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ASTMASTM D5599 Oxygenates in Gas by GC & O-FIDOxygenates Calibration CurvesWith Internal StandardM-GRO-CAL/IS-SET$ 250 / 8 x 1 mLM-GRO-CAL/IS-SET-PAKSAVE 20% $ 1,000 / 5 x (8 x 1) mLof 15 Comp. MixAnalyte Std. 1 Std. 2 Std. 3 Std. 4 Std. 5 Std. 6 Std. 7 Std. 8Calibration range Wt. % Wt. % Wt. % Wt. % Wt. % Wt. % Wt. % Wt. %Methanol 0.1 - 5.0 --- 0.1 2.5 --- 5 0.5 1 ---Ethanol 1.0 - 12.0 12 --- 3 --- 8 5 1 ---Isopropanol 0.1 - 2.0 2 1 --- 0.1 0.3 --- 0.5 ---t-Butanol 0.1 - 2.0 0.5 0.1 1 --- 2 0.3 --- ---Propanol 0.2 - 2.0 2 --- 0.7 0.2 1 --- 0.4 ---MtBE 1.0 - 17.0 5 17 --- --- 1 2.5 10 ---sec-Butanol 0.1 - 2.5 1 --- 0.5 0.1 --- 2.5 0.7 ---Diisopropyl ether 0.1 - 2.0 --- 0.5 0.3 0.1 2 1 --- ---iso-Butanol 0.1 - 2.0 2 0.5 --- 1 0.1 0.3 --- ---EtBE 1.0 - 18.0 --- 3.5 18 7.5 --- 1 12 ---t-Pentanol 0.1 - 2.0 0.3 1 --- 0.5 0.1 2 --- ---Butanol 0.1 - 2.0 1 --- 0.3 --- 0.5 0.1 2 ---TAME 1.0 - 18.0 --- 3.5 1 18 7.5 12 --- ---Technical NoteThis certified oxygenate calibrationcurve can be used in combinationwith other aromatic standards forcombined oxygenate/aromaticanalysis, to change the amount ofinternal standard added, or toincorporate alternative internalstandard analytes.1,2- Dimethoxyethane (ISTD) 4 4 4 4 4 4 4 ---RFA Gasoline 70.2 68.8 68.7 68.5 68.5 68.8 68.4 100Total oxygenates & ISTD 29.8 31.2 31.3 31.5 31.5 31.2 31.6 0ASTM D5599With Internal StandardM-GRO-CAL/IS-R1-SET$ 250 / 8 x 1 mLNEWM-GRO-CAL/IS Analyte 01-R1 02-R1 03-R1 04-R1 05-R1 06-R1 07-R1 08-R1Calibration range Wt. % Wt. % Wt. % Wt. % Wt. % Wt. % Wt. % Wt. %Methanol 0.1 - 5.0 -- 0.1 2.5 -- 5 0.5 1 --Ethanol 1.0 - 12.0 12 -- 3 -- 8 5 1 --Isopropanol 0.1 - 2.0 2 1 -- 0.1 0.3 -- 0.5 --t-Butanol 0.1 - 2.0 0.5 0.1 1 -- 2 0.3 -- --Propanol 0.2 - 2.0 2 -- 0.7 0.2 1 -- 0.4 --MtBE 1.0 - 17.0 5 17 -- -- 1 2.5 10 --sec-Butanol 0.1 - 2.5 1 -- 0.5 0.1 -- 2.5 0.7 --Diisopropyl ether 0.1 - 2.0 -- 0.5 0.3 0.1 2 1 -- --Isobutanol 0.1 - 2.0 2 0.5 -- 1 0.1 0.3 -- --EtBE 1.0 - 18.0 -- 3.5 18 7.5 -- 1 12 --tert-Pentanol 0.1 - 2.0 0.3 1 -- 0.5 0.1 2 -- --Butanol 0.1 - 2.0 1 -- 0.3 -- 0.5 0.1 2 --TAME 1.0 - 18.0 -- 3.5 1 18 7.5 12 -- --1,2-Dimethoxyethane (ISTD) 4 4 4 4 4 4 4 --RFA Gasoline 74.2 72.8 72.7 72.5 72.5 72.8 72.4 100Total oxygenates & ISTD 28.6 30.0 30.1 30.3 30.3 30.0 30.4 0Technical NoteThe revised Set formulates theproduct components and gasoline to100 mL volume and then adds theInternal Standard for a total volumeof 104 mL.D5599MeetsEPA Guidelinesfor RFGAnalysisWithout Internal StandardM-GRO-CAL-SET$ 850 / 8 x 10 mLof 14 Comp. MixAnalyte Std. 1 Std. 2 Std. 3 Std. 4 Std. 5 Std. 6 Std. 7 Std. 8Calibration range Wt. % Wt. % Wt. % Wt. % Wt. % Wt. % Wt. % Wt. %Methanol 0.1 - 5.0 --- 0.1 2.5 --- 5 0.5 1 ---Ethanol 1.0 - 12.0 12 --- 3 --- 8 5 1 ---Isopropanol 0.1 - 2.0 2 1 --- 0.1 0.3 --- 0.5 ---t-Butanol 0.1 - 2.0 0.5 0.1 1 --- 2 0.3 --- ---Propanol 0.2 - 2.0 2 --- 0.7 0.2 1 --- 0.4 ---MtBE 1.0 - 17.0 5 17 --- --- 1 2.5 10 ---sec-Butanol 0.1 - 2.5 1 --- 0.5 0.1 --- 2.5 0.7 ---Diisopropyl ether 0.1 - 2.0 --- 0.5 0.3 0.1 2 1 --- ---iso-Butanol 0.1 - 2.0 2 0.5 --- 1 0.1 0.3 --- ---EtBE 1.0 - 18.0 --- 3.5 18 7.5 --- 1 12 ---t-Pentanol 0.1 - 2.0 0.3 1 --- 0.5 0.1 2 --- ---Butanol 0.1 - 2.0 1 --- 0.3 --- 0.5 0.1 2 ---TAME 1.0 - 18.0 --- 3.5 1 18 7.5 12 --- ---RFA Gasoline 74.2 72.8 72.7 72.5 72.5 72.8 72.4 100Total oxygenates 25.8 27.2 27.3 27.5 27.5 27.2 27.6 0298 AccuStandard is accredited to ISO/IEC 17025 and certified to ISO 9001

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