Morcellet, J. Inclusion Phenom. Mol.Recognit. Chem., 2000, 38, 345-359.155. K. Fujimura, T. Ueda and T. Ando, Anal. Chem., 1983, 55, 446-450.175
Page 1 and 2:
Silica Immobilised MetalIon Activat
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ABSTRACTImmobilisation of functiona
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DECLARATIONI certify that this thes
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EtOHGPDMSGPDMESGPSGPTSethanolglycid
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CHAPTER ONEINTRODUCTION
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The focus of this work was to prepa
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sequestering anions has proved to b
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ange of pH due to its high basicity
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nitrophenol or p-nitrophenolate wit
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It has been shown by NMR and crysta
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within the cavity of a p-tert-butyl
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60 in 0.5% DMSO-MeCN (v/v). 82 The
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synthesised bi- tri- and tetra - π
Page 29 and 30:
adopt a trans-III conformation, whe
Page 31 and 32:
amide oxygen atoms on the pendant a
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apparent there is, nonetheless, evi
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However, hetero-N-substitution on t
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Si-OH +- OH SiO - + H 2 OFor surfac
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35This material was obtained with a
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OOSiOHOROR OSiOHOOOSiOSiOSiOSiOSiOS
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Tetraaza metal complexes immobilise
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CHAPTER TWOSYNTHESIS OF MACROCYCLIC
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In addition, successful immobilisat
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3233Figure 2.3Reaction of 3-(glycid
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The methodology chosen was adapted
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agreed with literature values. 109R
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XS HO O H61, n = 262, n = 3n+ClOSO6
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anhydrous ethanol, Scheme 2.7. The
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75Figure 2.5 Structure of (S)-(-)-p
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metal ion coordination the pendant
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CHAPTER THREEGUEST MOLECULE INCLUSI
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3.1 where K A is the association, o
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0.5cχG∆δ∆δGbaχ GFigure 3.1S
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χG∆δ∆δGFigure 3.4 Job's Plot
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The downfield movement of the guest
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arm framework. The relative magnitu
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This phenomenon correlates well wit
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non-classical hydrogen bonding is g
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The full set of logK values obtaine
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such that they would indicate precl
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CHAPTER 4MODIFICATION OF THE SILICA
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Chemical modification of the silica
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GPTSGPDMESFigure 4.4Schematic depic
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GPS, 33, linker material with an ex
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free νOHτSiOHνSi-O-SiδH 2 Oasym
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224, 225the surface silanol groups.
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esonances, the spectrum for Si-GPS-
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increase in surface coverage from t
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and, more so due to the larger size
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CHAPTER 5METAL ION UPTAKE STUDIES W
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Scheme 5.1 Metal(II) ion coordinati
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linker material, Si-GPS, 33; endcap
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[Cd(Trac)](ClO 4 ) 2 , 94, or Si-GP
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CHAPTER 6GUEST MOLECULE INCLUSION S
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and D-histidinate. Guest inclusion
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Table 6.2Percent inclusion data for
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contains two hydroxy groups in the
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methoxy group, as portrayed by the
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these guest molecules with receptor
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only about half of that taken up by
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Percent inclusion values for these
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Table 6.7Percent guest inclusion of
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6.1.7 Guest inclusion studies with
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A1 3542Neutral GuestBAnionic GuestH
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A1 46 7532 Anionic Guest8BCHostHost
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extent, meta-positioned hydroxy gro
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δ obs (ppm)6.2146.2136.2126.2116.2
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CHAPTER 7EXPERIMENTAL7.1 General Ex
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inding constants (logK values) and
Page 141 and 142:
delay time of 4 s. 13 C CPMAS NMR s
Page 143 and 144: C, -CH 2 - CH 2 OSO 2 ); 68.11 (1 C
Page 145 and 146: A solution of 69 (2.00 g, 10.1 mmol
Page 147 and 148: Bn, meta); 127.79 (1 C, Bn, para);
Page 149 and 150: added in a single portion. The mixt
Page 151 and 152: dioxane): δ 158.67 (1 C, C=O); 135
Page 153 and 154: 1-(benzyloxycarbonyl)-4,7,10-tris-(
Page 155 and 156: 1,4,7-tris-((S)-2-hydroxy-3-phenoxy
Page 157 and 158: 1,4,7-tris(S)-2-hydroxy-3-[4-((2-(2
Page 159 and 160: 1,4,7-tris(S)-2-hydroxy-3-[4-(2-(2-
Page 161 and 162: 1-(2-hydroxypropyl)-4,7,10-tris-((S
Page 163 and 164: 7.11 Preparation of the silica mate
Page 165 and 166: To a suspension of 33 (1.48 g, 1.1
Page 167 and 168: gel-like suspension that was cooled
Page 169 and 170: Si-GPS-Tri-Trac, 4545The title comp
Page 171 and 172: APPENDIX ABINDING CONSTANT DETERMIN
Page 173 and 174: 1.01000.880δ obs (ppm)0.60.4logK =
Page 175 and 176: APPENDIX BDETERMINATION OF STOICHIO
Page 177 and 178: 0.5χG∆δGFigure B.2χ GSimulated
Page 179 and 180: 13 C CPMAS NMR SPECTRA OF SOME HIGH
Page 181 and 182: Si-GPS-[Cd(Trac)(2,5-diydroxybenzoa
Page 183 and 184: REFERENCES
Page 185 and 186: 15. D. Tzalis and Y. Tor, Tetrahedr
Page 187 and 188: 42. A. P. Davis and R. S.Wareham, A
Page 189 and 190: 69. R. J. Bergeron, M. A. Channing
Page 191 and 192: 93. C. B. Smith, A. K. W. Stephens,
Page 193: 118. D. D. Dischino, E. J. Delaney,
Page 197 and 198: 169. J. M. Klunder, T. Onami and K.
Page 199 and 200: 197. K. A. Connors, Binding Constan
Page 201 and 202: 221. J. Blumel, J. Am. Chem. Soc.,
Page 203: 247. W. Likussar and D. F. Botz, An
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Jozef Hodyl PhD Thesis - Theses - Flinders University

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