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ILCD Handbook: Framework and requirements for LCIA models and ...

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<strong>ILCD</strong> <strong>H<strong>and</strong>book</strong>: <strong>Framework</strong> <strong>and</strong> <strong>requirements</strong> <strong>for</strong> <strong>LCIA</strong> <strong>models</strong> <strong>and</strong> indicators First edition<br />

external irradiation<br />

due to water<br />

Gy/day per Bq/kg<br />

freshwater<br />

radioactive releases<br />

internal irradiation due<br />

to bioaccumulation<br />

Gy/day per Bq/kg<br />

BCF L/kg<br />

Algae<br />

crustacae<br />

fish<br />

Damage on ecosystems<br />

sediment<br />

external irradiation<br />

due to sediments<br />

Gy/day per Bq/kg<br />

Figure 4-7 Overview of impact pathway on ecosystem <strong>for</strong> radioactive releases to freshwater.<br />

Solid lines refer to physical transfers of radioactive substances, whereas dotted<br />

lines correspond to exposures of radioactive radiation.<br />

4.5.2 Criteria <strong>for</strong> Evaluation of this impact category<br />

Since currently only a single method is presently considered relevant <strong>for</strong> each of the<br />

ionizing radiation subcategories, no detailed criteria-based comparison is planned as with the<br />

other impact categories. Hence no specific criteria have been developed <strong>for</strong> this impact<br />

category. Instead the evaluation is focused on the level of quality reached by the available<br />

methods within each main criterion.<br />

4.6 Photochemical ozone <strong>for</strong>mation<br />

4.6.1 <strong>Framework</strong> <strong>and</strong> scope<br />

The negative impacts from the photochemically generated pollutants are due to their<br />

reactive nature which enables them to oxidise organic molecules on the surfaces they<br />

expose. Impacts on humans arise when the ozone <strong>and</strong> other reactive oxygen compounds<br />

are inhaled <strong>and</strong> come into contact with the surface of the respiratory tract, where they<br />

damage tissue <strong>and</strong> cause respiratory diseases. Impacts on vegetation arise when the<br />

reactive compounds attack the surfaces of the plants or enter the stomata of the plant<br />

leaves, <strong>and</strong> cause oxidative damage on photosynthetic organelles. Impacts on man-made<br />

materials are caused by oxidation <strong>and</strong> damage to many types of organic materials which are<br />

exposed to ambient air. NB: the man-made environment is not considered in the<br />

recommendations, <strong>and</strong> there<strong>for</strong>e the effects on man-made materials will not be considered<br />

further.<br />

The reaction scheme underlying the impact pathway is highly complex <strong>and</strong> depends on<br />

the <strong>for</strong>mula of the concrete VOC, but it can be summarised as:<br />

4 Requirements <strong>for</strong> specific impact categories 51

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