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tel-00751814, version 1 - 14 Nov 2012<br />

Chapter 4. Nitri<strong>de</strong> Dispersion Strengthened Steels<br />

<strong>par</strong>ticle, forming the shell if solute <strong>de</strong>pletion rate from the core is greater than solute<br />

diffusion rate from the oxi<strong>de</strong>/matrix interface during the crystallization stage.<br />

Such mechanism could also occurs during MA in NDS steel. This could exp<strong>la</strong>in why there is<br />

no evi<strong>de</strong>nce of Cr shell in as-milled samples.<br />

a)<br />

b)<br />

Figure 4.23. Evolution of concentration of (a) Ti+N (at.%) and (b) Cr measured in<br />

MA NDS steel as a function of Guinier radius (Rg). Hot extru<strong>de</strong>d condition (h.e.) is also<br />

taken into account. Guinier Radius (x axis) is shown in logarithmic scale.<br />

156

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