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EPA Method 1614Mixtures of PBDEs Standard Solution for Accuracy & PrecisionBDE-AAP-A$ 195 / 1 x 1 mLAt stated conc. in Isooctane39 comps.ng/mL2-Bromodiphenyl ether (#1) 1003-Bromodiphenyl ether (#2) 1004-Bromodiphenyl ether (#3) 1002,4-Dibromodiphenyl ether (#7) 1002,4'-Dibromodiphenyl ether (#8) 1002,6-Dibromodiphenyl ether (#10) 1003,3'-Dibromodiphenyl ether (#11) 1003,4-Dibromodiphenyl ether (#12) 1003,4'-Dibromodiphenyl ether (#13) 1004,4'-Dibromodiphenyl ether (#15) 1002,2',4,-Tribromodiphenyl ether (#17) 1002,3',4-Tribromodiphenyl ether (#25) 1002,4,4'-Tribromodiphenyl ether (#28) 1002,4,6-Tribromodiphenyl ether (#30) 1002,4',6-Tribromodiphenyl ether (#32) 1002',3,4-Tribromodiphenyl ether (#33) 1003,3',4-Tribromodiphenyl ether (#35) 1003,4,4'-Tribromodiphenyl ether (#37) 1002,2',4,4'-Tetrabromodiphenyl ether (#47) 1002,2',4,5'-Tetrabromodiphenyl ether (#49) 1002,3',4,4'-Tetrabromodiphenyl ether (#66) 1002,3',4',6-Tetrabromodiphenyl ether (#71) 1002,4,4',6-Tetrabromodiphenyl ether (#75) 1003,3',4,4'-Tetrabromodiphenyl ether (#77) 1002,2',3,4,4'-Pentabromodiphenyl ether (#85) 1502,2',4,4',5-Pentabromodiphenyl ether (#99) 1502,2',4,4',6-Pentabromodiphenyl ether (#100) 1502,3,4,5,6-Pentabromodiphenyl ether (#116) 1502,3',4,4',5-Pentabromodiphenyl ether (#118) 1502,3',4,4',6-Pentabromodiphenyl ether (#119) 1503,3',4,4',5-Pentabromodiphenyl ether (#126) 1502,2',3,4,4',5'-Hexabromodiphenyl ether (#138) 2002,2',4,4',5,5'-Hexabromodiphenyl ether (#153) 2002,2',4,4',5,6'-Hexabromodiphenyl ether (#154) 2002,2',4,4',6,6'-Hexabromodiphenyl ether (#155) 2002,3,4,4',5,6-Hexabromodiphenyl ether (#166) 2002,2',3,4,4',5,6-Heptabromodiphenyl ether (#181) 2502,2',3,4,4',5',6-Heptabromodiphenyl ether (#183) 2502,3,3',4,4',5,6-Heptabromodiphenyl ether (#190) 250Mixture of Commonly Occurring PBDECongeners for Precision and RecoveryBDE-COC$ 600 / 1 x 1 mLAt stated conc. in Isooctane14 comps.µg/mL2,2',4,-Tribromodiphenyl ether (#17) 52,4,4'-Tribromodiphenyl ether (#28) 52,2',4,4’-Tetrabromodiphenyl ether (#47) 52,3',4,4'-Tetrabromodiphenyl ether (#66) 52,3',4',6-Tetrabromodiphenyl ether (#71) 52,2',3,4,4'-Pentabromodiphenyl ether (#85) 52,2',4,4',5-Pentabromodiphenyl ether (#99) 52,2',4,4',6-Pentabromodiphenyl ether (#100) 52,2',3,4,4',5'-Hexabromodiphenyl ether (#138) 52,2',4,4',5,5'-Hexabromodiphenyl ether (#153) 52,2',4,4',5,6'-Hexabromodiphenyl ether (#154) 52,2',3,4,4',5',6-Heptabromodiphenyl ether (#183) 52,3,3',4,4',5,6-Heptabromodiphenyl ether (#190) 5Decabromodiphenyl ether (#209) 25BDE-AAP-A-15X$ 750 / 1 x 1 mLAt stated conc. in Isooctane39 comps.µg/mL2-Bromodiphenyl ether (#1) 1.53-Bromodiphenyl ether (#2) 1.54-Bromodiphenyl ether (#3) 1.52,4-Dibromodiphenyl ether (#7) 1.52,4'-Dibromodiphenyl ether (#8) 1.52,6-Dibromodiphenyl ether (#10) 1.53,3'-Dibromodiphenyl ether (#11) 1.53,4-Dibromodiphenyl ether (#12) 1.53,4'-Dibromodiphenyl ether (#13) 1.54,4'-Dibromodiphenyl ether (#15) 1.52,2',4,-Tribromodiphenyl ether (#17) 1.52,3',4-Tribromodiphenyl ether (#25) 1.52,4,4'-Tribromodiphenyl ether (#28) 1.52,4,6-Tribromodiphenyl ether (#30) 1.52,4',6-Tribromodiphenyl ether (#32) 1.52',3,4-Tribromodiphenyl ether (#33) 1.53,3',4-Tribromodiphenyl ether (#35) 1.53,4,4'-Tribromodiphenyl ether (#37) 1.52,2',4,4'-Tetrabromodiphenyl ether (#47) 1.52,2',4,5'-Tetrabromodiphenyl ether (#49) 1.52,3',4,4'-Tetrabromodiphenyl ether (#66) 1.52,3',4',6-Tetrabromodiphenyl ether (#71) 1.52,4,4',6-Tetrabromodiphenyl ether (#75) 1.53,3',4,4'-Tetrabromodiphenyl ether (#77) 1.52,2',3,4,4'-Pentabromodiphenyl ether (#85) 2.252,2',4,4',5-Pentabromodiphenyl ether (#99) 2.252,2',4,4',6-Pentabromodiphenyl ether (#100) 2.252,3,4,5,6-Pentabromodiphenyl ether (#116) 2.252,3',4,4',5-Pentabromodiphenyl ether (#118) 2.252,3',4,4',6-Pentabromodiphenyl ether (#119) 2.253,3',4,4',5-Pentabromodiphenyl ether (#126) 2.252,2',3,4,4',5'-Hexabromodiphenyl ether (#138) 3.02,2',4,4',5,5'-Hexabromodiphenyl ether (#153) 3.02,2',4,4',5,6'-Hexabromodiphenyl ether (#154) 3.02,2',4,4',6,6'-Hexabromodiphenyl ether (#155) 3.02,3,4,4',5,6-Hexabromodiphenyl ether (#166) 3.02,2',3,4,4',5,6-Heptabromodiphenyl ether (#181) 3.752,2',3,4,4',5',6-Heptabromodiphenyl ether (#183) 3.752,3,3',4,4',5,6-Heptabromodiphenyl ether (#190) 3.75PBDE Congeners of Primary InterestBDE-CSM$ 225 / 1 x 1 mLAt stated conc. in Isooctane8 comps.µg/mL2,4,4'-Tribromodiphenyl ether (#28) 202,2',4,4'-Tetrabromodiphenyl ether (#47) 202,2',4,4',5-Pentabromodiphenyl ether (#99) 202,2',4,4',6-Pentabromodiphenyl ether (#100) 202,2',4,4',5,5'-Hexabromodiphenyl ether (#153) 202,2',4,4',5,6'-Hexabromodiphenyl ether (#154) 202,2',3,4,4',5',6-Heptabromodiphenyl ether (#183) 20Decabromodiphenyl ether (#209) 200Technical NoteResponding to the need for the analysisof polybrominated diphenyl ether(PBDE) congeners, the EPA hasdeveloped Method 1614. Method 1614is recommended for analysis ofaqueous, solid, tissue, and multi-phaseenvironmental samples. Eachformulation is prepared using PBDEswhich are synthesized and analyzed byAccuStandard.Additional congeners, mixesand metabolites are addedcontinuously. For an update,check our website.AccuStandard.comMethod 1614PBDE Congeners of Primary InterestCalibration MixBDE-CM$ 65 / 1 x 1 mLAt stated conc. in Isooctane8 comps.µg/mL2,4,4'-Tribromodiphenyl ether (#28) 2.52,2',4,4'-Tetrabromodiphenyl ether (#47) 2.52,2',4,4',5-Pentabromodiphenyl ether (#99) 2.52,2',4,4',6-Pentabromodiphenyl ether (#100) 2.52,2',4,4',5,5'-Hexabromodiphenyl ether (#153) 2.52,2',4,4',5,6'-Hexabromodiphenyl ether (#154) 2.52,2',3,4,4',5',6-Heptabromodiphenyl ether (#183) 2.5Decabromodiphenyl ether (#209) 25Matrix Spiking SolutionBDE-MS$ 40 / 1 x 1 mLAt stated conc. in Isooctane8 comps.ng/mL2,4,4'-Tribromodiphenyl ether (#28) 12,2',4,4'-Tetrabromodiphenyl ether (#47) 12,2',4,4',5-Pentabromodiphenyl ether (#99) 12,2',4,4',6-Pentabromodiphenyl ether (#100) 12,2',4,4',5,5'-Hexabromodiphenyl ether (#153) 12,2',4,4',5,6'-Hexabromodiphenyl ether (#154) 12,2',3,4,4',5',6-Heptabromodiphenyl ether (#183) 1Decabromodiphenyl ether (#209) 10PBDEs in Method 1614BDE-EPA-SET$ 500 / 8 x 1 mL50 µg/mL each in Isooctane 8 comps.2,4,4'-Tribromodiphenyl ether (#28)2,2',4,4'-Tetrabromodiphenyl ether (#47)2,2',4,4',5-Pentabromodiphenyl ether (#99)2,2',4,4',6-Pentabromodiphenyl ether (#100)2,2',4,4',5,5'-Hexabromodiphenyl ether (#153)2,2',4,4',5,6'-Hexabromodiphenyl ether (#154)2,2',3,4,4',5',6-Heptabromodiphenyl ether (#183)Decabromodiphenyl ether (#209)Tel. 800-442-5290 / 203-786-5290 • Fax 203-786-5287 • Web AccuStandard.com 57

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