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Final Chemistry Notebook

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The Learning Goal for this assignment is:<br />

Describes phase transations in terms of kinetic molecular theory<br />

The System and the Surroundings in <strong>Chemistry</strong><br />

Thermochemistry<br />

The system is the part of the universe we wish to focus our attention on. In the world of chemistry, the<br />

system is the chemical reaction. For example:<br />

2H2 + O2 ---> 2H2O<br />

The system consists of those molecules which are reacting.<br />

The surroundings are everything else; the rest of the universe. For example, say the above reaction is<br />

happening in gas phase; then the walls of the container are part of the surroundings.<br />

There are two important issues:<br />

1. a great majority of our studies will focus on the change in the amount of energy, not the<br />

absolute amount of energy in the system or the surroundings.<br />

2. regarding the direction of energy flow, we have a "sign convention."<br />

Two possibilities exist concerning the flow of energy between system and surroundings:<br />

1. The system can have energy added to it, which increases its amount and lessens the energy<br />

amount in the surroundings.<br />

2. The system can have energy removed from it, thereby lowering its amount and increasing the<br />

amount in the surroundings.<br />

We will signify an increase in energy with a positive sign and a loss of energy with a negative sign.<br />

Also, we will take the point-of-view from the system. Consequently:<br />

1. When energy (heat or work) flow out of the system, the system decreases in its amount. This<br />

is assigned a negative sign and is called exothermic.<br />

2. When energy (heat or work) flows into the system, the system increases its energy amount.<br />

This is assigned a positive sign and is called endothermic.<br />

We do not discuss chemical reactions from the surrounding's point-of-view. Only from the system's.<br />

Notes: All reaction accur due to the energy<br />

it sorrunding has or else it wouldnt funtion and when changing of phases accur temperatue and presuure changes.Endothermic r<br />

eaction is the process or reaction in which the system absorbs energy from its surroundings; usually,heat but not always. Examples<br />

of this would beas to liquid:Condensation, Liquid to solid;freezing, amd gas to solid ; deposition. While exothermic reactions are a<br />

chemical reaction that releases energy by heat. Exothermic means heat is given off or heat is flowing Some examples of e<br />

exothermic reactions would be, solid to liquid; melting, liquid to gas :vaporizing, and solid togas sublimation<br />

136

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