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NOx Emissions from Cement Mfg - US Environmental Protection ...

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dry process system. 5<br />

The choice between the wet or dry process for cement<br />

manufacturing often depends upon the moisture content in the raw<br />

feed materials mined <strong>from</strong> quarries. If the moisture content of<br />

the feed materials is already very high (15 to 20 percent), a wet<br />

process may be attractive. The recent trend, however, has been<br />

toward the dry process with preheater/precalciner systems. In<br />

1990, about 25 million tons of clinker were produced by the wet<br />

process with 55.8 million tons produced by a dry process. Within<br />

the dry process category, 15.7 million tons were produced by<br />

facilities equipped with a preheater system and 21.4 million tons<br />

were produced by facilities equipped with a precalciner system.<br />

3<br />

The different steps involved in the cement manufacturing<br />

process are described in the following subsections.<br />

3.3.3 Raw Materials and Kiln Feed Preparation<br />

Oxides of calcium, silicon, aluminum, and iron comprise the<br />

basic ingredients of cement. Because of the large requirement of<br />

CaO, the plants are generally located near the source of the<br />

calcareous material. The requisite silica and alumina may be<br />

derived <strong>from</strong> a clay, shale, or overburden <strong>from</strong> a limestone<br />

quarry. Such materials usually contain some of the required iron<br />

oxide, but many plants need to supplement the iron with mill<br />

scale, pyrite cinders, or iron ore. Silica may be supplemented<br />

by adding sand to the raw mix, whereas alumina can be furnished<br />

4<br />

by bauxites and alumina-rich flint clays. Industrial by-<br />

products are becoming more widely used as raw materials for<br />

cement, e.g., slags contain carbonate-free lime, as well as<br />

3-14

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