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Final Chemistry Notebook

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Then substitute them into the constant ratio of Charles' law:<br />

When using Charles' law, remember that volume and Kelvin temperature vary directly; therefore, an<br />

increase in either requires a proportional increase in the other.<br />

2. A gas occupying 660 ml at a laboratory temperature of 20°C was refrigerated until it shrank to 125<br />

ml. What is the temperature in degrees Celsius of the chilled gas?<br />

660/20c = 125ml/t<br />

+273<br />

660ml/293 = 125/t<br />

Gay-Lussac's Law<br />

36625=660t<br />

t=55.4924<br />

-273<br />

t=218.494<br />

p =200c<br />

-200 C<br />

This relationship between temperature and pressure is known as Gay-Lussac's law. It states that if<br />

the volume of a container is held constant as the temperature of a gas increases, the pressure inside<br />

the container will also increase. As with the other gas laws, this one can be represented in the form of<br />

an equation:<br />

P1 = P2<br />

T2<br />

Recall that we use 1s and 2s to indicate the quantities before (1s) and after (2s) a change has taken<br />

place. Also, note that the units for pressure do not matter, as long as they are the same throughout<br />

the entire equation. The units for temperature must be Kelvins or the equation will not work. This is<br />

because the Kelvin scale is an absolute scale - it doesn't go negative. <strong>Final</strong>ly, this equation only<br />

works for an ideal gas. Most gases that surround you and me behave very much like ideal gases, so<br />

we can use this equation as an approximation for the gases we encounter.<br />

T2<br />

126

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